Hydrochemical and Multivariate Statistical Evaluation of Heavy Metals in Shallow Alluvial Aquifers of North Brahmaputra Plain,India

The aim of this study was to display distribution and relationships of heavy elements in the unconfined, shallow alluvial aquifers of the lower Jia Bharali catchment and adjoining areas in central part of North Brahmaputra Plain (NBP), India using hydrochemical as well as multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis. The original matrix was made up of 10 trace elements (As, Cd, Cu, Co, Cr, Fe, Mn, Pb, Ni and Zn) estimated from 50 shallow alluvial dug wells in both the wet and the dry season for a duration of 3 hydrological years (2008–2011). Except As, Cu and Zn all the other toxic metals in the shallow aquifers were found exceeding the WHO maximum permissible limits for drinking water. PCA extracted five varimax factors as geogenic, agricultural and anthropogenic explaining about 71.2% of the total variance in the wet season and 69.3% total variance in the dry season. Hierarchical cluster analysis classified the dug wells into two groups in the wet season and three groups in the dry season with respect to the heavy elements. The results emphasized the need for routine monitoring and management in order to avoid contamination of groundwater sources in the NBP with respect to the dissolved trace elements.     

Improvement of the geoid in local areas by satellite gradiometry

Summary Satellite gradiometry is studied as a means to improve the geoid in local areas from a limited data coverage. Least-squares collocation is used for this purpose because it allows to combine heterogeneous data in a consistent way and to estimate the integrated effect of the attenuated spectrum. In this way accuracy studies can be performed in a general and reliable manner. It is shown that only three second-order gradients contribute significantly to the estimation of the geoidal undulations and that it is sufficient to have gradiometer data in a 5°×5° area around the estimation point. The accuracy of the geoid determination is strongly dependent on the degree and order of the reference field used. An accuracy of about ±1 m can be achieved with a reference field of (12, 12). There is an optimal satellite altitude for each reference field and this altitude may be higher than 300 km for a field of low degree and order. The influence of measuring errors is discussed and it is shown that only gradiometer data with accuracies better than ±0.05 E will give a significant improvement of the geoid. Finally, some results on the combination of satellite gradiometry and terrestrial gravity measurements are given. The proposed method seems to be well suited for local geoid determinations down to the meter range. It is especially interesting for unsurveyed and difficult areas because no terrestrial measurements are necessary. Furthermore, it has the practical advantage that only a local data coverage is needed.     

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.     

The southern cape conductive belt (South Africa): Its composition, origin and tectonic significance

Magnetometer array studies have led to the discovery and mapping of the Southern Cape Conductive Belt (SCCB) crossing the southern tip of Africa from west to southeast coasts. The SCCB lies just south of the Namaqua-Natal Belt of cratonic rocks remobilized about 1000 m.y. B.P. It is shown that it coincides with a zone of weakness which has been exploited by three major geosynclinal accumulations over some 600 m.y. Relationships between the SCCB and the basement geochronology, geology and tectonics are considered in detail. These relationships support the view that the conductive belt was formed by an accumulation of marine sediments and oceanic lithosphere at the top of a Proterozoic subduction which stopped about 1000 to 800 m.y. B.P. Associated with this subduction we propose a Proterozoic range of Andean mountains, whose roots are now exposed in the Namaqua-Natal Belt. Later subduction further south, near the present south coast, is proposed to account for the intrusion, between the south coast and the SCCB, of the Cape Granites in the time interval 600-500 m.y. B.P. There is some evidence for a third, yet more distant, subduction episode off Permian Gondwanaland. After outlining this tectonic history, the paper turns to a closer examination of the hypothesis that the Southern Cape Conductive Belt consists of partly serpentinized basalt accumulated at the top of a Proterozoic subduction. A large static magnetic anomaly, which correlates with the SCCB over most of its length, is well fitted by a model which strongly supports this hypothesis. Bouguer gravity anomalies along western and central profiles likewise support the hypothesis. A discussion follows of the process of formation of the proposed block of serpentinized marine rocks, beginning with serpentinization of the crust near oceanic ridges by reaction of warm, porous, newly-extruded basalt with seawater convecting through it. The serpentinized basalt is stable at crustal temperatures and pressures and so is transported in the seafloor until it reaches a subduction, where it accumulates because of its low density. Examples of such accumulations are cited. Finally, it is shown that any iron in the olivine and pyroxene in the original basalt precipitates, when these silicates are hydrated to serpentine, as magnetite which is the dominant mineral conferring high electrical conductivity and high magnetic susceptibility on serpentinites. In particular the Beattie static magnetic anomaly requires, in our model calculation, a very high susceptibility readily attainable in basalt at 15–20% serpentinization. The authors know of no other rock able to provide this high susceptibility. A similar percentage of serpentinization provides the density required to model the gravity anomalies.     

A direct comparison of C and Th ages at Searles Lake, California

Thorium-230 dating on saline of the Lower Salt unit in pluvial Searles Lake, California, shows that this unit was formed between 24,500 and 32,000 years ago. The initial apparent ¹⁴C age of the lake is estimated to be about 900 years. After correcting for nonradiogenic ²³⁰Th and for the initial ¹⁴C age, excellent agreement between ²³⁰Th and ¹⁴C ages is obtained. The reliability of ²³⁰Th dating on salt deposit opens a new way for continuation of absolute chronology below the Lower Salt in Searles Lake.     

Late Cainozoic stratigraphy,palaeomagnetic chronology and vegetational history from Lake George,N.S.W.

The sedimentary record from Lake George provides the longest relatively continuous Quaternary continental sequence yet available from Australia, and may record one of the longest Upper Cainozoic lacustrine records in the world.

Palaeomagnetic analysis of a 36 m core from the lake floor identifies a sequence of deposition extending through the Brunhes and Matuyama, to the Gauss magnetic Chron. A longer core from the same site, but with incomplete recovery, extends to 72 m in lacustrine sediment; the age of the base of this core estimated by extrapolation is between 4.2 and 7 Ma. As there are still older and deeper sediments in the basin, extending to an estimated depth of 134 m, the age of the tectonic formation of the Lake George basin must be reckoned as Middle Miocene or older.

The pattern of facies organisation through time demonstrates a phase of deep water deposition extending from the base of the cored sequence (72 m) up to 51.5 m, at which time a major change took place. A disconformity developed at this level, associated with a period of deep weathering and a prolonged phase of slope mantle deposition (from 51.5 to 30.8 m). A gradual return to lacustrine environments, with diminishing proportion of slope wash detritus, resulted in increased rates of deposition coincident with the Jaramillo Subchron at 21.5 m. Thereafter, throughout the Brunhes magnetic Chron, lacustrine conditions dominated, varying from deep to lake dry conditions in a rhythmic fashion, and reflecting the major climatic oscillations of the past 700 000 years, becoming more regular in the past 400 000 years.

The pollen analytical record of the upper 8.6 m, covering the last 350 000 years, provides the main framework for the reconstruction of climatic history. The pollen and algal records indicate a sequence of vegetation and lake level changes, in which four major glacial/interglacial cycles are correlated with stages 1 to 10 of the ¹⁸0 marine record. This provides by far the longest continuous biostratigraphic framework for the Quaternary period in Australia.

Comparison between the palaeoclimatic record and the lake level evidence shows that there is no simple correlation between the lake level fluctuations and the glacial/ interglacial oscillations. In fact, major falls in the lake level occured both at the peak of cold glacials and during the warm interglacials. Though the falls in the lake levels during a warm period (interglacial) can be explained by high rates of evaporation, drying during maximum cold can be explained best in terms of a fall in precipitation. Permanent to deep‐lake conditions generally occurred during intermediate cool periods following warm intervals, when perhaps the seas were still warm and low rates of evaporation on land prevailed. On the other hand, short periods of shallow to deep lake levels also occurred during warm (interglacial) periods, showing that these were associated with reasonably high rates of precipitation.     

RURAL ADDRESSING AND COMPUTER MAPPING IN NEW MEXICO

Specifying the location of a rural residence is a common geographic problem. Most addressing systems are designed for urban areas and are not applicable to rural areas. The mile marker addressing system meets all of the requirements for a rural addressing system. With the addition of computer mapping techniques, rural addressing can be done efficiently and can provide the basis for a county's computer mapping system. Projects in New Mexico provide several examples of computerized rural addressing projects.