Phase Equilibria in the Metamorphic Rocks of St. Paul Island and Cape North, Nova Scotia

A suite of schists—one from the garnet zone, 19 from thestaurolite zone, 2 from the kyanite isograd, and one from thekyanite zone—were separated into their constituent minerals.Chemical analyses of one chlorite and of 23 sets of coexistingbiotites and garnets were carried out by photometric and titrametricprocedures. Plots of garnet-biotite tie-lines from divariantassemblages on appropriate phase diagrams result in intersectingtie-lines which cannot be ascribed to experimental error. Theoreticalconsiderations argue that at equilibrium, at the same pressureand temperature or at constant pressure and varying temperature,tie-lines of divariant assemblages should not intersect. Possibleexplanations require that diffusion equilibrium of Fe and Mgbe restricted to volumes smaller than that of a hand specimenor that P as well as T varies considerably. Emission spectrographicdeterminations of Fe and Mg in biotite indicate that the Fe/Mgratio varies among biotites little more than a centimeter apart.Such a variation would argue more in favor of a lack of diffusionequilibrium.     

Structure and petrology of an alpine peridotite on Cypress Island,Washington, U.S.A

A study of the structural petrology of a peridotite exposed on Cypress Island in Skagit Co., Washington, U.S.A. has been carried out. The Cypress peridotite is, by virtue of its composition, structure and associations, typical of ultramafics of the alpine type. It contains relict layering and accumulative textures which show it to have originated by crystal settling from a magma of unknown initial composition. Parallelism of lineations and b-axes of folds in the layering with well-developed [100]-maxima in the fabrics of olivine crystals is considered to have arisen through a penetrative deformation of the mass accompanied by plastic flow or recrystallization of the olivine. An indication of the minimum temperature of the deformation is provided by cross-cutting veins of pyroxenite which have not participated in the folding. The most satisfactory interpretation of the overall fabric of the peridotite is that it was deformed, possibly during intrusion, as a crystal mush, and that filter pressing due to compaction of the solid particles by plastic flow or recrystallization removed all but a small percentage of the magmatic fraction which then crystallized following cessation of the movements.     

Melting Relationships in the System CaO-MgO-CO2-H2O, with Petrological Applications

Phase relationships on the vapor-saturated liquidus surfacein the system CaO-MgO-CO₂-H₂O have been deduced from data inthe systems CaO CO₂-H₂O, CaO-MgO-CO₂, and MgO-CO₂-H₂O, and frompreliminary experiments in the quaternary system. These areillustrated in composition tetrahedra, and in isobaric sectionsthrough the petrogenetic model. The univariant PT curve forthe beginning of melting lies between 625? C and 600? C in thepressure range 10 bars to 4 kilobars, in the presence of a vaporphase rich in H₂O. The curve is divided into three sectionsby two invariant points, each section having a different primarymagnesian phase involved in the melting reaction. Periclaseoccurs on the low-pressure section (less than about 1 kilobar),and with increasing pressure first brucite and then dolomitebecome stable on the liquidus. The pressure of the second invariantpoint, above which dolomite is stable on the liquidus, is notknown. The effect of FeO as an additional component is considered.Processes of crystallization resulting from changes in temperature,in pressure, and in the composition of the vapor phase are discussed.These processes are applied to the crystallization and differentiationof carbonatite magmas, and the reverse processes involving fusionare applied to the metamorphism of dolomites. Crystallizationdifferentiation of a carbonatite magma could produce the sequenceof intrusion observed at some carbonatite complexes: calcitics?vite, followed by ankeritic s?vite, and finally sideriticcarbonatite. Partial melting may occur during the thermal metamorphismof dolomites, but melting is unlikely during regional metamorphism.     

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Ohne Zusammenfassung     

SUPER-WIDE ANGLE PHOTOGRAPHY AND ITS APPLICATION WITH VARIOUS TECHNIQUES

Some of the advantages and disadvantages of super-wide angle photography are discussed. Special reference is made to photography of an area in Bechuanaland, when airborne profile recorder and horizon camera were used in conjunction with aerial photography. Data from these ancillary aids were used in the subsequent adjustment procedure. The paper concludes with an account of analytical bridging using super-wide angle photography and a monocomparator.     

Ion-exchange reactions on clay minerals and cation selective membrane properties as possible mechanisms of economic metal concentration

A series of exploratory experiments on the concentration of base metals through ion exchange reactions on clay minerals show promising results. The extraction of Pb, Zn and Cd from bentonite, illite, kaolinite and montmorillonite was successful and megascopic quantities of PbS, CdS and ZnS could be obtained at specific loci, depending essentially on the flow velocity, and the other cations present. These or similar exchange reactions are tentatively proposed as possible mechanisms of economic metal concentration during diagenesis.

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Zusammenfassung Es werden experimentelle Resultate zur Anreicherung von Schwermetallen durch Tonminerale (Montmorillonite, Illite und Kaolinite) mitgeteilt. Eine erste Anreicherung kann über den Kationenaustausch bewirkt werden. In dem darauffolgenden zweiten, sehr viel wirksameren Schritt werden die Schwermetallionen aus den Tonlagern extrahiert und in deren Nähe als schwerlösliche Sulfide oder Carbonate gefällt. Die Extraktion beruht darauf, daß Tonschichten als Kationen-permeable Membranen wirken können. Sie wird von der Art der Tonminerale und der Kationen, den Lösungsgenossen, den Konzentrationsverhältnissen, dem pH-Wert, der Reaktionstemperatur, dem Porenvolumen und der Porenverteilung im Sediment beeinflußt.