Observations of some oxygen-containing and sulfur-containing organic molecules in cold dark clouds

Observations of nine oxygen- and sulfur-containing organic molecules have been made toward the cold dark clouds TMC-1 and L134N. We have confirmed the presence of para-ketene (H2C2O) in TMC-1, have for the first time observed ortho-ketene, and find a total ketene column density approximately 1 x 10(13) cm-2. Thioformaldehyde (H2CS) is easily detectable in both TMC-1 and L134N, with a column density about 5 times larger in the former source (approximately 3 x 10(13) cm-2). The fractional abundance of ketene is comparable to the predictions of ion-molecule chemistry, while that of thioformaldehyde in TMC-1 is one to two orders of magnitude greater than that expected from such models at steady state. Interstellar sulfur chemistry thus continues to be poorly understood. We set upper limits for the column densities of formic acid (HCOOH), vinyl alcohol (CH2CHOH), methyl formate (HCO2CH3), formamide (NH2CHO), methyl mercaptan (CH3SH), isothiocyanic acid (HNCS), and thioketene (H2C2S) in both sources.     

Assessing trophic adaptability is critical for understanding the response of predatory fishes to climate change: a case study of Pomatomus saltatrix in a global hotspot

There is a growing need to incorporate biotic interactions, particularly those between predators and their prey, when predicting climate-driven shifts in marine fishes. Predators dependent on a narrow range of prey species should respond rapidly to shifts in the distribution of their prey, whereas those with broad trophic adaptability may respond to shifts in their prey by altering their diet. Small pelagic fishes are an extremely important component of the diet of many marine predators. However, their populations are expected to shift in distribution and fluctuate in abundance as the climate changes. We conducted a comparative study of the seasonal diet of adult Pomatomus saltatrix over two periods (June–December 2006 and 2012) and examined the available data on small pelagic fishes biomass in a global hotspot (the coastal region of southern Angola, southern Africa) to gain an understanding of the tropic adaptability of the species. Despite a drop (630 000 t to 353 000 t) in the abundance of their dominant prey (Sardinella aurita) in the region, it remained the most important prey item during both study periods (Period 1 = 99.3% RI, Period 2 = 85.3% RI, where %RI is a ranking index of relative importance). However, the diet during Period 2 was supplemented with prey typically associated with the nearshore zone. The seasonal data showed that P. saltatrix were capable not only of switching their diet from S. aurita to other prey items, but also of switching their trophic habitat from the pelagic to the nearshore zone. These findings suggest that P. saltatrix will not necessarily co-migrate if there is a climate-driven shift in the distribution of small pelagic fishes (their dominant prey). Accordingly, understanding the trophic adaptability of predators is critical for understanding their response to the impacts of climate change.     

Groundwater recharge to a sedimentary aquifer in the topographically closed Uley South Basin, South Australia

The chloride mass balance (CMB) and water-table fluctuation (WTF) analysis methods were used to estimate recharge rates in the Uley South Basin, South Australia. Groundwater hydrochemistry and isotope data were used to infer the nature of recharge pathways and evapotranspiration processes. These data indicate that some combination of two plausible processes is occurring: (1) complete evaporation of rainfall occurs, and the precipitated salts are washed down and redissolved when recharge occurs, and (2) transpiration dominates over evaporation. It is surmised that sinkholes predominantly serve to by-pass the shallow soil zone and redistribute infiltration into the deeper unsaturated zone, rather than transferring rainfall directly to the water table. Chlorofluorocarbon measurements were used in approximating recharge origins to account for coastal proximity effects in the CMB method and pumping seasonality was accounted for in the WTF-based recharge estimates. Best estimates of spatially and temporally averaged recharge rates for the basin are 52?C63 and 47?C129?mm/year from the CMB and WTF analyses, respectively. Adaptations of both the CMB and WTF analyses to account for nuances of the system were necessary, demonstrating the need for careful application of these methods.     

Bosumtwi impact structure,Ghana: Geochemistry of impactites and target rocks,and search for a meteoritic component

Abstract— Major and trace element data, including platinum group element abundances, of representative impactites and target rocks from the crater rim and environs of the Bosumtwi impact structure, Ghana, have been investigated for the possible presence of a meteoritic component in impact‐related rocks. A comparison of chemical data for Bosumtwi target rocks and impactites with those for Ivory Coast tektites and microtektites supports the interpretation that the Bosumtwi structure and Ivory Coast tektites formed during the same impact event. High siderophile element contents (compared to average upper crustal abundances) were determined for target rocks as well as for impactites. Chondrite‐normalized (and iron meteorite‐normalized) abundances for target rocks and impactites are similar. They do not, however, allow the unambiguous detection of the presence, or identification of the type, of a meteoritic component in the impactites. The indigenous siderophile element contents are high and possibly related to regional gold mineralization, although mineralized samples from the general region show somewhat different platinum‐group element abundance patterns compared to the rocks at Bosumtwi. The present data underline the necessity of extensive target rock analyses at Bosumtwi, and at impact structures in general, before making any conclusions regarding the presence of a meteoritic component in impactites.     

Phylogeny of the Sepia officinalis species complex in the eastern Atlantic extends the known distribution of Sepia vermiculata across the Benguela upwelling region

Accurate species identification and biogeographic characterisation are fundamental for appropriate management of expanding cephalopod fisheries. This study addresses this topic within the common cuttlefish Sepia officinalis species complex (S. officinalis, S. hierredda and S. vermiculata), with an emphasis on occurrence in African waters. Tissue samples from the currently presumed distributions of S. vermiculata and S. hierredda (from South Africa and Ghana/Angola, respectively) were sequenced for the cytochrome c oxidase subunit I (COI) and the cytochrome b (cytb) genes of the mitochondrial genome and then compared to existing S. officinalis sequences. Three highly divergent and reciprocally monophyletic clades, corresponding to S. officinalis, S. hierredda and S. vermiculata, were resolved, representing the first molecular confirmation of the distinct species status of S. hierredda and S. vermiculata. The sequences also revealed that, contrary to expectations based on presently published information, all samples from southern Angola were S. vermiculata. These results indicate that the range of S. vermiculata extends beyond the currently described northern limit and that S. hierredda and S. vermiculata may be indiscriminately harvested in Angolan waters. Finer-scale patterns within S. vermiculata phylogeography also indicate that the Benguela Current System and/or other environmental factors serve to isolate northern and southern stocks.     

Saturn's Rings: Azimuthal variations,phase curves,and radial profiles in four colors

Four-color photographic photometry of Saturn for the 1977–1979 apparitions has been analyzed to determine the dependence of ring brightness on wavelength, solar phase angle, ring particle orbital phase angle (azimuthal effect), declination of the Earth relative to the ring plane (tilt angle), and radial distance from Saturn. Azimuthal brightness variations up to ±20% relative to the ansae are clearly apparent for the maximum of ring A, but are not detectable for ring B or the outer portion of ring A. The shape of the intensity (I) versus orbital phase angle (θ) curve varies with ring tilt (B) and probably with wavelength, and shows 180° symmetry. As characterized by its slope near the ansae, this curve suggests that the azimuthal effect increases as B decreases from 26 to ≈11°. The phase curves l(α) for the ansae show very little dependence on ring tilt (26° > B > 6°), on wavelength, or on radial distance from Saturn; possibly the curves are somewhat steeper at the smallest tilt angles and for ring A relative to ring B. The radial profile of both rings becomes flatter with decreasing tilt angle and with decreasing wavelength. The latter effect is a natural result of the classical, many-particle-thick ring model.