Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

Desert vegetation and timing of solar radiation

Timing and amount of solar radiation were examined as factors influencing the distribution of seven perennial plants on a small mountain located in the Chihuahuan Desert. Average direct beam solar radiation fluxes at differing times throughout the day and year were estimated with computer calculations. Principal components analysis was used to reduce the number of solar radiation parameters and include the maximum available information with a manageable number of variables. The remaining solar radiation parameters were compared to plant distributions using redundancy analysis and generalized additive models. Unimodal, bimodal, and monotonic responses were all found depending upon the species and solar radiation parameter. Niche separation at this location depends upon the timing as well as the amount of solar radiation.     

On the evaluation of an integral connected with the thermonuclear reaction rate in closed form

The standard expression of the reaction rate for low-energy, nonresonant nuclear reactions in nondegenerate plasma contains a parameter-dependent integral which in all previous calculations with physical or astrophysical background is considered as not capable of being evaluated in a closed form. So one usually resorts to approximation methods concerning large values of the parameter. At first we point out that CONSUL (1964) has given a series representation of the integral which was identified with a MEIJER 's G-function by MATHAI (1971). Next, in view of a physically more exact determination of the reaction rate formula, especially in connection with calculations concerning stellar energy generation, we consider a more general integral containing the mentioned one as special case and give an approximation-free representation by means of MEIJER 's G-function. The G-function so obtained may be conceived as complex-valued continuation of CONSUL 's series representation of a certain class of integrals contained in the considered one. From the series we extract a small parameter approximation of the special integral.     

Petrology and geochemistry of Northwest Africa 5480 diogenite and evidence for a basin‐forming event on Vesta

We performed a petrological and geochemical study of an olivine diogenite, Northwest Africa (NWA) 5480. NWA 5480 is a crystalline stone, but shows a heterogeneous texture. Olivine aggregates and grains of olivine and chromite display resorption textures set in a crystalline pyroxene matrix. Large olivine aggregates are penetrated by pyroxene matrix. Flow textures are observed near olivine aggregates. Olivine, chromite, and pyroxene show minor chemical zoning, implying relatively rapid cooling. NWA 5480 contains a significant amount of platinum group elements with chondritic relative proportions. All this evidence supports that NWA 5480 is an impact‐melt breccia from a target composed of olivine and pyroxene‐rich lithologies. Such impact melt would have formed by melting crustal materials, possibly during one of the impacts that formed the South Pole basins on Vesta.     

Photometrische Kalibrierung von Schmidtspiegelaufnahmen durch ein bildteilendes Hilfsprisma

Plates of the Tautenburg Schmidt can be calibrated with the aid of a beam-splitting prisma only if Schraffierkassette plates are used. The effects of image structure, scintillation and intermittence on in-focus images are different for the main component and the prismatic companion. Therefore, such plates cannot be used to set up a photometric scale.     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...     

Contribution to the search for binaries among Am stars – VIII. New spectroscopic orbits of eight systems and statistical study of a sample of 91 Am stars

Red clump giant (RCG) stars can be used as distance indicators to trace the mass distribution of the Galactic bar. We use RCG stars from 44 bulge fields from the OGLE-II microlensing collaboration data base to constrain analytic triaxial models for the Galactic bar. We find the bar major-axis is oriented at an angle of 24°–27° to the Sun–Galactic Centre line-of-sight. The ratio of semimajor and semiminor bar axis scalelengths in the Galactic plane   x ₀, y ₀  , and vertical bar scalelength z ₀, is   x ₀ :  y ₀ :  z ₀= 10 : 3.5 : 2.6  , suggesting a slightly more prolate bar structure than the working model of Gerhard which gives the scalelength ratios as   x ₀ :  y ₀ :  z ₀= 10 : 4 : 3  .     

Numerical Modeling of the Observed Wiechert Seismograph Magnification

—The paper presents results of experiments designed to measure the actual dynamic magnification of the Wiechert 1000 kg horizontal seismometer when excited by seismic waves. This is accomplished by comparing 51 digital records of seismic events recorded by the Wiechert and a well calibrated reference seismometer. The results obtained indicate that the magnification of the Wiechert seismometer is influenced by the interaction of its mass and frame, especially for high frequencies. This interaction has been modeled by considering a system of two coupled pendulums, yielding a theoretical dynamic magnification curve which exhibits main features of the observed magnification. The dis crepancy between the nominal and the actual response of the Wiechert seismograph may lead to errors in studies involving spectral analyses of recorded seismograms, and to overestimation of local earth quake magnitudes.     

Geotechnical assessment of the bearing capacity of coal mine floors

Summary This investigation concerns 3 longwall faces having variable strata and mining conditions, but supported by 202 tonnes hydraulic 6-leg chocks. Bearing capacity tests along the faces were conducted to evaluate the factors influencing floor deformation and failure. The effect of size, shape and perimeter of the base plates, thickness of the floor layer, time and moisture on the ultimate bearing capacity of the floor was measured and discussed. Application of this work is the prediction of stability and support performance of face ends, as well as the design of support systems and ground control on production faces.