Distribution of wave crests in a non-Gaussian sea

The sea elevation at a fixed point is modelled as a quadratic form of a vector valued Gaussian process with arbitrary mean. With this model, saddlepoint methods are used to approximate the mean upcrossing intensity with which the sea level crosses upwards at a certain height. This estimated intensity is further used to determine the probability distribution of wave crests. The use of saddlepoint technique is particularly important here because it can approximate the crest distribution without the need to perform simulations or use fitted distributions. Several numerical examples are given, including two with measured data. In the cases of real data, the results obtained with the saddlepoint technique are also compared with the results obtained with well known methods commonly used in the industry.     

Nickelpicromerite,K<Subscript>2</Subscript>Ni(SO<Subscript>4</Subscript>)<Subscript>2</Subscript>•6H<Subscript>2</Subscript>O,a new picromerite-group mineral from Slyudorudnik,South Urals,Russia

A new picromerite-group mineral, nickelpicromerite, K₂Ni(SO₄)₂?·?6H₂O (IMA 2012–053), was found at the Vein #169 of the Ufaley quartz deposit, near the town of Slyudorudnik, Kyshtym District, Chelyabinsk area, South Urals, Russia. It is a supergene mineral that occurs, with gypsum and goethite, in the fractures of slightly weathered actinolite-talc schist containing partially vermiculitized biotite and partially altered sulfides: pyrrhotite, pentlandite, millerite, pyrite and marcasite. Nickelpicromerite forms equant to short prismatic or tabular crystals up to 0.07 mm in size and anhedral grains up to 0.5 mm across, their clusters or crusts up to 1 mm. Nickelpicromerite is light greenish blue. Lustre is vitreous. Mohs hardness is 2–2½. Cleavage is distinct, parallel to {10–2}. D _meas is 2.20(2), D _calc is 2.22 g cm^?3. Nickelpicromerite is optically biaxial (+), α?=?1.486(2), β?=?1.489(2), γ?=?1.494(2), 2V_meas =75(10)°, 2V_calc =76°. The chemical composition (wt.%, electron-microprobe data) is: K₂O 20.93, MgO 0.38, FeO 0.07, NiO 16.76, SO₃ 37.20, H₂O (calc.) 24.66, total 100.00. The empirical formula, calculated based on 14 O, is: K_1.93Mg_0.04Ni_0.98S_2.02O_8.05(H₂O)_5.95. Nickelpicromerite is monoclinic, P2₁/c, a?=?6.1310(7), b?=?12.1863(14), c?=?9.0076(10) Å, β?=?105.045(2)°, V?=?649.9(1) ų, Z?=?2. Eight strongest reflections of the powder XRD pattern are [d,Å-I(hkl)]: 5.386–34(110); 4.312–46(002); 4.240–33(120); 4.085–100(012, 10–2); 3.685–85(031), 3.041–45(040, 112), 2.808–31(013, 20–2, 122), 2.368–34(13–3, 21–3, 033). Nickelpicromerite (single-crystal X-ray data, R?=?0.028) is isostructural to other picromerite-group minerals and synthetic Tutton’s salts. Its crystal structure consists of [Ni(H₂O)₆]²⁺ octahedra linked to (SO₄)^2? tetrahedra via hydrogen bonds. K⁺ cations are coordinated by eight anions. Nickelpicromerite is the product of alteration of primary sulfide minerals and the reaction of the acid Ni-sulfate solutions with biotite.     

Detrital geochronology of unroofing magmatic complexes and the slow erosion of Oligocene volcanoes in the Alps

Tectonic reconstructions and quantitative models of landscape evolution are increasingly based on detailed analysis of detrital systems. Since the definition of closure temperature in the 1960s, mineral ages of low-temperature geochronometers are traditionally interpreted as the result of cooling induced by erosion, whose rate is a simple, unique function of age patterns. Such an approach can lead to infer paradoxically high erosion rates that conflict with compelling geological evidence from sediment thickness in basins. This indicates that tectonic and landscape models that solely interpret mineral ages as due to cooling during exhumation may not be valid.Here we propose a new approach that takes into account the effects of both crystallization and exhumational cooling on geochronometers, from U–Pb on zircon to fission tracks on apatite. We first model the mechanical erosion of an unroofing magmatic complex and the resulting accumulation and burial of the eroded units in reverse order in the basin. Detrital mineral ages follow a regular pattern downsection. Some mineral ages, such as e.g. U–Pb ages of zircons, cluster around the “magmatic age”, i.e. the crystallization of the magma. Its value is constant along the stratigraphic column in the sedimentary basin; we refer to this behavior as “stationary age peak”. Some other mineral ages, such as e.g. apatite fission-track ages, are often younger than the magmatic age. When they vary smoothly with depth, they define a “moving age peak”, which is the only possible effect of undisturbed cooling during overburden removal, and can therefore be used to calculate an erosion rate.The predictions of our model were tested in detail on the extremely well-studied Bregaglia (Bergell) orogenic pluton in the Alps, and on the sedimentary succession derived from its erosion, the Gonfolite Group. The consistency between predicted and observed age patterns validates the model. Our results resolve a long-standing paradox in quantitative modelling of erosion–sedimentation, namely the scarcity of sediment during apparently fast erosion. Starved basins are the observational baseline, and modelling must be tuned to include a correct analysis of detrital mineral geochronology in order to reconcile perceived discrepancies between stratigraphical and geochronological information. In addition, our data demonstrate that volcanoes were active on top of the growing Oligocene Alps.This study illustrates rigorous criteria for detrital mineral geochronology that are applicable to any geological setting, including magmatic arcs and collision orogens, and provides fundamental interpretive keys to solve complex puzzles and apparent paradoxes in geological reconstructions.     

Anelastic acoustic impedance and the correspondence principle

A general definition of seismic wave impedance is proposed as a matrix differential operator transforming the displacement boundary conditions into traction ones. This impedance is proportional to the standard acoustic impedance at all incidence angles and allows extensions to attenuative media and to the full elastic case. In all cases, reflection amplitudes at the contact of two media are uniquely described by the ratios of their impedances. Here, the anelastic acoustic impedance is studied in detail and attenuation contrasts are shown to produce phase‐shifted reflections. Notably, the correspondence principle (i.e., the approach based on complex‐valued elastic modules in the frequency domain) leads to incorrect phase shifts of the impedance due to attenuation and consequently to wrong waveforms reflected from attenuation contrasts. Boundary conditions and the Lagrange formulation of elastodynamics suggest that elastic constants should remain real in the presence of attenuation and the various types of energy dissipation should be described by their specific mechanisms. The correspondence principle and complex‐valued elastic moduli appear to be applicable only to homogeneous media and therefore they should be used with caution when applied to heterogeneous cases.     

Cretaceous-Eocene compression in the central Southern Alps (N Italy) inferred from Ar/Ar dating of pseudotachylytes along regional thrust faults

The integration of structural analyses with ⁴⁰Ar/³⁹Ar dating of fault-related pseudotachylytes provides time constraints for the reconstruction of the Alpine evolution of the central portion of the South Alpine orogenic wedge. In the northern sector of the belt a Variscan basement is stacked southward on the Permian to Mesozoic cover along regional faults (Orobic and Porcile thrusts). Fault zones, slightly postdating a first folding event of Alpine age, experienced a complex evolution through the ductile and brittle deformation regime, showing greenschist facies mylonites overprinted by a penetrative cataclastic deformation. Generation of fault-related pseudotachylyte veins marks the onset of brittle conditions, lasting up to the youngest episodes of fault activity. ⁴⁰Ar/³⁹Ar dating of the pseudotachylyte matrix of 9 samples give two separated age clusters: Late Cretaceous (80–68 Ma) and latest Palaeocene to Middle Eocene (55–43 Ma). These new data provide evidence that the pre-Adamello evolution of the central Southern Alps was characterised by the superposition of different tectonic events accompanying the exhumation of the deepest part of the belt through the brittle–ductile transition. The oldest pseudotachylyte ages demonstrate that south-verging regional thrusting in the central Southern Alps was already active during the Late Cretaceous, concurrently with the development of a synorogenic foredeep basin where the Upper Cretaceous Lombardian Flysch was deposited.     

Distribution, magnitude and characterization of the toxicity of Ukrainian estuarine sediments

During the Soviet era, Ukraine was an important industrial and agricultural region of the Soviet Union. This industrial and agricultural activity resulted in contamination of Ukraine’s estuaries with legacy anthropogenic pollutants. Investigations on the toxicological effects of this estuarine contamination have been limited. For this research, we measured the toxicity of contaminated sediments from four Ukrainian estuaries to several aquatic organisms over 3 years. Sediment chemical analyses and whole sediment toxicity identification evaluations (TIEs) were also performed to determine the classes of contaminants contributing to toxicity. Toxic sediments were observed in several of the Ukrainian estuaries and chemical analyses of the sediments demonstrated anthropogenic contaminants were widely distributed. Contaminants were also detected in macrobenthic organisms collected from the sediments. Several lines of evidence, including TIEs, indicated hydrophobic organic chemicals (HOCs) were contributing substantially to observed toxicity. This information can guide environmental managers to prioritize portions of the estuaries requiring remediation.     

Hydrochemical system analysis of public supply well fields, to reveal water-quality patterns and define groundwater bodies: The Netherlands

Hydrochemical system analysis (HCSA) is used to better understand the individual state of and spatial patterns in groundwater quality, by addressing the spatial distribution of groundwater bodies with specific origins (hydrosomes) and characteristic hydrochemical zones within each hydrosome (facies). The origin is determined by environmental tracers or geomorphological and potentiometric maps, the facies by combining age, redox and alkalinity indices. The HCSA method is applied to all 206 active public supply well fields (PSWFs) in The Netherlands, resulting in the distinction of nine hydrosomes and eleven facies parameters—age (young, intermediate, old), redox ((sub)oxic, anoxic, deep anoxic, mixed) and alkalinity (very low, low, intermediate and high). The resulting classification of PSWFs provides a means to (1) predict their vulnerability; (2) optimize groundwater-quality monitoring programs; and (3) better delineate groundwater bodies, by considering groundwater origin and flow. The HCSA translates complex hydrochemical patterns into easily interpretable maps by showing PSWFs, groundwater bodies and hydrochemical facies. Such maps facilitate communication between researchers, water resources managers and policy makers and can help to solve complex groundwater resources management problems at different scales, ranging from a single well(field) or region to the national or European scale.     

Long-term variability of sea surface temperature in Taiwan Strait

Long-term variability of sea surface temperature (SST) in the Taiwan Strait was studied from the U.K. Met Office Hadley Centre climatological data set HadISST1. In 1957–2011, three epochs were identified. The first epoch of cooling SST lasted through 1976. The regime shift of 1976–1977 led to an extremely rapid warming of 2.1 °C in 22 years. Another regime shift occurred in 1998–1999, resulting in a 1.0 °C cooling by 2011. The cross-frontal gradient between the China Coastal Current and offshore Taiwan Strait waters has abruptly decreased in 1992 and remained low through 2011. The long-term warming of SST increased towards the East China Sea, where the SST warming in 1957–2011 was about three times that in the South China Sea. The long-term warming was strongly enhanced in winter, with the maximum warming of 3.8 °C in February. The wintertime amplification of long-term warming has resulted in a decrease of the north–south SST range from 5 to 4 °C and a decrease in the amplitude of seasonal cycle of SST from 11 to 8 °C.     

Integration of EO-based vulnerability estimation into EO-based seismic damage assessment: a case study on L’Aquila, Italy, 2009 earthquake

Remote sensing is proving very useful for identifying damage and planning support activities after an earthquake has stricken. Radar sensors increasingly show their value as a tool for damage detection, due to their shape-sensitiveness, their extreme versatility and operability, all weather conditions. The previous work of our research group, conducted on 1-m resolution spotlight images produced by COSMO-SkyMed, has led to the discovery of a link between some selected texture measures, computed on radar maps over single blocks of an urban area, and the damage found in these neighbourhoods. Texture-to-damage correlation was used to develop a SAR-based damage assessment method, but significant residual within-class variability makes estimations sometimes unreliable. Among the possible remedies, the injection of physical vulnerability data into the model was suggested. The idea here is to do so while keeping all the sources of data in the EO domain, by estimating physical vulnerability from the observation of high-resolution optical data on the area of interest. Although preliminary results seem to suggest that no significant improvement can be directly obtained on classification accuracy, there appears to be some link between estimated damage and estimated accuracy on which to build a more refined version of the damage estimator.