Amino acid nitrogen in atmospheric aerosols: Occurrence,sources and photochemical modification

The presence of amino acids in atmospheric precipitation and aerosols has been noted for many years, yet relatively little is known about these or other nitrogen containing organic compounds in the atmosphere. Marine and continental rainwater analyses indicate that atmospheric aerosols, and subsequently atmospheric precipitation, may contain substantial levels of free and combined amino acids. The most likely source of amino N in the remote marine atmosphere appears to be the injection of proteinaceous material through the action of bursting bubbles at the sea-air interface or the long range transport from terrestrial sources. The capacity of these substrates to undergo photooxidation and photodegradation in the atmosphere to simpler species, such as ammonium ions, carboxylic acids, and for the S containing amino acids, oxidized forms of sulfur, has received little attention from atmospheric chemists. The photochemistry of covalently bound amino groups, particularly as found in peptides and amino acids, is discussed here with the purpose of summarizing what is known of their occurrence and their possible importance to atmospheric chemistry.     

Structure and collapse of three-dimensional magnetic neutral points

Abstract

The structure and collapse of linear three-dimensional magnetic neutral points is studied by varying the four parameters (p, q,j_|,j_⊥ ) that define, in general, the linear field of a neutral point. The effect of these parameters on both the skeleton structure (i.e. the fan and spine) and the actual field line structure of the null is considered. It is found that one current component (j_⊥ ) causes the skeleton structure of the null to fold up from its potential state, whereas the other current component (j _|;) causes the field lines to bend. The two other parameters (p,q) determine the potential structure of the null and cause the null to transform from a three-dimensional null to a two-dimensional null and from a positive (type B) null to a negative (type A) null.

To investigate the collapse of three-dimensional nulls, solutions to the linear, low-β ideal magnetohydrodynamic equations are found. It is found that three-dimensional null points can collapse if the field line foot-points are free and energy can propagate into the system.     

Efficacy of Selected Compounds on Thermocyclops oblongatus,one of the Main Intermediate Hosts of Guinea Worm in Africa

Ten selected compounds were tested on Thermocyclops oblongatus to determine their ability to be used for treatment of drinking water sources. None were shown to be interesting for individual application in household water tanks. Tested compounds, such as potassium permanganate or chlorine-releasing products, were ineffective or affected dramatically the taste or colour of the water. For collective application in water sources, temephos appeared to be the most valuable pesticide because it was effective against cyclops and harmless for environment. Other pesticides should be proposed as substitutes in case of cyclops resistance to temephos.     

Inverse analysis of deformation mechanism by geodetic surveys−a case study

In 1988 two large earthquakes with magnitude of Ms 7.6 and Ms 7.2 occurred in Lancang-Genma area, Southwest China. This paper discusses the determination of the spatial distribution of fault slip caused by the earthquakes using geodetic surveys. The prior information obtained from geological surveys and seismological investigations was used to determine the geometry of the fault plane and the average fault slip. The smooth constraints on the fault slips have been described by a normal distribution with hyperparameters, which are incorporated in the inversion analysis with a Bayesian model. Akaike’s Bayesian Information Criterion (ABIC) is used to get the optimal values of hyperparameters. Once the hyperparameters are determined, the maximum likelihood method is employed to estimate the patterns of a fault slip. Based on the results of inverse analysis monitoring geodetic surveys can be properly designed and conducted to obtain crust deformations and predict potential earthquake sources.     

Mean wind-direction shear through a forest canopy

The equations of motion applying to the wind field in a forest canopy are simplified to a balance between the shearing stress gradient and either the form-drag of the leaves in the upper dense canopy, or the overall horizontal pressure gradient in the more open space beneath. The equations imply that, in descending through the forest, the stress and wind vectors turn through an angle which depends on the forest characteristics and on the stability and the speed of the airflow above the forest. The turning is roughly confirmed by an overall average measured on a very flat site near Thetford, Norfolk, covered by an extensive uniform pine forest.     

Transformations of mercury, iron, and sulfur during the reductive dissolution of iron oxyhydroxide by sulfide

Methylmercury can accumulate in fish to concentrations unhealthy for humans and other predatory mammals. Most sources of mercury (Hg) emit inorganic species to the environment. Therefore, ecological harm occurs when inorganic Hg is converted to methylmercury. Sulfate- and iron-reducing bacteria (SRB and FeRB) methylate Hg, but the effects of processes involving oxidized and reduced forms of sulfur and iron on the reactivity of Hg, including the propensity of inorganic Hg to be methylated, are poorly understood. Under abiotic conditions, using a laboratory flow reactor, bisulfide (HS⁻) was added at 40 to 250 μM h⁻¹ to 5 g L⁻¹ goethite (α-FeOOH) suspensions to which Hg(II) was adsorbed (30-100 nmol m⁻²) at pH 7.5. Dissolved Hg initially decreased from 10³ or 10⁴ nM (depending on initial conditions) to 10⁻¹ nM, during which the concentration of Hg(II) adsorbed to goethite decreased by 80% and metacinnabar (β-HgS_(s)) formed, based on identification using Hg L_III-edge extended X-ray absorption fine structure (EXAFS) spectroscopic analysis. The apparent coordination of oxygens surrounding Hg(II), measured with EXAFS spectroscopy, increased during one flow experiment, suggesting desorption of monodentate-bound Hg(II) while bidentate-bound Hg(II) persisted on the goethite surface. Further sulfidation increased dissolved Hg concentrations by one to two orders of magnitude (0.5 to 10 nM or 30 nM), suggesting that byproducts of bisulfide oxidation and Fe(III) reduction, primarily polysulfide and potentially Fe(II), enhanced the dissolution of β-HgS_(s) and/or desorption of Hg(II). Rapid accumulation of Fe(II) in the solid phase (up to 40 μmol g⁻¹) coincided with faster elevation of dissolved Hg concentrations. Fe(II) served as a proxy for elemental sulfur [S(0)], as S(0) was the dominant bisulfide oxidation product coupled to Fe(III) reduction, based on sulfur K-edge X-ray absorption near edge structure (XANES) spectroscopy. In one experiment, dissolved Hg concentrations tracked those of all sulfide species [S(-II)]. These results suggest that S(-II) reacted with S(0) to form polysulfide, which then caused the dissolution of β-HgS_(s). A secondary Fe-bearing phase resembling poorly formed green rust was observed in sulfidized solids with scanning electron microscopy, although there was no clear evidence that either surface-bound or mineralized Fe(II) strongly affected Hg speciation. Examination of interrelated processes involving S(-II) and Fe(III) revealed new modes of Hg solubilization previously not considered in Hg reactivity models.     

Low-angle reflectivity modeling of land clutter

In this letter, a practical mean reflectivity model of radar land clutter (LC) for the complex system design of ground-based radars involved in low-angle targets on some typical terrains is studied using the inductive reasoning method. The functional relationships between the radar parameters and radar surface clutter backscattering are analyzed. Following the recent research work in the area of reflectivity modeling of LC in the literature, the least squares method is employed to estimate the model parameters. The model is validated using reliable practical data and shown to outperform other models in accuracy.