Comparative analysis of anthropogenic impact on water resources in Russia,Belarus, and Ukraine in the post-soviet period

Anthropogenic impacts on water resources in Russia, Ukraine, and Belarus after the collapse of the Soviet Union are considered. Estimates of water consumption and its dynamics since 1990 are given. Current changes in the state of water resources are characterized. Differences in the efficiency of water consumption in the countries under consideration are demonstrated.     

A nested rediscretization method to improve pathline resolution by eliminating weak sinks representing wells

This paper discusses a method for overcoming the problem of weak sinks representing wells that result from spatial discretization effects when using MODPATH, the particle-tracking postprocessor for the ground water flow model MODFLOW. Weak sink cells are model cells that represent a well that does not discharge at a sufficiently large rate to capture all of the flow entering the cell; therefore, flowpaths within these cells cannot be uniquely defined because it is impossible to know whether a given water particle discharges to the well or passes through the cell. Creating a submodel of the well cell by using the nested rediscretization method can eliminate this ambiguity by converting the weak sink cell into a strong sink cell. The method is designed to be run manually for each well and for steady-state conditions. Other advantages, disadvantages, technical considerations, and limitations of the method are presented. Software created for the method consists of five Fortran programs that are operated using a set of instructions. A practical application of the method is presented by using an example wellhead-protection problem that demonstrates that nested rediscretization can provide more accurate particle-tracking results than those obtained by using a coarsely discretized model alone.     

Initiation of a multiple peat slide on Cuilcagh Mountain,Northern Ireland

In October 1998 a multiple peat slide occurred on the northern slopes of Cuilcagh Mountain, Co. Fermanagh, in response to a high‐magnitude rainfall event. Few peat slides have been recorded in Ireland, and a detailed field survey and investigation of the failure was undertaken within four weeks of the event. The morphological evidence indicated a distinct sequence of events which appeared to begin with the failure of a small segment of slope above a degraded transverse drainage ditch which was cut less than ten years previously. This segment of slope was no more than 42 m wide and 25 m long, with 0·7 m of peat overlying up to 0·5 m of a pale coloured clay, the latter containing small pipes and resting on the surface of a darker coloured loamy material. The failure surface was located at or near the base of the pale clay layer. Finite element software was used to model hydrological conditions within the upper segment of slope and to calculate factors of safety for different slope configurations including the presence or absence of a drain or a subsurface pipe. Using the peak shear strength of the pale clay, as determined in the laboratory, both the drain and subsurface pipes were required to obtain a factor of safety of 1·0 or less. Allowing for the uncertainties associated with the hydrological modelling of the pipes, it is suggested that the cutting of the drain and the hydrological impacts of its subsequent degradation are ultimately responsible for the failure. Copyright © 2001 John Wiley & Sons, Ltd.     

Physiological Responses of Five Seagrass Species to Trace Metals

Trace metal run-off associated with urban and industrial development poses potential threats to seagrasses in adjacent coastal ecosystems. Seagrass from the largest urban (Moreton Bay) and industrial (Port Curtis) coastal regions in Queensland, Australia were assessed for metal concentrations of iron (Fe), aluminium (Al), zinc (Zn), chromium (Cr) and copper (Cu). Trace metal concentrations in seagrass (Zostera capricorni) leaf and root-rhizome tissue had the following overall trend: [Fe] > [Al] > [Zn] > [Cr] > [Cu]. Rainfall events and anthropogenic disturbances appeared to influence metal concentrations in seagrasses with the exception of Al, which does not appear to bioaccumulate. In laboratory experiments, five seagrass species (Halophila ovalis, H. spinulosa, Halodule uninervis, Z. capricorni, Cymodocea serrulata) were incubated with iron (1 mg Fe l⁻¹) and copper (1 mg Cu l⁻¹) and responses assessed by changes in PSII photochemical efficiency (Fv/Fm), free amino acid content and leaf/root-rhizome metal accumulation. Iron addition experiments only affected Halophila spp, while copper additions affected other seagrass species as well. Trace metal contamination of seagrasses could have ramifications for associated trophic assemblages through metal transfer and seagrass loss. The use of photosystem II photochemical efficiency as well as amino acid concentrations and composition proved to be useful sublethal indicators of trace metal toxicity in seagrasses.     

Elastic fields in two joined transversely isotropic media of infinite extent as a result of rectangular loading

This paper presents the closed‐form solutions for the elastic fields in two bonded rocks induced by rectangular loadings. Each of the two bonded rocks behaves as a transversely isotropic linear elastic solid of semi‐infinite extent. They are completely bonded together at a horizontal surface. The rectangular loadings are body forces along either vertical or horizontal directions and are uniformly applied on a rectangular area. The rectangular area is embedded in the two bonded rocks and is parallel to the horizontal interface. The classical integral transforms are used in the solution formulation, and the elastic solutions are expressed in the forms of elementary harmonic functions for the rectangular loadings. The stresses and displacements in the rocks induced by both the horizontal and vertical body forces are also presented. The numerical results illustrate the important effect of the anisotropic bimaterial properties on the stress and displacement fields. The solutions can be easily implemented for numerical calculations and applied to problems encountered in rock mechanics and engineering. Copyright © 2011 John Wiley & Sons, Ltd.     

Sea water basalt interaction in spilites from the Iberian Pyrite Belt

Low grade hydrothermally metamorphosed mafic rocks from the Iberian Pyrite Belt are enriched in ¹⁸O relative to the oxygen isotopic ratio of fresh basalt (+6.5±1). The observed ¹⁸O whole rock values range from +0.87 to +15.71 corresponding to positive isotopic shifts of +5 to +10, thus requiring isotopic exchange with fluids under conditions of high water:rock ratios at low temperatures. The lowest ¹⁸O observed corresponds to an albitized dolerite still and is compatible with independent geochemical data suggesting lower water: rock ratios for the alteration of these rocks.The isotope data are consistent with the hypothesis that the spilites from the Pyrite Belt were produced by interaction of basaltic material with sea water.Significant leaching of transition metals from the mafic rocks during alteration coupled with available sulphur isotopic data for the sulphide ores also suggest that sea water may have played an important role in the formation of ore deposits in the Iberian Pyrite Belt.     

Interpreting tracer breakthrough tailing in a conduit-dominated karstic aquifer

Breakthrough tailing has been observed during dye-tracing recovery tests in the Norville aquifer system (chalk), France. Karst-conduit flow and transport parameters were assessed using two different interpretative methods: the linear graphical method and the Chatwin method (implemented in the Qtracer2 program). The linear graphical method was used to model the observed tailing effects, which was explained by a second smaller delayed breakthrough curve. By comparing the results of tracer-test interpretation for the two methods, it was possible to relate the area of this second curve to the importance of turbulent flow in spring discharge. The more turbulent the flow, the less important the contribution of the second breakthrough curve and the tailing effect. The observed tailing could possibly be controlled by hydrodynamics to a greater extent than usually expected, the tailing effects being mostly attributed to diffusion phenomena. Tailing effects were expected to increase with discharge and the piezometric level, which would have resulted in overpressure in conduits, fissure flooding, etc. Instead, breakthrough tailing tended to disappear with increasing aquifer discharge, which would support the hypothesis of there being mostly hydrodynamic-controlled tailing effects instead of matrix- or fissure-diffusion.An erratum to this article can be found at     

The isotopic composition and concentration of Ag in iron meteorites and the origin of exotic silver

The isotopic composition of Ag and the concentration of Ag and Pd have been determined in Canyon Diablo (IA), Grant (IIIB), Hoba, Santa Clara, Tlacotepec and Warburton Range (IVB), Piñon and Deep Springs (anom.). Troilite from Grant and Santa Clara have also been analyzed. All of these meteorites, with the exception of Canyon Diablo, give ${}^{107}\text{Ag}{}^{109}\text{Ag}$ in the metal phase that is greater than the terrestrial value with the enrichments of ¹⁰⁷Ag ranging from ~2% to 212%. These data show that Ag of anomalous isotopic composition is common to all IVB and anomalous meteorites. The results on Grant suggest that the anomalies may be widespread including more common meteorite groups. There is a general correlation of ${}^{107}\text{Ag}{}^{109}\text{Ag}$ with $\text{Pd}\text{Ag}$ except for the data from FeS of Santa Clara. It is concluded that the excess ¹⁰⁷Ag is the result of decay of ¹⁰⁷Pd, a nuclide that is extinct at present with an abundance of ${}^{107}\text{Pd}{}^{108}\text{Pd}$ of about 3 × 10^?5. The troilite in Grant exhibits normal ${}^{107}\text{Ag}{}^{109}\text{Ag}$ to within errors, a high Ag concentration and a low ratio of ${}^{108}\text{Pd}{}^{109}\text{Ag}$ ~0.17. Grant metal has ${}^{107}\text{Ag}{}^{109}\text{Ag}$ that is ~2% greater than normal and a high ratio of ${}^{108}\text{Pd}{}^{109}\text{Ag}$ ~ 10³. The data from Grant appear to represent a ¹⁰⁷Pd-¹⁰⁷Ag isochron and indicate that the cooling rate at elevated temperatures was sufficiently rapid to preserve substantial isotopic differences between metal and troilite. Troilite in Santa Clara was found to contain Ag with a very high ${}^{107}\text{Ag}{}^{109}\text{Ag}$ ratio (108% above normal), an Ag concentration only a factor of three above the metal and a high value of ${}^{108}\text{Pd}{}^{109}\text{Ag}$ ~1.3 × 10⁴. The troilite has a higher ${}^{107}\text{Ag}{}^{109}\text{Ag}$ than the metal. These data are not compatible with a simple model of in situ decay and subsequent local Ag redistribution between metal and troilite during cooling. These data suggest that Ag in Santa Clara and possibly other IVB meteorites is made up of almost pure ¹⁰⁷Ag produced from ¹⁰⁷Pd decay and ¹⁰⁹Ag produced by nuclear reactions with only a small amount of “normal” Ag. This indicates an intense energetic particle bombardment history in the early solar system (~10²⁰ p/m²) which occurred after the formation of small planetary bodies. We infer that a T-Tauri activity by the early sun contributed to some late stage “nucleosynthesis” and the heating of a dust cloud. In addition, implications on the early thermal evolution of iron meteorites are presented based on ¹⁰⁷Pd decay and models of the cooling history.