Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

The stratigraphy of Ordovician volcanic rocks on the southern and eastern flanks of the Harlech Dome in Merionethshire

The stratigraphy of nine areas of Ordovician volcanic rocks flanking the Harlech Dome is dcscribed and a correlation of the Ordoyician volcanic succession from Arenig to Cader Idris proposed. Nine formations are distinguished which together form a distinct lithostratigraphic unit termed the Aran Volcanic Group. At least six disconformities can bc recognised within the Group.     

Beobachtungsergebnisse der Berliner Arbeitsgemeinschaft für veränderliche Sterne e. V. (BAV)

In this 8th compilation, the following results of observations are given: 207 observed minima of 56 eclipsing binaries, 100 maxima of 21 RR Lyrae- and δ Cephei-stars, 82 results of 32 Mira stars and long period variables, and 47 results of 9 RV Tauri stars, semiregular, and irregular variables, from the years 1966 up to 1968.     

The ordovician and other post-rosslare series Rocks in Southeast Co. Wexford

Ordovician sediments at Tagoat and Rosslare Harbour are re-described and their relationship to the underlying Rosslare Series discussed. A brief outline of their petrology is given, but it is shown that the fauna is in need of revision before reliable correlations can be made. Similar rocks are recorded near Tomhaggard; amongst these, spotted mudstones imply Ordovician or later intrusions. Undeformec dykes intrusive into the Rosslare Series are believed to be representatives of this phase.     

Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.