The palaeoenvironmental and palaeohydrological evolution of Padul Peat Bog (Granada, Spain) over one million years, from elemental, isotopic and molecular organic geochemical proxies

The elemental (concentration of organic carbon, atomic H/C and C/N ratios), isotopic (δ¹³C values of organic matter) and molecular (predominant n-alkane chain length and carbon preference index (CPI)) organic components were measured for 600 samples taken from a 107-m long core from the Padul Basin (Andalusia, Spain). The record runs from the Lower Pleistocene (ca. 1 Ma B.P.) to the mid-Holocene (ca. 4.5 ka B.P.) with, in general, little diagenesis (removal of components). Two markedly different hydrogeological scenarios were interpreted: (1) From ca. 1 Ma to ca. 400 ka B.P. run-off recharge was significant and water depths were greater (lacustrine scenario). From ca. 400 to 4.5 ka B.P., the Padul Basin became a peat bog s.s. with the major water input coming from groundwater inflow. From ca. 400 to ca. 180 ka B.P. alternating episodes with either predominant grasses, trees or aquatic macrophytes which were linked to wet/dry phases, took place. An important deglaciation episode has been interpreted to occur between ca. 180 and 170 ka B.P. The global climatic changes occurring from ca. 170 to 25 ka B.P. were not recorded in the proxies, though they do show important variations linked to the Last Glacial Maximum and the beginning of the Holocene (ca. 25–10 ka B.P.): (2) Cold phases coexisting with dry periods produced the recession of forests and the development of grasses. After these periods, as both temperature and precipitation increased, forests expanded and the water level, linked to thaw, rose, especially at ca. 20 ka B.P. Few changes occurred during the Holocene, although there were short alternations between wet and dry episodes. Overall, the techniques applied proved to be excellent palaeoenvironmental proxies for studying the basin’s palaeoclimatological and palaeohydrological evolution.     

Soil contamination from urban and industrial activity: example of the mining district of Linares (southern Spain)

The Linares region (southern Spain) has been subjected to two important sources of pollution: the intensive mining works and the urban-industrial activity. To obtain a geochemical characterisation of the soil, 31 trace elements were analysed and 669 soil samples were collected. By means of clustering analysis, we identified groups of elements and grid squares in which relations could be established concerning soil lithology, urban and industrial activities and the degree of pollution impact; in addition, we were able to characterise the geochemical background of the study area. The multivariate study led us to identify four factors. Particularly important was factor 2, which represented the elements associated with mineral paragenesis (Cu, Pb, As, Co, Mn, Zn, Sn, Ba). This factor also contains elements related with an urban-industrial activity, such as Pb, Cu, Zn, As and Ba. Furthermore, we identified factor 4, associating Ni, V and Cr, and which is related to the use of fuels.     

The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Solution mechanisms of H2O in depolymerized peralkaline melts

Solubility mechanisms of water in depolymerized silicate melts quenched from high temperature (1000°-1300°C) at high pressure (0.8-2.0 GPa) have been examined in peralkaline melts in the system Na₂O-SiO₂-H₂O with Raman and NMR spectroscopy. The Na/Si ratio of the melts ranged from 0.25 to 1. Water contents were varied from ∼3 mol% and ∼40 mol% (based on O = 1). Solution of water results in melt depolymerization where the rate of depolymerization with water content, ∂(NBO/Si)/∂X_H2O, decreases with increasing total water content. At low water contents, the influence of H₂O on the melt structure resembles that of adding alkali oxide. In water-rich melts, alkali oxides are more efficient melt depolymerizers than water. In highly polymerized melts, Si-OH bonds are formed by water reacting with bridging oxygen in Q⁴-species to form Q³ and Q² species. In less polymerized melts, Si-OH bonds are formed when bridging oxygen in Q³-species react with water to form Q²-species. In addition, the presence of Na-OH complexes is inferred. Their importance appears to increase with Na/Si. This apparent increase in importance of Na-OH complexes with increasing Na/Si (which causes increasing degree of depolymerization of the anhydrous silicate melt) suggests that water is a less efficient depolymerizer of silicate melts, the more depolymerized the melt. This conclusion is consistent with recently published ¹H and ²⁹Si MAS NMR and ¹H-²⁹Si cross polarization NMR data.     

Microtectonic and geochemical characterization of thrusting in a foreland basin: Example of the South-Pyrenean orogenic wedge (Spain)

In orogenic systems, thrust faults play a major role in stacking different tectonic units and may act as conduits for the expulsion of large amounts of fluid of different origins (metamorphic, diagenetic, meteoric). This study focuses on the Monte Perdido thrust unit emplaced in the Paleogene Jaca thrust-sheet-top basin, in the SW-central Pyrenees. We aim to decipher the mechanisms and P-T conditions of deformation in fault zones and characterize the related fluid involvement, through combined microstructural, geochemical and microthermometry analyses. Two thrust faults cutting platform limestones, marls and siliciclastic turbidites of the lower part of the basin-fill (Paleocene–lower Eocene) have been studied. The fault zones are characterized by metre-thick shear zones with highly deformed, foliated clay-rich sediments. Foliation is underlined by preferentially oriented phyllosilicates. Several generations of shear and extension calcite, quartz and chlorite-bearing veins attest to fluid-rock interactions during a multi-stage deformation. Microstructural observations and stable isotope analyses on calcite from veins and host sediments suggest that deformation was aseismic and dominated by diffusive mass transfer from pressure solution sites along cleavage and stylolites to the precipitation sites in veins, with mineralizing fluids in equilibrium with the host sediments. Our results suggest an essentially closed hydrologic system, and imply the absence of significant fluid flow along the studied fault zones. Microthermometric study on fluid inclusions present in calcite and quartz veins, and calcite-quartz oxygen isotopic fractionation determined for the first generation shear veins, allow a geothermal gradient of 34 °C/km to be estimated. Analytical results demonstrate an evolution of the fault zones in three stages. The first stage was related to the emplacement of the Monte Perdido thrust unit during the middle Eocene at a temperature of ～208 °C and a burial depth of ～5.7 km. The second stage corresponds to a fault reactivation at a temperature of ～240 °C and a burial depth of ～6.5 km. The latter deformation may have been related to folding of the Monte Perdido thrust unit during the emplacement of the underlying Gavarnie thrust unit during the late Eocene–early Oligocene, with deeper burial resulting from aggradation of the thrust-sheet-top basin-fill. The last event corresponds to the formation of a dilatant vein system likely related to the exhumation of the massif.     

High-resolution spectroscopy of ROSAT-discovered weak-line T Tauri stars near Lupus

We present high-resolution optical echelle spectroscopy for a large fraction of the Li-rich late-type stars recently discovered in the vicinity of the Lupus dark clouds. Our results confirm the high Li  i   λ 6708 equivalent widths previously estimated from medium-resolution spectra, thus adding strength to the conclusion that the large majority of these stars are still in the pre-main-sequence phase of their evolution, contrary to claims from other authors that many of them might be zero-age main-sequence stars. We present a statistical approach to derive a mean distance for the sample, and find that it is consistent with, or slightly lower than, the Hipparcos distance of the Lupus star-forming region. The radial velocities measured for part of these stars are consistent with those observed for the Lupus star-forming region, while stars outside the dark clouds show a mean difference of the order of 3 km s⁻¹. The projected rotational velocities show a lack of slow rotators, which is interpreted as a consequence of the X-ray selection of the sample. The Li-rich stars in Lupus studied in this work yield a fairly 'clean' sample of very young stars, while in other star-forming regions a larger fraction of older zero-age main-sequence stars has been found among ROSAT -discovered Li-rich stars. We argue that this fact reflects the relation of these stars with the Gould Belt.     

Variability of organic δC and C/N in the Mersey Estuary, U.K. and its implications for sea-level reconstruction studies

Microfossil analysis (e.g. diatoms, foraminifera and pollen) represents the cornerstone of Holocene relative sea-level (RSL) reconstruction because their distribution in the contemporary inter-tidal zone is principally controlled by ground elevation within the tidal frame. A combination of poor microfossil preservation and a limited range in the sediment record may severely restrict the accuracy of resulting RSL reconstructions. Organic δ¹³C and C/N analysis of inter-tidal sediments have shown some potential as coastal palaeoenvironmental proxies. Here we assess their viability for reconstructing RSL change by examining patterns of organic δ¹³C and C/N values in a modern estuarine environment. δ¹³C and C/N analysis of bulk organic inter-tidal sediments and vegetation, as well as suspended and bedload organic sediments of the Mersey Estuary, U.K., demonstrate that the two main sources of organic carbon to surface saltmarsh sediments (terrestrial vegetation and tidal-derived particulate organic matter) have distinctive δ¹³C and C/N signatures. The resulting relationship between ground elevation within the tidal frame and surface sediment δ¹³C and C/N is unaffected by decompositional changes. The potential of this technique for RSL reconstruction is demonstrated by the analysis of part of an early Holocene sediment core from the Mersey Estuary. Organic δ¹³C and C/N analysis is less time consuming than microfossil analysis and is likely to provide continuous records of RSL change.     

Suitability analysis for sand and gravel extraction site location in the context of a sustainable development in the surroundings of Zaragoza (Spain)

Zaragoza city is located in the central Ebro Basin, in the Iberian Peninsula. The fluvial terraces formed by the Ebro River present a valuable resource of sand and gravel deposits. However, taking advantage of these available resources implies conflicts with other land use interests like urban and industrial development as well as agricultural use, which has also traditionally occupied the alluvial terraces. These deposits represent a substantial groundwater resource that should be preserved for future generations. The development of spatial decision support systems (SDSS) has greatly assisted efforts for solving land-use conflicts. These systems combine the benefits of geographic information systems (GIS) and decision support methodologies and are therefore suitable to manage sustainable development of urban areas. In this contribution, an extraction suitability map taking into consideration a variety of environmental criteria is created with the help of a SDSS. The method used is the analytical hierarchy process which is integrated in ArcGIS. Areas most suitable to sand and gravel extraction are located in the high terraces, and in those terraces covered by pediments where the thickness of resource is relatively high. These areas are far from valuable natural areas, outside areas most vulnerable to groundwater contamination, and beneath soils with poor irrigation characteristics.     

Investigation of the electrostatic charging of dust particles in a Paul-trap

Dust particles (glass, tungsten, and nickel) with sizes ranging from 0.25 to 3m were levitated in a Paul-trap and charged by ions or electrons. For ions the particle potential is limited at field strength of about 1×10⁹ V m^–1 by a temperature-dependent discharge mechanism. The particles interaction with 2 to 20 keV electrons always leads to positive surface potentials which can be explained in terms of a decreased absorption of electrons by small particles. Micrometer sized agglomerates were used for the investigation of the electrostatic fragmentation. Fragmentation takes place in a twofold manner: small surface flufl can be removed or the parent particle can be disrupted into smaller agglomerates.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.