An Intercomparison of Large-Eddy Simulations of the Stable Boundary Layer

Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL.     

Spheroidal equal angular DEMs: The specificity of morphometric treatment

Digital elevation models (DEMs) are commonly constructed using two main types of regular grids: plane square grids and spheroidal equal angular grids. Methods and algorithms intended for plane square‐gridded DEMs should not be directly applied to spheroidal equal angular DEMs. This is because these grids have fundamentally different geometry. However, some researchers continue to apply square‐grid algorithms to spheroidal equal angular DEMs. It seems appropriate to consider once again the specifity of morphometric treatment of spheroidal equal angular DEMs. This article, first, demonstrates possibilities of direct calculation of local, nonlocal, and combined morphometric variables from spheroidal equal angular DEMs exemplified by slope gradient, catchment area, and topographic index. Second, the article shows computational errors when algorithms for plane square‐gridded DEMs are unreasonably applied to spheroidal equal angular DEMs. The study is exemplified by two DEMs. A medium‐resolution DEM of a relatively small, high‐mountainous area (Mount Elbrus) was extracted from the SRTM1 DEM. A low‐resolution DEM of a vast region with the diverse topography (the central and western regions of Kenya) was extracted from the SRTM30_PLUS DEM. The results show that application of square‐grid methods to spheroidal equal angular DEMs leads to substantial computational errors in models of morphometric variables.     

K-Ar datability of altered rocks: variability of excess Ar in hydrothermal minerals

⁴⁰Ar/³⁹ Ar stepwise heating on one hydrothermal anhydrite and two partly hydrothermalized feldspars from a borehole in Vulcano volcano show that the initial trapped Ar does not have a constant isotopic composition. The constant ⁴⁰Ar/³⁶Ar ratio of the anhydrite, 306±3, is not a well-defined endmember for the two feldspars, which record a variety of fluid compositions. As the system is young (<100 ka), radiogenic Ar is much less than excess Ar.     

Compliance of the Parties to the Kyoto Protocol in the first commitment period

This article provides an ex post analysis of the compliance of the Parties to the Kyoto Protocol during the first commitment period (2008–2012) based on the final data for national GHG emissions and exchanges in carbon units that became available at the end of 2015. On the domestic level, among the 36 countries that fully participated in the Kyoto Protocol, only nine countries emitted higher levels of GHGs than committed and therefore had to resort to flexibility mechanisms. On the international level – i.e. after the use of flexibility mechanisms – all Annex B Parties are in compliance. Countries implemented different compliance strategies: purchasing carbon units abroad, stimulating the domestic use of carbon credits by the private sector and incentivizing domestic emission reductions through climate policies.

Overall, the countries party to the Protocol surpassed their aggregate commitment by an average 2.4 GtCO₂e yr^–1. Of the possible explanations for this overachievement, ‘hot-air’ was estimated at 2.2 GtCO₂e yr^–1, while accounting rules for land use, land-use change and forestry (LULUCF) further removed 0.4 GtCO₂e yr^–1 from the net result excluding LULUCF. The hypothetical participation of the US and Canada would have reduced this overachievement by a net 1 GtCO₂e yr^–1. None of these factors – some of which may be deemed illegitimate – would therefore on its own have led to global non-compliance, even without use of the 0.3 GtCO₂e of annual emissions reductions generated by the Clean Development Mechanism. The impact of domestic policies and ‘carbon leakage’ – neither of which is quantitatively assessed here – should not be neglected either.

Policy relevance

Given the ongoing evolution of the international climate regime and the adoption of the Paris Agreement in December 2015, we believe that there is a need to evaluate the results of the first commitment period of the Kyoto Protocol. To our knowledge there has been no overarching quantitative ex post assessment of the Kyoto Protocol based on the final emissions data for 2008–2012, which became available in late 2015. This article attempts to fill this gap, focusing on the domestic and international compliance of the Parties to the Kyoto Protocol in the first commitment period.     

Oxygen radicals production and actin filament disruption in bivalve haemocytes treated with benzo(a)pyrene

Haemocytes play an essential role in the internal defence of molluscs. It has been reported that organic xenobiotics commonly found as pollutants in the marine environment impair defence capabilities of haemocytes. The purpose of the present study was to investigate the effects of benzo(a)pyrene [B(a)P] on the integrity of the actin cytoskeleton and on endocytosis in haemocytes and to see if these effects are related to generation of reactive oxygen species. Haemocytes were exposed in vitro to B(a)P (0.5–40 μg/ml) for 1 h. Cell viability (using 2,3-bis[2-methoxy-4-nitro-5-sulfophenyl]-2H-tetrazolium-5-carboxanilide or XTT assay) indicated that selected doses were sublethal. Uptake of neutral red was significantly decreased in a dose-dependent manner in B(a)P-treated haemocytes. Distribution of actin filaments, labeled with rhodamine-conjugated phalloidin, was altered in haemocytes treated with 20 or 40 μg/ml B(a)P. These effects could be related to an increased production of superoxide anion during B(a)P metabolism, as detected by the nitroblue tetrazolium (NBT) reduction assay in haemocytes treated with 10 μg/ml B(a)P.     

Doppler-shift approximations of encountered wave statistics

In this paper the joint density of waveheight and half-wavelength is considered for waves observed at a fixed time point and encountering waves that are overtaking a ship from behind. The densities for these two cases are related by a Doppler shift, expressed in terms of the relative velocity of the waves and the ship. Based on this observation, an approximation of the encountered density is proposed. This approximation is then investigated for a Gaussian sea having a Pierson–Moskowitz spectrum.