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851.
Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process
with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al2O3 contents (60 and 70 mol%, respectively) and varying SiO2 plus B2O3 contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing
bulk B2O3 content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding
infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is
able to incorporate large amounts of boron into its structure (up to about 20 mol% B2O3 depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the
mullite structure in form of planar three-fold coordinated BO3 groups.
Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria 相似文献
852.
M. Mejías J. Garcia-Orellana J. L. Plata M. Marina E. Garcia-Solsona B. Ballesteros P. Masqué J. López C. Fernández-Arrojo 《Environmental Geology》2008,54(3):521-536
A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic
aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a
previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated
combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics
and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural
analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and
groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were
applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium
isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (18O, 2H and 3H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system.
Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics
of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater
uses in the area of study. 相似文献
853.
Implementation of reconstructed geomorphologic units in landslide susceptibility mapping: the Melen Gorge (NW Turkey) 总被引:6,自引:2,他引:4
In the international literature, although considerable amount of publications on the landslide susceptibility mapping exist,
geomorphology as a conditioning factor is still used in limited number of studies. Considering this factor, the purpose of
this article paper is to implement the geomorphologic parameters derived by reconstructed topography in landslide susceptibility
mapping. According to the method employed in this study, terrain is generalized by the contours passed through the convex
slopes of the valleys that were formed by fluvial erosion. Therefore, slope conditions before landsliding can be obtained.
The reconstructed morphometric and geomorphologic units are taken into account as a conditioning parameter when assessing
landslide susceptibility. Two different data, one of which is obtained from the reconstructed DEM, have been employed to produce
two landslide susceptibility maps. The binary logistic regression is used to develop landslide susceptibility maps for the
Melen Gorge in the Northwestern part of Turkey. Due to the high correct classification percentages and spatial effectiveness
of the maps, the landslide susceptibility map comprised the reconstructed morphometric parameters exhibits a better performance
than the other. Five different datasets are selected randomly to apply proper sampling strategy for training. As a consequence
of the analyses, the most proper outcomes are obtained from the dataset of the reconstructed topographical parameters and
geomorphologic units, and lithological variables that are implemented together. Correct classification percentage and root
mean square error (RMSE) values of the validation dataset are calculated as 86.28% and 0.35, respectively. Prediction capacity
of the different datasets reveal that the landslide susceptibility map obtained from the reconstructed parameters has a higher
prediction capacity than the other. Moreover, the landslide susceptibility map obtained from the reconstructed parameters
produces logical results. 相似文献
854.
855.
Black varnish commonly develops on rain-washed fine-grained monument sandstone. Stone modifications are, to the naked eye, limited to 10-μm thick black film and underlying modified zone about 1-mm thick. Transfer properties (absorption and drying kinetics and permeability) are, however, modified several centimetres under the surface. The present study investigates the modifications of black-varnish covered siliceous sandstones taken from Alsatian monuments (East of France) and of fresh sandstone undergoing wetting–drying cycles in the laboratory. Double-coloured thin-sections revealed gradual changes in the porous network, up to 3 cm under the black varnish. SEM observations showed that the film was mainly composed of iron and phosphorus while the modified zone was rich in calcium and sulphur. Fifty capillary absorption–drying cycles were carried out on fresh sandstone. Absorption kinetics was measured at each cycle. A continuous decrease of sandstone absorption kinetics over the fifty cycles was interpreted as a reorganisation of the porous network, reducing the connectivity of the porous network although total porosity remained unchanged. Wetting–drying cycles carried out under an environmental microscope (ESEM) showed a displacement of the finest particles (clay clusters), filling the macroporosity and decreasing the connectivity. 相似文献
856.
857.
Abstract The Taiwan orogen has been the focus of a number of models of mountain building processes, but little attention has been paid to high‐pressure (HP) metamorphic rocks that are found as exotic blocks intermingled within the deepest units of the mountain belt. In this study, we re‐appraise from updated petrological and thermodynamic databases the physical conditions of HP metamorphism in Taiwan, and we combine our findings with available geochronological data to estimate the thermal history of these rocks. Our results indicate that peak metamorphic conditions of ~550 °C and 10–12 kbar have been followed by a rapid isothermal decompression, with exhumation possibly as rapid as burial. These units have subsequently been stored at a pressure of ~3 kbar for ~4–5 Myr, before their final exhumation, probably facilitated by the accretion of passive margin sequences during the Late Cenozoic collision. Therefore, HP units in Taiwan maintain a record of processes at depth from the early stages of oceanic subduction to the present arc‐continent collision. 相似文献
858.
K. Vinod kumar R. C. Lakhera Tapas R. Martha R. S. Chatterjee A. Bhattacharya 《Environmental Geology》2008,55(4):789-799
Mass movements such as landslides in mountainous terrains are natural degradation processes and one of the most important
landscape-building factors. Varunawat Parbat overlooking Uttarkashi town witnessed a series of landslides on 23 September
2003 and the debris slides and rock falls continued for 2 weeks. This landslide complex was triggered due to the incessant
rainfall prior to the event, and its occurrence led to the blockage of the pilgrim route to Gangotri (source of the Ganges
river) and evacuation of thousands of people to safer places. Though there was no loss of lives due to timely evacuation,
heavy losses to the property were reported. High-resolution stereoscopic earth observation data were acquired after the incidence
to study the landslide in detail with emphasis on the cause of the landslide and mode of failure. Areas along the road and
below the Varunawat foothill region are mapped for landslide risk. It was found that the foothill region of the Varunawat
Parbat was highly disturbed by man-made activities and houses are dangerously located below steep slopes. The potential zones
for landslides along with the existing active and old landslides are mapped. These areas are critical and their treatment
with priority is required in order to minimise further landslide occurrences. 相似文献
859.
饱和粉砂不稳定性的试验研究 总被引:3,自引:0,他引:3
通过对净砂和级配良好粉砂(含10 %粉土)进行一系列三轴固结不排水试验(CU),研究了粉土、孔隙比和围压对饱和粉砂不稳定性的影响。试验结果表明,净砂与粉砂在不排水剪切条件下均会出现应变软化现象(即不稳定性)。同一围压下脆性指数(IB)随孔隙比增加,但不稳定线的应力比随孔隙比增加而减小。引用等效粒间孔隙比(ege)后,净砂和粉砂在ege-ln p?平面上拥有基本相同的临界状态线。在临界状态理论及等效粒间孔隙比的基础上,提出在同一修正状态参数(?ge)下净砂和级配良好粉砂有相似的不稳定性。 相似文献
860.
A numerical analysis of cyclotron instabilities is carried out by computing the dispersion relation for a three component cold plasma-beam system. Rates of growth and damping for various values of the stream density are calculated from the dispersion relation. The rates of growth and damping increase monotonically as the number density of the proton stream increases. It is found that the frequencies at the rates of maximum growth and the damping decrease slightly to lower frequencies and a sharp peak at these frequencies becomes blunt. The minimum e-folding times of an ion cyclotron wave for (a) σs = 10−4, σi = 10−2 and (b) σs = 10−1, σi = 10−2 are about 3·84 and 0·16 sec respectively in the vicinity of the equatorial plane at 6 Re, where σs and σi are the ratios of the beam density Ns and the helium ion (H6+) density Ni to the total positive ions in the plasma-beam system. 相似文献