Geochronology of anthropogenic pollutants in riparian wetland sediments of the Lippe River (Germany)

Anthropogenic pollutants were determined in a dated sediment core, collected from a riparian wetland of the Lippe River (Ruhr district, Germany). The historical trend in heavy metals, polycyclic aromatic hydrocarbons, organochlorines, polychlorinated biphenyls and linear alkylbenzenes as well as more recent contaminants such as industrial additives, organotins, synthetic musks, methyltriclosan and some other compounds were determined for the time period between 1930 and 1986. Emission sources, information on technical production and usage, as well as on the individual pollution pathways, with appropriate environmental stability, were considered in the interpretation of the sediment contamination over the past 50 years.Contaminants were analysed and interpreted according to two different criteria: (a) the origin of the main contaminants as related to mining and industrial activities as well as municipal sewage and agricultural effluents and (b) the pollution history. Due to a significant appearance of formerly missing contaminants in sediments deposited since 1970, we suggest classifying contaminants as either common (predating 1970) or modern (postdating 1970).In summary, the study provided a comprehensive reconstruction of the pollution history of the Lippe River system.     

Perceptions of climate change in China: The research and policy connection

Global climate change has evolved from a scientific problem into an economic and political problem oI worlOwloe rater- est. National perspectives play a crucial role in addressing climate change. Mutual understanding of perspectives is nec- essary to result in rational policies and a consensus among stakeholders with divergent interests. Conceptual frameworks for understanding the problem of climate change in China, the largest developing country and the largest greenhouse gas emitter, are of great significance to national and international efforts to address the problems of climate change. Chinese perceptions of climate change as a sustainable development problem have recently been in tension with an emerging Western perspective that frames climate change as a security issue. This paper explores Chinese perceptions of climate change as expressed in recent governmental policy statements, public opinion surveys, and academic scholarship with a focus on publications in Chinese-language journals, often unfamiliar in the West. It looks at the relationship between Chinese research and policy and finds that the Chinese policy frame of climate change as a sustainable development problem draws from the body of domestic research and is reflective of the perspectives and multidisciplinary approach of Chinese researchers in areas of climate change.     

Modeling preferential flow in reactive barriers: implications for performance and design

Reactive barriers are passive and in situ ground water treatment systems. Heterogeneities in hydraulic conductivity (K) within the aquifer-reactive barrier system will result in higher flux rates, and reduced residence times, through portions of the barrier. These spatial variations in residence time will affect the treatment capacity of the barrier. A numerical flow model was used to evaluate the effects of spatial variations in K on preferential flow through barriers. The simulations indicate that the impact of heterogeneities in K will be a function of their location and distribution; the more localized the high K zone, the greater the preferential flow. The geometry of the reactive barrier will also strongly influence flow distribution. Aquifer heterogeneities will produce greater preferential flow in thinner barriers compared to thicker barriers. If the barrier K is heterogeneous, greater preferential flow will occur in thicker barriers. The K of the barrier will affect the flow distribution; decreasing the K of the barrier can result in more even distribution of flow. Results indicate that less variable flow will be attained utilizing thicker, homogeneous barriers. The addition of homogeneous zones to thinner barriers will be effective at redistributing flow only if installed immediately adjacent to both the up- and downgradient faces of the barrier.     

Applying personal carbon trading: a proposed ‘Carbon,Health and Savings System’ for British Columbia,Canada

Addressing climate change requires the synergy of technological, behavioural and market mechanisms. This article proposes a policy framework that integrates the three, deploying personal carbon trading as a key element within a policy portfolio to reduce personal carbon footprints. It draws on policy and human motivation literatures that address the behavioural changes that may be needed in the context of a long-term threat such as climate change. This proposal builds on an analysis of the British Columbia carbon tax, international examples of carbon pricing instruments and strategies for behavioural change such as social networks, loyalty management, mobile apps and gamification. Interviews were conducted with experts in financial services, energy conservation and clean technology, as well as with specialists in climate, health and taxation policy. Their input, together with a review of the theoretical literature and practical case studies, informed the proposed design of a Carbon, Health and Saving System for promoting individual engagement and collective action by linking long-term climate mitigation measures with short-term personal and social goals, including health, recreation and social reinforcement.

Policy Relevance

This article identifies areas for climate policy innovation and recommends policies that can support, promote and enable personal carbon budgeting and collective action. Although this study is focused on British Columbia, both the input provided by key opinion leaders and the proposed framework are applicable to other jurisdictions.

This policy proposal shows how personal carbon trading could work in the context of a Canadian province with an existing climate mitigation policy. It also specifies a minimum viable product approach to establishing the economic, social and technological foundations for personal carbon trading.

The Carbon, Health and Saving System identifies the technologies and stakeholders needed to implement personal carbon trading, and offers the possibility of motivating a widespread conscious human response in the event that carbon taxation proves insufficient to generate economic adaptation in a changing climate.     

A Raman spectroscopic study of H/D isotopically substituted hydrous aluminosilicate glasses

We have obtained high quality Raman spectra for two H/D isotopically substituted hydrous aluminosilicate glasses with compositions along the NaAlSi₃O₈-SiO₂ join. Consistent with the results of previous studies, the isotope shift for the band near 900 cm^–1, whose intensity grows with increasing water content, is extremely small: v _h /v _d = 1.004 ± 0.004. The lack of a definite H/D isotope shift for this band does not, however, preclude its association with a vibration of a hydrous species in the glass, because of likely strong coupling between different vibrational modes of hydrated framework species. The 900 cm^–1 band could well be due to a T — OH (T = Si, Al) stretching or bending vibration in the hydrous glass, as required by the presence of a combination band near 4500 cm^–1 in near-infrared spectra.     

Interaction between a circular opening and fractures originating from its boundary in a piecewise homogeneous plane

The complex variables boundary element method (CVBEM) is used to study interaction between a circular opening and fractures originating from its boundary in a piecewise homogeneous plane. A new complex hypersingular equation for piecewise homogeneous media with a circular opening is obtained. The equation is solved using the CVBEM technique with circular and straight boundary elements and polynomial approximations (with square root asymptotics for crack tip elements) for the unknown functions. The algorithm is verified through comparison with known semi‐analytical and numerical solutions that involve interaction between a circular opening and specific systems of cracks or other openings. New numerical results concerning the interaction of the circular opening with the cracks and circular inclusions are presented. The method is applied to an important problem in the petroleum industry: modelling propagation of hydraulic fractures in the vicinity of a borehole. Copyright © 2000 John Wiley & Sons, Ltd.     

Some basic notions in geographical synthesis

Modern geography is based on ecological thinking. In this paper some geoecological notions are discussed: the scales and levels regarding spatial magnitude and complexity, the “hierarchy” of landscape units and espcially the scale of time and the concept of the supper-imposing “stamps”. This last mentioned concept is very important in relation to the problem regarding regionalization and its possibilities. Three “stamps” are recognized: 1. the substrate, 2. the climatic conditions, 3. the human (noötic) influence. Holistic regionalization in which all elements (including the human influences) are telling to full advantage, is unsatisfactory.