Cation ordering of orthopyroxenes from the Skaergaard Intrusion: implications for the subsolidus cooling rates and permeabilities

 We have determined the quenched cation ordering states of five orthopyroxene crystals collected from the marginal border group and the lower zone a and b of the Skaergaard intrusion, and modeled these data to retrieve their closure temperatures (T _c) of Fe–Mg ordering and cooling rates. According to existing thermal models for the Skaergaard pluton, conductive cooling dominated the high and low temperature regimes, which were separated by an intermediate temperature regime in which the cooling was controlled primarily by convective fluid circulation. The cooling rates retrieved from the quenched cation ordering states of the orthopyroxene crystals strictly apply to temperatures around the closure temperatures of the ordering states, ∼340–400^° C, which fall at the transition from convective to the lower temperature conductive cooling. The cooling rates obtained from the cation ordering states of orthopyroxene vary from ∼1 to 270 K/ka. These results agree well with a thermal model calculated using an assumed average permeability of 10^-12 cm² for the pluton, but not completely with a model calculated on the basis of an average permeability of 10^-13 cm², although both values produced shifts of δ¹⁸O that are comparable to those observed in the pluton. Received: 27 February 1995/Accepted: 20 July 1995     

Long term atmospheric deposition as the source of nitrate and other salts in the Atacama Desert, Chile: New evidence from mass-independent oxygen isotopic compositions

Isotopic analysis of nitrate and sulfate minerals from the nitrate ore fields of the Atacama Desert in northern Chile has shown anomalous ¹⁷O enrichments in both minerals. Δ¹⁷O values of 14-21 ‰ in nitrate and 0.4 to 4 ‰ in sulfate are the most positive found in terrestrial minerals to date. Modeling of atmospheric processes indicates that the Δ¹⁷O signatures are the result of photochemical reactions in the troposphere and stratosphere. We conclude that the bulk of the nitrate, sulfate and other soluble salts in some parts of the Atacama Desert must be the result of atmospheric deposition of particles produced by gas to particle conversion, with minor but varying amounts from sea spray and local terrestrial sources. Flux calculations indicate that the major salt deposits could have accumulated from atmospheric deposition in a period of 200,000 to 2.0 M years during hyper-arid conditions similar to those currently found in the Atacama Desert. Correlations between Δ¹⁷O and δ¹⁸O in nitrate salts from the Atacama Desert and Mojave Desert, California, indicate varying fractions of microbial and photochemical end-member sources. The photochemical nitrate isotope signature is well preserved in the driest surficial environments that are almost lifeless, whereas the microbial nitrate isotope signature becomes dominant rapidly with increasing moisture, biologic activity, and nitrogen cycling. These isotopic signatures have important implications for paleoclimate, astrobiology, and N cycling studies.     

Pollution history and recovery of a boreal lake exposed to a heavy bleached pulping effluent load

We examined the effects of heavy pulp mill discharges on the Lake Lievestuoreenjärvi ecosystem and the later recovery of diatom and chironomid communities from age-dated short core samples. Beginning in 1927 the lake received a heavy effluent load from a sulphite pulp mill. Except for the recession during the Second World War and the temporary closure of the mill from 1967 to 1971, the industrial load, containing large quantities of nutrients, organic matter and toxic compounds, increased continuously. In the early 1980s, laboratory documents were falsified by the directors of the mill and the systematic illegal effluent overload led to a collapse of the whole lake ecosystem. In 1985, the outdated plant was finally closed down. Based on the assessment of chemical properties and biological remains of the sediment, we distinguished five developmental phases in the ecological state of the lake. In the pre-industrial phase, the pelagic and profundal benthic communities were dominated by species preferring ultraoligotrophic or oligotrophic lakes. Concomitant with the increasing discharge and deposition of chlorine compounds, resin acids, and mercury, as well as strong acidity and hypolimnetic and epilimnetic anoxia, the ecological status changed in a short period from excellent to bad. Finally, in the early 1960s, the majority of the lake was virtually dead and the aquatic life survived only in the uppermost littoral zone. Since 1985, a fast recovery in the water quality has led to a strong, but temporary eutrophy in pelagic communities. The main peak of eutrophication was caused by the invasion of a species new to the lake,Aulacoseira granulata var.angustissima. Later, the pelagic communities shifted towards oligotrophy, but the original, pre-industrial status has not been re-established. The profundal benthic communities have not achieved the pre-industrial structure, but at present indicate mesotrophy.     

Rainfall thresholds for landsliding in the Himalayas of Nepal

Landsliding of the hillslope regolith is an important source of sediment to the fluvial network in the unglaciated portions of the Himalayas of Nepal. These landslides can produce abrupt increases of up to three orders of magnitude in the fluvial sediment load in less than a day. An analysis of 3 years of daily sediment load and daily rainfall data defines a relationship between monsoonal rainfall and the triggering of landslides in the Annapurna region of Nepal. Two distinct rainfall thresholds, a seasonal accumulation and a daily total, must be overcome before landslides are initiated. To explore the geomorphological controls on these thresholds, we develop a slope stability model, driven by daily rainfall data, which accounts for changes in regolith moisture. The pattern of rainfall thresholds predicted by the model is similar to the field data, including the decrease in the daily rainfall threshold as the seasonal rainfall accumulation increases. Results from the model suggest that, for a given hillslope, regolith thickness determines the seasonal rainfall necessary for failure, whereas slope angle controls the daily rainfall required for failure.     

Apparent and real bias in numerical transfer functions in palaeolimnology

We present an evaluation of the procedure by which model prediction bias is examined in palaeolimnological transfer function inference models. We argue that most of the prediction biases commonly reported in the literature are, in fact, fallacious, and are the artificial consequence of the inappropriate manner in which residuals are traditionally examined. We show that the extent of the specious model bias is entirely predictable from first principles and is essentially determined by the strength of the predictive model. We suggest that the analysis of residuals should always be examined as a function of the model's predictions and we discuss the implications of the old and new approaches.     

Long-term bed load transport rate based on aerial-photo and ground penetrating radar surveys of fan-delta growth, Coast Mountains, British Columbia

Sequential aerial photography, sonar bathymetry, ground-penetrating radar (GPR), and sediment sampling and analysis provide the basis for calculating the volumetric and mass rate of progradation of the delta of Fitzsimmons Creek, a steep, high-energy, debris-flow-dominated channel draining about 100 km² of the southern Coast Mountains of British Columbia. Fitzsimmons Creek is typical of small mountain rivers in the region. GPR imaging is used to define the pre-depositional morphology of the receiving basin, a technique that improves the accuracy of the volumetric survey. The 52-year record (1947–1999) of progradation yielded an average annual volumetric transport rate of 1.00±0.16×10⁴ m³ year⁻¹ for bed load, corresponding to a mass transport rate of 1.60±0.28×10⁴ Mg year⁻¹. Bed load yields are consistent with those obtained in hydrogeomorphically similar basins in the region and elsewhere. Decade-based annual rates, which vary from 0.64±0.11×10⁴ to 2.85±0.38×10⁴ Mg year⁻¹, provide poor estimates of the 52-year average. Indeed, the 52-year record may also not be long enough to fully integrate the significant fluctuations in the sediment efflux from Fitzsimmons Creek. The methodology proposed in this paper can be transferred to other comparable mountain environments worldwide.     

A constrained 2D gravity model of the Sebastián Vizcaíno Basin, Baja California Sur, Mexico

The subsurface geometry of the Sebastián Vizcaíno Basin is obtained from the 2D inversion of gravity data, constrained by a density-versus-depth relationship derived from an oil exploration deep hole. The basin accumulated a thick pile of marine sediments that evolved in the fore-arc region of the compressive margin prevalent along western North America during Mesozoic and Tertiary times. Our interpretation indicates that the sedimentary infill in the Sebastián Vizcaíno Basin reaches a maximum thickness of about 4 km at the centre of a relatively symmetric basin. At the location of the Suaro-1 hole, the depth to the basement derived from this work agrees with the drilled interface between calcareous and volcaniclastic members of the Alisitos Formation. A sensitivity analysis strongly suggests that the assumed density function leads to a nearly unique solution of the inverse problem.