The 2.5-5.0 micrometers spectra of Io: evidence for H2S and H2O frozen in SO2

Infrared spectra of Io in the region 2.5-5.0 micrometers, including new observational data, are analyzed using detailed laboratory studies of plausible surface ices. Besides the absorption bands attributable to sulfur dioxide frosts, four infrared spectral features of Io are shown to be unidentified. These unidentified features show spatial and temporal band strength variations. One pair is centered around 3.9 micrometers (3.85 and 3.91 micrometers) and the second pair is centered around 3.0 micrometers (2.97 and 3.15 micrometers). These absorptions fall close to the fundamental stretching modes in H2S and H2O, respectively. The infrared absorption spectra of an extensive set of laboratory ices ranging from pure materials, to binary mixtures of H2S and H2O (either mixed at different concentrations or layered), to H2O:H2S:SO2 mixtures are discussed. The effects of ultraviolet irradiation (120 and 160 nm) and temperature variation (from 9 to 130 K) on the infrared spectra of the ices are examined. This comparative study of Io reflectance spectra with the laboratory mixed ice transmission data shows the following: (1) Io's surface most likely contains H2S and H2O mixed with SO2. The 3.85- and 3.91-micrometers bands in the Io spectra can be accounted for by the absorption of the S-H stretching vibration (nu 1) in H2S clusters and isolated molecules in an SO2-dominated ice. The weak 2.97- and 3.15-micrometers bands which vary spatially and temporally in the Io spectra coincide with the nu 3 and nu 1 O-H stretching vibrations of clusters of H2O molecules complexed, through hydrogen bonding and charge transfer interactions, with SO2. (2) The observations are well matched qualitatively by the transmission spectra of SO2 ices containing about 3% H2S and 0.1% H2O which have been formed by the condensation of a mixture of the gases onto a 100 K surface. (3) No new features are produced in the region 2.5 to 5.0 micrometers in the spectrum of these ices under prolonged ultraviolet irradiation or temperature variation up to 120 K. (4) Comparison of the Io spectra to transmission spectra of both mixed molecular ices and layered ices indicates that only the former can explain the shifts and splitting of the absorption bands seen in the Io spectrum and additionally can account for the fact that solid H2S is observed in the surface material of Io at temperature and pressure conditions above the sublimation point of pure H2S.     

Observations of Saturn in the 5- to 8-μm spectral region

A spectrum of Saturn obtained from the Kuiper Airborne Observatory exhibits an emission peak at 6.8 μm attributed to ethane, but is otherwise dominated by absorption from 5.3 to 7.2 μm. While the large absorption in this spectral region is consistent with the presence of ammonia gas or ammonia ice, or both, such an explanation is inconsistent with the lack of a major absorption near 3.0 μm.     

The discovery of a new infrared emission feature at 1905 wavenumbers (5.25 microns) in the spectrum of BD +30 degrees 3639 and its relation to the polycyclic aromatic hydrocarbon model

We have discovered a new IR emission feature at 1905 cm-1 (5.25 microns) in the spectrum of BD +30 degrees 3639. This feature joins the family of well-known IR emission features at 3040, 2940, 1750, 1610, "1310," 1160, and 890 cm-1 (3.3, 3.4, 5.7, 6.2, "7.7," 8.6, and 11.2 microns). The origin of this new feature is discussed and it is assigned to an overtone or combination band involving C-H bending modes of polycyclic aromatic hydrocarbons (PAHs). Laboratory work suggests that spectral studies of the 2000-1650 cm-1 (5.0-6.1 microns) region may be very useful in elucidating the molecular structure of interstellar PAHs. The new feature, in conjunction with other recently discovered spectral structure, suggests that the narrow IR emission features originate in PAH molecules rather than large carbon grains. Larger species are likely to be the source of the broad underlying "plateaus" seen in many of the spectra.     

华南西部地区晚中生代与W-Sn矿有关花岗岩的年代学格架及地质意义

华南西部地区是我国重要的大型-超大型锡多金属矿床分布区。本文根据近年来新获得的花岗岩LA-ICP-MS锆石U-Pb数据,结合近几年以来新报道的高精度成岩成矿年代学资料和地球动力学研究进展,总结发现华南西部地区中生代岩浆-成矿作用的时代主要集中在晚白垩世(76～98Ma)。通过分别总结华南东、西部地区晚白垩岩浆作用及相应的成矿作用的特征,发现华南东、西部的成岩成矿作用特征表现出明显的差异,但是这两地内部各自却表现出高度的一致性;且东部地区明显要比西部地区更为复杂,但二者之间的共同点在于该时期均处于岩石圈伸展的环境和壳幔间的相互作用明显。晚白垩世华南西部地区主要受控于华南陆块陆内背景下岩石圈伸展而导致的岩浆-成矿作用这一因素,而东部地区除此之外还受到太平洋古板块北北东向走滑带来的影响。     

The Oldest Evidence for Human Habitation in the Baltic Region: A Preliminary Report on the Chronology and Archaeological Context of the Riadino‐5 Archaeological Site

We report the discovery of the oldest evidence for human presence in the southeastern Baltic Sea region. This paper presents an overview of the Riadino‐5 archaeological site in the lower course of the Šešupė River (Kaliningrad Oblast of Russia) and direct infrared stimulated luminescence (IRSL) ages for the culture‐bearing sediments from the site, which place the time of occupation well within the range of Marine Isotope Stage (MIS) 3 (ca 57–26 ka). Luminescence ages were determined using the multiple‐aliquot additive‐dose technique, applied to sand‐sized potassium feldspar. Four of the six IRSL samples from the site come from the cultural deposits, while two are from the surrounding sediments. The luminescence age of the deposits implies that human occupation of the southeastern Baltic Sea region occurred at least between 50 ka and 44 ka during the first half of MIS 3 and the Middle‐Upper Paleolithic.     

System Optimisation Of Multi-Beam Aperture Synthesis Arrays For Survey Performance

Investigating the requirements for an aperture synthesis array that optimise the performance for surveying shows that, next to collecting area and system temperature, the field-of-view (FoV) is key parameter. However, the effective sensitivity not only depends on bandwidth and integration time but could be seriously limited by side lobe confusion and by gain errors that determine the effective dynamic range. From the basic sensitivity equation for a radiometric system we derive an optimum cost ratio between collecting area and processing electronics, where the latter should be less than a third of the total cost. For an instrument that has to cover a fraction of sky larger than its field-of-view, the FoV enters the equation for survey sensitivity and we identify the number of independent feed systems per unit collecting area as a key parameter. Then the optimum cost distribution allows the electronics to account for up to half the total cost. Further analysis of the sensitivity formula shows that there is an optimum design frequency for a survey instrument below 1 GHz. We discuss the impact of station size and array configuration on self-calibration, side lobe confusion and effective sensitivity and conclude that a minimum station size of 20 m diameter is required at 0.3 GHz as long as multi-patch self-calibration procedures need, per baseline, a signal-to-noise ratio of more than two for each ionospheric coherence patch.     

A search for fragmentation debris near Ursa Major Stream stars

Accretion models of planet formation and the early cratering history of the solar system suggest that planet formation is accompanied by a cloud of debris resulting from accumulation and fragmentation. A rough estimate of the infrared luminosities of debris clouds is presented for comparison with measured 10-μm luminosities of young stars. New measurements of 13 F, G, and K main-sequence stars of the Ursa Major Stream, which is thought to be about 2.7 x 10⁸ years old, place constraints on the amount of debris which could be present near these stars.     

The infrared emission bands. II. A spatial and spectral study of the Orion Bar

We have studied the spectral and spatial distribution across the Orion Bar of the 3-14 micrometers emission, including hydrogen Brackett alpha and 12.8 micrometers [Ne II] emission lines and several "dust" emission features. The data indicate that the "dust" consists of three components; (1) "classical" dust with a temperature of approximately 60 K accounting for emission longward of 20 micrometers, (2) amorphous carbon particles or polycyclic aromatic hydrocarbon (PAH) clusters (approximately 400 C atoms) which produce broad emission features in the 6-9 and 11-13 micrometers bands, and (3) free PAHs which emit in sharper bands (most strongly at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometers). The 3.3 and 11.3 micrometers features, which are due to C-H modes, are well correlated spatially, while the 7.7 micrometers band, due to C=C modes, has a different distribution than the 3.3 and 11.3 micrometers bands. We conclude that the sharp emission bands arise in the photodissociation transition region between the H II region and the molecular cloud and are not present in the H II region. The broad continuum feature extending from 11-13 micrometers is strong in both regions. Previous broad-band observations of the 10 and 20 micrometers flux distributions, which show that the 10 micrometers radiation extends farther into the neutral gas to the south than the 20 micrometers radiation, suggest that some of the 10 micrometers flux is supplied via a nonthermal mechanism, such as fluorescence.     

Quantifying the largest aggregation of giant trevally Caranx ignobilis (Carangidae) on record: implications for management

The giant trevally Caranx ignobilis (Forsskål) is an important apex predatory fish typically associated with coral reef communities. It is prized in recreational and commercial fisheries, yet little is known about its aggregation dynamics and susceptibility to fishing pressure. This study reports on a previously undocumented aggregation of mature giant trevally observed over a period of eight years (2010–2017) at Ponta do Ouro Partial Marine Reserve in southern Mozambique. The aggregation is one of the few recorded for this carangid in the western Indian Ocean and represents the first subtropical aggregation of giant trevally. The aggregation is also the largest recorded for this species, with up to 2 413 individuals representing an estimated biomass of approximately 30 tonnes. The size and predictability of this annual aggregation make it vulnerable to overexploitation and point towards the need for an appropriate conservation management strategy.     

Cost Effective Frequency Ranges For Multi-Beam Dishes, Cylinders, Aperture Arrays, and Hybrids

Five out of six Square Kilometre Array (SKA) science programs need extensive surveys at frequencies below 1.4 GHz and only four need high-frequency observations. The latter ones drive to expensive high surface accuracy collecting area, while the former ask for multi-beam receiver systems and extensive post correlation processing. In this paper, we analyze the system cost of a SKA when the field-of-view (Fov) is extended from 1 deg² at 1.4 GHz to 200 deg² at 0.7 GHz for three different antenna concepts. We start our analysis by discussing the fundamental limitations and cost issues of wide-band focal plane arrays (FPA) in dishes and cylinders and of wide-band receptors in aperture arrays. We will show that a hybrid SKA in three different antenna technologies will give the highest effective sensitivity for all six key science programs.