Archaean lode gold deposits in the Coolgardie Goldfield, Western Australia, occur in mafic and ultramafic rocks which have
been metamorphosed to the amphibolite facies. Mineralisation was broadly synchronous with peak metamorphism, the main phase
of granitoid emplacement, and regional deformation. Several different structural styles are represented by the deposits of
the Coolgardie Goldfield. Mineralisation occurs along sheared felsic porphyry-ultramafic rock contacts, in gabbro-hosted quartz-vein
sets, in fault-bounded quartzvein sets, and in laminated quartz reefs sited in brittleductile shear zones. The structures
hosting mineralisation formed in response to a progressive deformation event, related to granitoid emplacement in an east-west
compressional far-field stress régime, but with local heterogeneous stress orientations. This occurred after an earlier period
of thrust-stacking, with probable north-south directed tectonic transport. Two contrasting styles of goldrelated wallrock
alteration are associated with the auriferous lodes of the Coolgardie Goldfield. A high-temperature assemblage (formation
temperature >500°C), characterised by the proximal alteration assemblage garnet+ hornblende + plagioclase + pyrrhotite, contrasts
with a medium-temperature assemblage (formation temperature <500°C), consisting of calcic amphibole + biotite + plagioclase
+ calcite + arsenopyrite + pyrrhotite. The distribution of the two styles of gold-related alteration is controlled by distance
from voluminous syntectonic granitoids located to the west of the Coolgardie Goldfield, with the high-temperature style of
alteration more proximal to the granitoid-greenstone contact than the medium-temperature style. The occurrence of gold deposits
that formed under amphibolite facies conditions throughout the Coolgardie Goldfield supports a crustal continuum model for
Archaean lode-gold deposits, which proposes that gold is deposited in metamorphic environments that range from the sub-greenschist
to granulite facies. In addition, the data from Coolgardie suggest that syntectonic, synmineralisation granitic plutons may
play a significant role in controlling the style of gold associated wallrock-alteration at deep crustal levels. 相似文献
The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ13C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates. 相似文献
A major fraction of particulate organic carbon (POC) in the deep ocean remains molecularly uncharacterized. In an effort to determine the chemical characteristics and source(s) of sinking POC, we studied a nonhydrolyzable fraction of sinking POC using 13C NMR (nuclear magnetic resonance) spectroscopy and analytical pyrolysis. 13C NMR spectra and products from analytical pyrolysis of the nonhydrolyzable fraction exhibit a strongly aliphatic character that is distinct from that of bulk POC. The aliphatic nature of this fraction is consistent with its low stable carbon isotope values. We hypothesize that the nonhydrolyzable fraction derives to a significant extent from a refractory component of organisms that selectively accumulates, resulting in its manifestation as a major part of POC sinking to the deep ocean and in underlying sediments. 相似文献
In underground flow tracing studies, the estimation of the nature and the importance of interactions undergone by the substance used very often constitutes an obstacle to good modeling of mass-transfer processes in solution.
We propose a method to quantify these phenomena by the use of lanthanides as tracers.
For this study, we set up an analytical methodology adapted to routine measurements. The quality of five lanthanides as indicators has been examined. We have demonstrated the formation, by substitution, of a carbonate complex which is extremely stable in the natural environment. The field experiments carried out demonstrated the efficiency of those tracers and confirmed their great stability.
Tracer recovery graphs show that, in accord with our hypothesis, convection and dispersion are identical for all the lanthanide elements. Moreover, we have established a direct relation between their fixing rate on earth materials and the value of their stability constants.
Thus, we demonstrate the possibility of correlative multitracing, with known and quantifiable interelement relations.
Résumé
Dans les études de circulations souterraines par traceur, l'estimation de la nature et de l'importance des interactions subies par la substance utilisée constitue, bien souvent, un obstacle à une bonne modélisation des processus de transfert de masse en solution.
Nous proposons une méthode de quantification de ces phénomènes par l'utilisation des lanthanides comme traceurs.
Pour cette étude, nous avons mis au point une méthodologie analytique adaptée aux mesures de routine. Les qualités, en tant qu'indicateurs, de cinq lanthanides ont été examinées. Nous avons démontré la formation, par substitution, d'un complexe carbonaté extrèment stable en milieu naturel. Les expériences de terrain réalisées ont prouvé l'efficacité de ces traceurs et confirmé leur grande stabilité.
Les courbes de restitution obtenues ont montré que, conformément à nos hypothèses, la convection et la dispersion sont identiques pour l'ensemble de ces éléments. De plus, il a été établi une relation directe entre leurs taux de fixation sur le terrain et la valeur de leurs constantes de stabilité.
On dispose ainsi d'une possibilité de multitraçage corrélatif, avec des relations interélémentaires connues et quantifiables. 相似文献
The course of the active North Anatolian Fault system from Lake Abant to Lake Sapanca was traced by its high micro-earthquake activity. If approaching from the east this section includes a broad south to north overstep (fault offset) of the main fault. Local seismicity has been recorded in this area by a semi-permanent network of 8 stations since 1985 within the frame of the Turkish–German Joint Project for Earthquake Research. The effect of the overstep and its complex fracture kinematics are reflected by the seismicity distribution, the variations of composite fault-plane solutions, and by the spatial coda-Q distribution. Areas of different stress orientation can be distinguished and assigned to different groups of faults. The stresses and the tectonic pattern only in part correspond to a simple model of an extensional overstep and its correlative pull-apart basin. Other types of deformation involved are characterized by normal faulting on faults parallel to the general course of the main strike-slip fault and by synthetic strike-slip faults oriented similar to Riedel shears. Shear deformation by this fault group widely distributed in an area north and east of the main fault line may play an important role in the evolution of the overstep. The development of a pull-apart basin is inhibited along the eastern half of the overstep and compatibility of both strands of the main fault (Bolu–Lake Abant and Lake Sapanca– Izmit–Marmara Sea) seems to be achieved with the aid of the fault systems mentioned. The extension of the missing part of the pull-apart basin seems to be displaced to positions remote from the Lake Abant–Lake Sapanca main fault line, i.e. to the Akyaz?–Düzce basin tract. Highest Q-values (lowest attenuation of seismic waves) were found in the zone of highest seismicity north and west of the overstep which is the zone of strongest horizontal tension. If high coda-Q is an indicator for strong scattering of seismic waves it might be related to extensional opening of fractures. 相似文献
The Kamoto deposit consists of two stratiform orebodies separated by a barren sedimentary unit. It is a copper and cobalt deposit, the main features of which are summarized in the first part of the paper. Above the upper orebody, dolostone beds are found, where pyrite is the only sulfide mineral. This pyrite was investigated with the help of a microprobe: all idiomorphic grains were found to be surrounded by a well-defined rim, where the cobalt content reaches 4%; framboidal grains were also found to be heterogeneous with respect to cobalt. The distribution of nickel and copper is described. These observations afford one more evidence that post-depositional events played an important role in the Mine Series of Katanga, especially with regard to heavy metals geochemistry.
Resume Le gisement de Kamoto est constitué de deux corps minéralisés stratiformes séparés par une unité sédimentaire stérile. C'est un gisement de cuivre et de cobalt dont les principales caractéristiques sont brièvement résumées. Audessus du corps minéralisé supérieur, on trouve des couches de dolomie, où la pyrite est le seul sulfure présent. Cette pyrite a été étudiée à l'aide d'une microsonde: tous les grains idiomorphes y sont entourés d'une bordure bien nette, où la teneur en cobalt atteint 4%; les grains d'apparence framboïdale sont également hétérogènes au point de vue de leur teneur en cobalt. La distribution du nickel et du cuivre est décrite. Ces observations apportent um témoignage supplémentaire de l'importance des événements postérieurs au dépôt dans la «Série des Mines» katangaise, tout spécialement en ce qui concerne la géochimie des métaux lourds. Elles démontrent que le «système» constitué par la roche sédimentaire est resté ouvert pendant un certain temps après la sédimentation.