White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

Irish on the move

Trends in emigration from Ireland over time are reviewed. "During the eighteenth and nineteenth centuries overseas migration to the United States and seasonal harvest migration to Britain were the main types of movement, but over the past 100 years the Irish have developed a special affinity for settling in British towns. Although the outflow was halted for a time during the 1970s, when return migration took over, the 1980s have seen a renewal of the exodus. This time, however, the character of the flow has changed from predominantly low-skill construction and factory workers to embrace better-educated emigrants, including many graduates. This shift reflects Ireland's changing position in the international market for labour."     

Diffusion-deposition patterns in Martian streaks

The spreading angle of a number of light and dark Martian streaks is determined from selected Mariner 9 images. The resulting frequency distributions of spreading half-angles have maxima at ～5° for light, and ～7° for dark streaks; however the dark streaks have a secondary maximum spreading angle at ～14°. The smaller values, which include most streaks, are interpreted as crater-wake spreading phenomena. The larger value, found in only a few dark streaks or “tails,” may result from atmospheric diffusion and subsequent deposition of material from isolated sources such as vents or blowouts. An atmospheric diffusion-deposition analysis is presented, assuming this streak origin, from which it is possible to deduce the eddy diffusivity, K, in Mars' boudary layer. Calculated K values are found to agree with various theoretical estimates. They lie in the range 10⁷ and 10⁹ cm² sec^?1 and exhibit the proper scale dependence. Thus it appears that, in addition to streak-derived wind direction patterns and speed information, it is possible in a few cases to derive information on Mars' boundary-layer turbulence from streak-spreading measurements.     

Habitat, occurrence and conservation of Saharo-Arabian-Turanian element Forsskaolea tenacissima L. in the Iberian Peninsula

The aim of this study is to assess the Iberian populations of Forsskaolea tenacissima L. according to its biogeographical interest, habitat, geographical range and conservation status. Results point out that they are restricted to gravel wadis of Tabernas Desert (SE Spain), are scarcely included in protected areas and represent historically isolated populations with relict behaviour. We also describe a new association, Senecioni-Forsskaoleetum tenacissimae. Conservation status of species is cause for concern and two conservation actions must be carried out. Firstly, protected areas should house Forsskaolea populations and secondly, phytosociological characterization of a community allows inventorying its habitat and directing conservation efforts to community level.