Investigation by backscatter radar of artificial irregularities produced in ionospheric plasma heating experiments

The artificial ionospheric turbulence occurs in the ionosphere illuminated by high power HF radio waves. There are a lot of irregularities stretched along the geomagnetic field in this region. The investigation of the artificially disturbed ionospheric region is based on the reception of back scattered signals (BSS) which permits the basic parameters of this region to be estimated and its inhomogeneous structure to be described.Experiments were carried out using ‘Sura’ heating facility in the frequency range of ? = 4.7–9 MHz (ordinary mode) with the effective radiated power P_eff = 50–70 MW beamed vertically upwards. The most important dynamic and statistical BSS characteristics (the built-up time, the relaxation and autocorrelation times, the BSS amplitude spatial correlation function and power spectra) were measured using probe waves in the frequency range of that made it possible to obtain the basic parameters of the artificial irregularities. The model representation of a disturbed region in a form of a periodic structure gives a possibity to evaluate the scale of the structure, the whole size of the disturbance and its power and to calculate the main BSS characteristics.     

Models of the Southern Oscillation in the 300–100 mb layer and the basis of seasonal forecasting

Summary The geometry of the principal Upper High (near the Indian Occean) in the 300–100 mb layer appears to account for the Southern Oscillation (S.O.), and models of its behaviour are presented. Significant features of these models include the equatorial points of upper convergence (C) and divergence (D), a pressure discontinuity (CNDS) forming «arcs» and an «enclosure» around the high, and, lastly, encircling «crescents» both outside and inside the enclosure. The geography of the seasonal sucession can thus—in a qualitative manner—be interpreted in the light of known wind and contour patterns near the tropopause. With a few general principles, the established empirical rules of long-range forecasting then follow by deduction. The models and the terminology are useful likewise in the interpretation of solar-terrestrial relations and of climatic fluctuations.     

Beitrag zur Phosphorbestimmung im Klärschlamm

As the introduction, the advantages and drawbacks of a large number of phosphorus determination methods and digestion techniques for particulate matter, as e. g. sewage sludge, used in practice are described. The results of some investigations concerning the techniques of digestion as well as the further preparation of the extracts for the phosphorus determination proper are graphically and in tabular form represented and interpreted. The investigated photo-metric methods may be disturbed by iron and silicic-acid components. Advice about, and possibilities for avoiding such disturbances are given. In the case of the simultaneous application of the Kjeldahl digestion for the determination of nitrogen as well as of phosphorus there should be paid attention to possible disturbances by the selenium- or mercury-containing catalyst additives in the further processing of samples due to the formation of deposits.     

UV camera measurements of fumarole field degassing (La Fossa crater,Vulcano Island)

The UV camera is becoming an important new tool in the armory of volcano geochemists to derive high time resolution SO₂ flux measurements. Furthermore, the high camera spatial resolution is particularly useful for exploring multiple-source SO₂ gas emissions, for instance the composite fumarolic systems topping most quiescent volcanoes. Here, we report on the first SO₂ flux measurements from individual fumaroles of the fumarolic field of La Fossa crater (Vulcano Island, Aeolian Island), which we performed using a UV camera in two field campaigns: in November 12, 2009 and February 4, 2010. We derived ~ 0.5 Hz SO₂ flux time-series finding fluxes from individual fumaroles, ranging from 2 to 8.7 t d^?1, with a total emission from the entire system of ~ 20 t d^?1 and ~ 13 t d^?1, in November 2009 and February 2010 respectively. These data were augmented with molar H₂S/SO₂, CO₂/SO₂ and H₂O/SO₂ ratios, measured using a portable MultiGAS analyzer, for the individual fumaroles. Using the SO₂ flux data in tandem with the molar ratios, we calculated the flux of volcanic species from individual fumaroles, and the crater as a whole: CO₂ (684 t d^?1 and 293 t d^?1), H₂S (8 t d^?1 and 7.5 t d^?1) and H₂O (580 t d^?1 and 225 t d^?1).     

Sr-isotope stratigraphy of the Upper Jurassic of central Portugal (Lusitanian Basin) based on oyster shells

Strontium isotope stratigraphy was performed on oyster shells from the Late Jurassic of the Lusitanian Basin (central Portugal). This represents the first approach to obtain numerical ages for these strata. The new chronostratigraphic data provide a more precise age determination of several units. After a basin-wide hiatus sedimentation in the Late Jurassic is proven in the Cabo Mondego and Cabaços formations to resume as early as the Middle Oxfordian. The Alcobaça formation can be placed in the latest Late Oxfordian to Late Kimmeridgian, while data from the upper part of the Abadia Formation indicate an Early to Late Kimmeridgian age. The Farta Pao formation ranges from the latest Kimmeridgian to the latest Tithonian. The largely synchronous Sobral, Arranhó I, and Arranhó II members are overlain by the late Early to Late Tithonian Freixial Member. The brief, local carbonate incursion of the Arranhó I member marks the Kimmeridgian–Tithonian boundary. Oysters are shown once more to be suitable for strontium isotope studies. Their calcitic shells are often unaffected by diagenesis. In particular for marginal marine Jurassic and Cretaceous strata, where belemnites are usually absent, oysters may serve as a valuable tool for isotope stratigraphy.     

Carbonate cements in Miller field of the UK North Sea: a natural analog for mineral trapping in CO<Subscript>2</Subscript> geological storage

Miller field of the North Sea has had high concentrations of natural CO₂ for ~70 Ma. It is an ideal analog for the long-term fate of CO₂ during engineered storage, particularly for formation of carbonate minerals that permanently lock up CO₂ in solid form. The Brae Formation reservoir sandstone contains an unusually high quantity of calcite concretions; however, C and O stable isotopic signatures suggest that these are not related to the present-day CO₂ charge. Margins of the concretions are corroded, probably because of reduced pH due to CO₂ influx. Dispersed calcite cements are also present, some of which postdate the CO₂ charge and, therefore, are the products of mineral trapping. It is calculated that only a minority of the reservoired CO₂ in Miller (6–24%) has been sequestrated in carbonates, even after 70 Ma of CO₂ emplacement. Most of the CO₂ accumulation is dissolved in pore fluids. Therefore, in a reservoir similar to the Brae Formation, engineered CO₂ storage must rely on physical retention mechanisms because mineral trapping is both incomplete and slow.     

Copper, lead and cadmium concentrations in surface water, sediment and fish, C. Carpio, samples from Lake Naivasha: effect of recent anthropogenic activities

Following recent concerns of chemical pollution around Lake Naivasha, especially originating from recent agricultural activities in the catchment, samples of water, sediments, and fish Common carp (Cyprinus carpio) were collected from the Hippo Point, Kasarani, Mouth of Malewa River, Mouth of Karati River, Crescent Island, Sher Karuturi Discharge outlet and Oserian Bay for analysis of Cu, Cd and Pb by FAAS. The mean heavy metal levels ranged from 5.12?C58.11 (Pb), 1.06?C1.73 (Cd), and <0.03?C2.29 (Cu) mg/kg wet weight in C. carpio muscle, <100?C179.83 (Pb), <10.00?C10.06 (Cd) and <30.00?C32.33 (Cu) ??g/L in surface water, and 17.11?C53.07 (Pb), 1.18?C5.58 (Cd) and 3.00?C8.48 (Cu) mg/kg dry weight in sediment and showed a wide variation within and between samples with relatively high concentrations in sediments and fish muscle tissues. The results indicate that Lake Naivasha, in some parts, is polluted with these heavy metals of which relatively higher concentrations are found at the discharge outlets near Sher Karuturi and Oserian Bay. This indicates possible contribution from surrounding horticultural/floricultural activities and the Mouths of the Rivers Malewa and Karati which flow from it??s upper catchment.