A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...     

Numerical Modeling of the Observed Wiechert Seismograph Magnification

—The paper presents results of experiments designed to measure the actual dynamic magnification of the Wiechert 1000 kg horizontal seismometer when excited by seismic waves. This is accomplished by comparing 51 digital records of seismic events recorded by the Wiechert and a well calibrated reference seismometer. The results obtained indicate that the magnification of the Wiechert seismometer is influenced by the interaction of its mass and frame, especially for high frequencies. This interaction has been modeled by considering a system of two coupled pendulums, yielding a theoretical dynamic magnification curve which exhibits main features of the observed magnification. The dis crepancy between the nominal and the actual response of the Wiechert seismograph may lead to errors in studies involving spectral analyses of recorded seismograms, and to overestimation of local earth quake magnitudes.     

Formation Mechanism of Mud Bank Along the Southwest Coast of India

Mud bank formation during the southwest monsoon along the southwest coast of India remains an enigma to the researchers and coastal community in spite of several earlier studies. The present study attempts to unravel the mystery through a high-frequency, season-long time-series observation at Alappuzha, located at the southern part of the west coast of India, a region of frequent occurrence of mud bank. Using 7-month-long weekly time-series observation, we identified strong winds and high waves associated with onset of the southwest monsoon and subsequent three episodic atmospheric low-pressure events (LPEs).With the help of in situ time-series data, we show that the strong winds and high waves associated with southwest monsoon pre-conditions the near shore bottom sediment to bring it into suspension. The high amplitude waves associated with the southwest monsoon, while propagating from the deep water to shallow water region, interact with the bottom initiating bottom-sediment movement and its suspension due to wave refraction and shoaling. The sporadic occurrence of the atmospheric LPEs enhances the process of suspension of bottom sediment in the near shore region leading to the formation of fluid mud. Simulations with a cohesive sediment transport model yielded realistic estimates of sediment transport, in the presence of an onshore current, a pre-requisite for transporting the fluid mud toward the coast. The prevailing onshore upwelling current during the southwest monsoon provides the favorable pre-requisite conditions for transporting the fluid mud through depression channel network towards the coast. Once sufficient quantity and thickness of fluid mud is accumulated in the near shore region, it acts as a wave damper for subsequent high monsoon waves, as indicated by the time-series wave data, leading to the formation of tranquil mud bank region. Depression channel networks extending from the shelf to the coast off Alappuzha, Kochi, Ponnani, Beypore, and Ullal were found in the bathymetric charts, thus explaining why mud banks occur only at few locations in spite of the prevalence of similar monsoon conditions.     

Geotechnical assessment of the bearing capacity of coal mine floors

Summary This investigation concerns 3 longwall faces having variable strata and mining conditions, but supported by 202 tonnes hydraulic 6-leg chocks. Bearing capacity tests along the faces were conducted to evaluate the factors influencing floor deformation and failure. The effect of size, shape and perimeter of the base plates, thickness of the floor layer, time and moisture on the ultimate bearing capacity of the floor was measured and discussed. Application of this work is the prediction of stability and support performance of face ends, as well as the design of support systems and ground control on production faces.     

Climatic response of thick leaf spruce (Picea crassifolia) tree-ring width at different elevations over Qilian Mountains, northwestern China

Tree-ring cores of thick leaf spruce (Picea crassifolia) taken from four sites at different elevations, in the middle of the Qilian Mountains, in the arid and semi-arid region of northwestern China, were used to develop four tree-ring width chronologies using standard dendrochronological methods. Results indicate that with increasing altitude the chronologies’ year-to-year variations decreased. Hence, the sensitivity of the tree-ring chronologies to climate decreases with altitude. Further analysis showed that the significant limiting factor on tree growth is spring precipitation. Measurements of stomata density and leaf dry weight suggest the species’ ecological adaptation strategy changes with elevation. At high elevation the metabolic rate of thick leaf spruce decreases, thus showing the effect of the climate.     

The Nootka Fault Zone — a new plate boundary off western Canada

Summary. Relative motion across a boundary between the main Juan de Fuca plate and its northern extension, the Explorer plate, had earlier been suggested from sea-floor magnetic anomaly analysis and from earthquakes recorded on the western Canada land seismic network. The location of the boundary, called the Nootka fault zone, and the motion across it have been examined through seismic reflection profiles, accurate location of earthquakes with an array of ocean bottom seismometers and through analysis of magnetic, gravity and bathymetric data. The fault zone extends from a ridge-fault—fault triple point at the northern end of the Juan de Fuca ridge to a fault—trench—trench triple junction at the margin off north-central Vancouver Island. The active portion of the fault zone is about 20 km wide, and has produced extensive disturbance in the 0.5 to 1 km of overlying sediments. Magnetic anomaly analysis suggests present left-lateral strike slip motion of about 3 cm/yr, with convergence at the margin being more rapid to the south than to the north of the fault zone. Because of rapidly changing spreading parameters on the Explorer and Juan de Fuca ridges over the past 5 Myr the Nootka fault zone has had a very complex history.     

An expanded surface-water palaeotemperature inference model for use with fossil midges from eastern Canada

Using an expanded surface sample data set, representing lakes distributed across a transect from southernmost Canada to the Canadian High Arctic, a revised midge-palaeotemperature inference model was developed for eastern Canada. Modelling trials with weighted averaging (with classical and inverse deshrinking; with and without tolerance downweighting) and weighted averaging partial least squares (WA-PLS) regression, with and without square-root transformation of the species data, were used to identify the best model. Comparison of measured and predicted temperatures revealed that a 2 component WA-PLS model for square-root transformed percentage species data provided the model with the highest explained variance (r =0.88) and the lowest error estimate (RMSEP _jack =2.26 °C). Comparison of temperature inferences based on the new and old models indicates that the original model may have seriously under-estimated the magnitude of late-glacial temperature oscillations in Atlantic Canada. The new inferences suggest that summer surface water temperatures in Splan Pond, New Brunswick were approximately 10 to 12 °C immediately following deglaciation and during the Younger Dryas. During the Allerod and early Holocene, surface water temperatures of 20 to 24 °C were attained. The new model thus provides the basis for more accurate palaeotemperature reconstructions throughout easternmost Canada.     

Hanford tank residual waste – Contaminant source terms and release models

Residual waste is expected to be left in 177 underground storage tanks after closure at the US Department of Energy’s Hanford Site in Washington State, USA. In the long term, the residual wastes may represent a potential source of contamination to the subsurface environment. Residual materials that cannot be completely removed during the tank closure process are being studied to identify and characterize the solid phases and estimate the release of contaminants from these solids to water that might enter the closed tanks in the future. As of the end of 2009, residual waste from five tanks has been evaluated. Residual wastes from adjacent tanks C-202 and C-203 have high U concentrations of 24 and 59 wt.%, respectively, while residual wastes from nearby tanks C-103 and C-106 have low U concentrations of 0.4 and 0.03 wt.%, respectively. Aluminum concentrations are high (8.2–29.1 wt.%) in some tanks (C-103, C-106, and S-112) and relatively low (<1.5 wt.%) in other tanks (C-202 and C-203). Gibbsite is a common mineral in tanks with high Al concentrations, while non-crystalline U–Na–C–O–P ± H phases are common in the U-rich residual wastes from tanks C-202 and C-203. Iron oxides/hydroxides have been identified in all residual waste samples studied to date. Contaminant release from the residual wastes was studied by conducting batch leach tests using distilled deionized water, a Ca(OH)₂-saturated solution, or a CaCO₃-saturated water. Uranium release concentrations are highly dependent on waste and leachant compositions with dissolved U concentrations one or two orders of magnitude higher in the tests with high U residual wastes, and also higher when leached with the CaCO₃-saturated solution than with the Ca(OH)₂-saturated solution. Technetium leachability is not as strongly dependent on the concentration of Tc in the waste, and it appears to be slightly more leachable by the Ca(OH)₂-saturated solution than by the CaCO₃-saturated solution. In general, Tc is much less leachable (<10 wt.% of the available mass in the waste) than previously predicted. This may be due to the coprecipitation of trace concentrations of Tc in relatively insoluble phases such as Fe oxide/hydroxide solids.