The migration of fluid-filled grain boundaries in recrystallizing synthetic bischofite: first results of in-situ high-pressure, high-temperature deformation experiments in transmitted light

The effect of fluids on recrystallization behaviour is well known; however, the detailed microscale distribution of fluid in grain boundaries and the influence of fluid on grain boundary migration are still unresolved. In this study, in‐situ deformation experiments in transmitted light microscopy were undertaken, as this allows continuous and direct observation of the whole range of processes involved in fluid‐assisted grain boundary migration. A new see‐through deformation apparatus was developed to enable the control of fluid pressure. Bischofite containing small amounts of aqueous fluid was deformed at temperatures between 50 and 90 °C, over a range of fluid pressure from 0.5 to 1 MPa, and strain rates of 5 × 10^?6 to 1 × 10^?4 s^?1. The rates of grain boundary migration were measured at different temperatures and strain rates. Detailed observations during and after the deformation illustrate the evolution of migrating fluid‐filled grain boundaries and show that the incorporation of fluids from inclusions as well as their pinch‐off is dependent on the grain boundary velocity, the thickness of the grain boundary and the size and shape of the inclusions. Direct evidence is presented for the contraction of the grain boundary fluids into isolated inclusions after equilibrium conditions are attained.     

Morphological and microtectonic analysis of Quaternary deformation from Puná and Santa Clara Islands, Gulf of Guayaquil, Ecuador (South America)

This paper presents the neotectonic study of Santa Clara and Puná Islands sited in the Gulf of Guayaquil eastern part. Both islands are located on the south-western segment of the fault zone bounding to the east the North Andean Block. Fault motion and morphostructural analysis were carried out from Pleistocene age terrain. A two step deformation characterises the South Puná tectonics. The first step involves the Zambapala Cordillera uplift that post-dates Pleistocene sediments and pre-dates a marine terrace correlated with the M.I.S. 11 or 13 (440–550 ka). The second step is the formation of a pull-apart that shows evidence of 2.9 km dextral offset since the M.I.S. 11 or 13, giving an offset mean rate of 5.3 to 6.6 mm/yr. This rate is higher than the one calculated on the Pallatanga Fault northeast of the study area, in the Western Andean Cordillera, suggesting that deformation is split in different fault segments from the Gulf of Guayaquil to the continent. The Zambapala Cordillera uplift and transpression deformation requires a compressive event that may have been induced by the subduction process during the early Pleistocene.     

Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

Electrodialytic remediation of CCA-treated waste wood in pilot scale

When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m³ wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Continental rift systems and anorogenic magmatism

Precambrian Laurentia and Mesozoic Gondwana both rifted along geometric patterns that closely approximate truncated-icosahedral tessellations of the lithosphere. These large-scale, quasi-hexagonal rift patterns manifest a least-work configuration. For both Laurentia and Gondwana, continental rifting coincided with drift stagnation, and may have been driven by lithospheric extension above an insulated and thermally expanded mantle. Anorogenic magmatism, including flood basalts, dike swarms, anorthosite massifs and granite-rhyolite provinces, originated along the Laurentian and Gondwanan rift tessellations. Long-lived volcanic regions of the Atlantic and Indian Oceans, sometimes called hotspots, originated near triple junctions of the Gondwanan tessellation as the supercontinent broke apart. We suggest that some anorogenic magmatism results from decompression melting of asthenosphere beneath opening fractures, rather than from random impingement of hypothetical deep-mantle plumes.     

A review of the occurrence, form and origin of C-bearing species in the Khibiny Alkaline Igneous Complex, Kola Peninsula, NW Russia

The Khibiny Complex hosts a wide variety of carbon-bearing species that include both oxidized and reduced varieties. Oxidised varieties include carbonate minerals, especially in the carbonatite complex at the eastern end of the pluton, and Na-carbonate phases. Reduced varieties include abiogenic hydrocarbon gases, particularly methane and ethane, dispersed bitumens, solid organic substances and graphite. The majority of the carbon in the Khibiny Complex is hosted in either the carbonatite complex or within the so-called “Central Arch”. The Central Arch is a ring-shaped structure which separates khibinites (coarse-grained eudialite-bearing nepheline-syenites) in the outer part of the complex from lyavochorrites (medium-grained nepheline-syenites) and foyaites in the inner part. The Central Arch is petrologically diverse and hosts the major REE-enriched apatite–nepheline deposits for which the complex is best known. It also hosts zones with elevated hydrocarbon (dominantly methane) gas content and zones of hydrothermally deposited Na-carbonate mineralisation. The hydrocarbon gases are most likely the product of a series of post-magmatic abiogenic reactions. It is likely that the concentration of apatite-nepheline deposits, hydrocarbon gases and Na-carbonate mineralisation, is a function of long lived fluid percolation through the Central Arch. Fluid migration was facilitated by stress release during cooling and uplift of the Khibiny Complex. As a result, carbon with a mantle signature was concentrated into a narrow ring-shaped zone.     

The lower marine to lower freshwater Molasse transition in the northern Alpine foreland basin (Oligocene; central Switzerland–south Germany): age and geodynamic implications

The Wilhelmine Alpe section near Immenstadt (Allgäu, south Germany), which represents one of the best continuously exposed outcrops within the northern Alpine foreland basin, has been analyzed for magnetostratigraphic and palynostratigraphic signals. The section comprises the marine-to-terrestrial transition from Lower Marine (UMM) to Lower Freshwater Molasse (USM) sediments. Based on the correlation of the local magnetic pattern with the geomagnetic polarity timescale (GPTS) and palynostratigraphic data, an age of about 31 Ma is suggested for the UMM–USM transition in the Wilhelmine Alpe section. A comparison with coeval magnetostratigraphic sections from central and eastern Switzerland indicates that the regression of the UMM sea along the southern margin of the Molasse basin occurred strongly heterochronously between 31.5 and 30 Ma. The heterochroneity is attributed to the deposition of fan-delta and alluvial fan sediments which document that the overall marine conditions during the UMM were accompanied by strong clastic input derived from the rising Alps. This clastic contribution had a much stronger influence on the depositional pattern than previously thought.     

Formation of the accretion disk in the SS 433 system with explicit radiative cooling,convective heat conduction,and radiation pressure

The paper continues three-dimensional hydrodynamical computations of the formation of an accretion disk in the SS 433 system, taking into account radiative cooling explicitly, convective thermal conductivity, and radiation pressure. The computational results show that the powerful, broad flow forms an optically thick accretion disk with a gas density of 10¹²–10¹⁴ cm^?3, a temperature of 15000–35 000 K, a radius of about 0.3, and a height of 0.2–0.3 (in units of the component separation). Spiral shocks form in the disk, and a narrow conelike cavity (tunnel) forms at the center. In this tunnel, gas is accelerated to relativistic speeds, leaving the system in the form of narrow jets.