Piecewise‐continuous velocity inversion

We suggest a new method to determine the piecewise‐continuous vertical distribution of instantaneous velocities within sediment layers, using different order time‐domain effective velocities on their top and bottom points. We demonstrate our method using a synthetic model that consists of different compacted sediment layers characterized by monotonously increasing velocity, combined with hard rock layers, such as salt or basalt, characterized by constant fast velocities, and low velocity layers, such as gas pockets. We first show that, by using only the root‐mean‐square velocities and the corresponding vertical travel times (computed from the original instantaneous velocity in depth) as input for a Dix‐type inversion, many different vertical distributions of the instantaneous velocities can be obtained (inverted). Some geological constraints, such as limiting the values of the inverted vertical velocity gradients, should be applied in order to obtain more geologically plausible velocity profiles. In order to limit the non‐uniqueness of the inverted velocities, additional information should be added. We have derived three different inversion solutions that yield the correct instantaneous velocity, avoiding any a priori geological constraints. The additional data at the interface points contain either the average velocities (or depths) or the fourth‐order average velocities, or both. Practically, average velocities can be obtained from nearby wells, whereas the fourth‐order average velocity can be estimated from the quartic moveout term during velocity analysis. Along with the three different types of input, we consider two types of vertical velocity models within each interval: distribution with a constant velocity gradient and an exponential asymptotically bounded velocity model, which is in particular important for modelling thick layers. It has been shown that, in the case of thin intervals, both models lead to similar results. The method allows us to establish the instantaneous velocities at the top and bottom interfaces, where the velocity profile inside the intervals is given by either the linear or the exponential asymptotically bounded velocity models. Since the velocity parameters of each interval are independently inverted, discontinuities of the instantaneous velocity at the interfaces occur naturally. The improved accuracy of the inverted instantaneous velocities is particularly important for accurate time‐to‐depth conversion.     

Normal moveout velocity for pure‐mode and converted waves in layered orthorhombic medium

We study the azimuthally dependent hyperbolic moveout approximation for small angles (or offsets) for quasi‐compressional, quasi‐shear, and converted waves in one‐dimensional multi‐layer orthorhombic media. The vertical orthorhombic axis is the same for all layers, but the azimuthal orientation of the horizontal orthorhombic axes at each layer may be different. By starting with the known equation for normal moveout velocity with respect to the surface‐offset azimuth and applying our derived relationship between the surface‐offset azimuth and phase‐velocity azimuth, we obtain the normal moveout velocity versus the phase‐velocity azimuth. As the surface offset/azimuth moveout dependence is required for analysing azimuthally dependent moveout parameters directly from time‐domain rich azimuth gathers, our phase angle/azimuth formulas are required for analysing azimuthally dependent residual moveout along the migrated local‐angle‐domain common image gathers. The angle and azimuth parameters of the local‐angle‐domain gathers represent the opening angle between the incidence and reflection slowness vectors and the azimuth of the phase velocity ψ_phs at the image points in the specular direction. Our derivation of the effective velocity parameters for a multi‐layer structure is based on the fact that, for a one‐dimensional model assumption, the horizontal slowness and the azimuth of the phase velocity ψ_phs remain constant along the entire ray (wave) path. We introduce a special set of auxiliary parameters that allow us to establish equivalent effective model parameters in a simple summation manner. We then transform this set of parameters into three widely used effective parameters: fast and slow normal moveout velocities and azimuth of the slow one. For completeness, we show that these three effective normal moveout velocity parameters can be equivalently obtained in both surface‐offset azimuth and phase‐velocity azimuth domains.     

Magnetic studies at Starunia paleontological and hydrocarbon bearing site (Carpathians,Ukraine)

The Starunia oil-ozokerite deposit occurs in the Boryslav-Pokuttya Unit of the Carpathian Foredeep, which is the main oil- and gas-bearing part of the Ukrainian Carpathians. Starunia is of great interest in studying the relationship between the magnetic properties of rocks, soils and hydrocarbons due to extensive surface microseeps yielding oil and gas, mineral water, and clay pulp containing hydrocarbons. We identified a local negative magnetic anomaly (30–35 nT) with a width of about 700 m within the MAG1 profile. The magnetic high is associated with the area of the largest mud volcanoes in the Starunia structure. Magnetic susceptibility of the soil was measured on a site with three distinct landscape features: a patch of forest with phaeozem and mass-specific susceptibility (χ) of 20–45 × 10^?8 m³/kg for the surface topsoil; an area near the volcano and Nadia-1 well with visible hydrocarbon microseepage at the surface and the topsoil showing no visible evidence of hydrocarbon presence with χ = 20–50 × 10^?8 m³/kg; and a patch of lowland with gleysols and χ = 10–20 × 10^?8 m³/kg. Hydrocarbon-containing clays and soils from the alluvial sediments of the Velyky Lukavets River and bedrock clays near the Nadia-1 well demonstrated high χ values (up to 250–440 × 10^?8 m³/kg).     

Seismic activity and deep conductivity structure of the Eastern Carpathians

We present results of a study of the seismicity and the geoelectric structure of the Eastern Carpathians. After the evaluation of the seismicity, new methods of processing and analyzing seismic data are developed, which allow constructing an averaged horizontal-layered velocity model of the crust in the Carpathian region of Ukraine, tracing the seismic active faults and localizing the seismic events both in horizontal and in vertical direction with a better precision. For the study of the conductivity structure beneath the Eastern Carpathians, the collected magnetovariation and magnetotelluric data are used. The depth of electrical conductivity anomalies are estimated and the resulting quasi-3D model of the conductivity structure beneath the Carpathians is compared with the seismicity in the depth range of 10 ± 2.5 km. The comparison suggests possible geological mechanisms: the seismic events occur mainly in resistive solid rock domains which surround aseismic high-conductivity zones, consisting of at least partially melted material. Aqueous fluids, or a joint effect of several mechanisms, may also play an active role in this distribution.     

Recent Efforts Toward the Establishment of the Lonjsko Polje Geomagnetic Observatory

More than ten years ago, the Geophysical Institute initiated the installation of a geomagnetic observatory in Croatia. Over the past decade, extensive surveys and studies have been conducted in order to determine the proper location for the observatory. Finally, in 2012, the observatory was established in Lonjsko Polje. This paper presents the first data recorded in the period 2012.5-2015.0. Also presented are the technical aspects and data processing techniques of this remotely operated observatory. Analysis of data quality and comparison with data from the surrounding INTERMAGNET observatories is discussed in detail. Although remote observatories cannot provide the ideal environment for magnetometers, the obtained results accentuate the potential of the new observatory to provide high-quality data. The establishment of this observatory paves the way for scientific and professional development of geomagnetism in Croatia.     

Fronts in Large Marine Ecosystems

Oceanic fronts shape marine ecosystems; therefore front mapping and characterization are among the most important aspects of physical oceanography. Here we report on the first global remote sensing survey of fronts in the Large Marine Ecosystems (LME). This survey is based on a unique frontal data archive assembled at the University of Rhode Island. Thermal fronts were automatically derived with the edge detection algorithm of (Cayula and Cornillon, 1992), (Cayula and Cornillon, 1995) and (Cayula and Cornillon, 1996) from 12 years of twice-daily, global, 9-km resolution satellite sea surface temperature (SST) fields to produce synoptic (nearly instantaneous) frontal maps, and to compute the long-term mean frequency of occurrence of SST fronts and their gradients. These synoptic and long-term maps were used to identify major quasi-stationary fronts and to derive provisional frontal distribution maps for all LMEs. Since SST fronts are typically collocated with fronts in other water properties such as salinity, density and chlorophyll, digital frontal paths from SST frontal maps can be used in studies of physical–biological correlations at fronts. Frontal patterns in several exemplary LMEs are described and compared, including those for: the East and West Bering Sea LMEs, Sea of Okhotsk LME, East China Sea LME, Yellow Sea LME, North Sea LME, East and West Greenland Shelf LMEs, Newfoundland–Labrador Shelf LME, Northeast and Southeast US Continental Shelf LMEs, Gulf of Mexico LME, and Patagonian Shelf LME. Seasonal evolution of frontal patterns in major upwelling zones reveals an order-of-magnitude growth of frontal scales from summer to winter. A classification of LMEs with regard to the origin and physics of their respective dominant fronts is presented. The proposed classification lends itself to comparative studies of frontal ecosystems.     

Disks and outflows in the S255IR area of high mass star formation from ALMA observations

We describe the general structure of the well known S255 IR high mass star forming region,as revealed by our recent ALMA observations. The data indicate a physical relation exists between the major clumps SMA1 and SMA2. The driving source of the extended high velocity, well collimated bipolar outflow, is not the most pronounced disk-like SMA1 clump harboring a 20 M_⊙young star(S255 NIRS3), as was assumed earlier. Apparently, it is the less evolved SMA2 clump, which drives the outflow and contains a compact rotating structure(probably a disk). At the same time, the SMA1 clump drives another outflow, with a larger opening angle. The molecular line data do not show an outflow from the SMA3 clump(NIRS1), which was suggested by IR studies of this region.     

Cloning a new cytochrome P450 isoform (CYP356A1) from oyster Crassostrea gigas

We have cloned the full-length cDNA of the first member of a new cytochrome P450 (CYP) family from the Pacific oyster Crassostrea gigas. This new CYP gene was obtained based on an initial 331bp fragment previously identified among the list of the differentially expressed genes in oysters exposed to untreated domestic sewage. The full-length CYP has an open reading frame of 1500bp and based on its deduced amino acid sequence was classified as a member of a new subfamily, CYP356A1. A phylogenetic analysis showed that CYP356A1 is closely related to members of the CYP17 and CYP1 subfamilies. Semi-quantitative RT-PCR was performed to analyze the CYP356A1 expression in different tissues of the oyster (digestive gland, gill, mantle and adductor muscle). Results showed slightly higher CYP356A1 expression in digestive gland and mantle, than the other tissues, indicating a possible role of the CYP356A1 in xenobiotic biotransformation and/or steroid metabolism.