Oil pollution of the anabranches of the Ob river on the territory of Khanty-Mansi Autonomous Okrug–Yugra

An analysis is made of the oil pollution of the Ob river waters using a long-term (1993–2013) hydrochemical monitoring of oil fields in Khanty-Mansi Autonomous Okrug. Contents of oil hydrocarbons (OHC) were determined in 4277 samples from the main Ob channel, and in 7076 samples from its anabranches by using infrared spectrometry. An increase in MAC (0.05 mg/dm³) was observed in 28% of the samples from the main channel, and in 32% from the anabranches. The total percentage of samples with an extremely high (> 50 MAC) and high (30–50 MAC) pollution level made up 0.3% of the samples for the anabranches, and 0.1% for the main channel. Maximum pollution was revealed in the eastern part of Okrug, from its eastern boundary to the mouth of the Trom’egan river which is associated with a considerable number of accidents on the pipelines within the Nizhnevartovskii district. The upper and lower quantiles in the most polluted anabranches, Pasl and Bagras, are 0.03–01.7 and 0.032–0.16 mg/dm³, respectively, whereas in the main Ob channel they vary from 0.022 to 0.065 mg/dm³ (0.4–1.2 MAC). The methods of geoinformatics and mathematical statistics were used to assess a dependence of OHC on the number of pollution sources (well clusters, and the area of oil spills) in zones at different distances from the river channels. By calculating the Spearman correlation coefficients, it was shown that OHC contents are dependent mainly on the number of wells, and on the area of oil spills located at less than 2 km from the channels.     

The Eastern Congo—a beauty spot,rediscovered from a geological point of view

In East Africa, the feedback between tectonic uplift, erosional denudation and associated possible climate changes is being studied by a multidisciplinary research group, ‘Riftlink’. The group's focus is the Albertine Rift, the northern part of the western branch of the East African Rift System, and in particular the rising Rwenzori Mountains that stretch along the border of the D.R. Congo and Uganda. Major questions relate to the timing of the formation of the Rwenzori Mountains, and whether the height of these mountains (> 5000 m) relates to rift movements in Neogene times, or represents an old basement block that formed a topographic high long before. Though, at first, research concentrated on the eastern (Ugandan) part of the Albertine Rift and Rwenzori Mountains, it has now moved further to the west to the D.R. Congo. A first field‐campaign, covering the area from northern Lake Edward along the rift shoulder up to the Blue Mountains at Lake Albert, was conducted in summer 2009, in cooperation with the Ruwenzori State University of Butembo. Here, we present a brief overview of the field‐campaign, with impressions gathered on the morphology and geology of the study area.     

Estimation of unrecorded groundwater abstractions in Jordan through regional groundwater modelling

Jordan suffers from water scarcity and groundwater covers the majority of Jordan’s water supply. Therefore, there is an urgent need to manage this resource conscientiously. A regional numerical groundwater flow model, developed as part of a decision support system for the country of Jordan, allows for quantification of the overexploitation of groundwater resources and enables determination of the extent of unrecorded agricultural groundwater abstraction. Groundwater in Jordan is abstracted from three main aquifers partly separated by aquitards. With updated geological, structural, and hydrogeological data available in the country, a regional numerical groundwater flow model for the whole of Jordan and the southernmost part of Syria was developed using MODFLOW. It was first calibrated for a steady-state condition using data from the 1960s, when groundwater abstraction was negligible. After transient calibration using groundwater level measurements from all aquifers, model results reproduce the large groundwater-level declines experienced in the last decades, which have led to the drying out of numerous springs. They show a reversal of groundwater flow directions in some regions, due to over-abstraction, and demonstrate that documented abstractions are not sufficient to cause the observed groundwater-level decline. Only after considering irrigation water demand derived from remote sensing data, the model is able to simulate these declines. Illegal abstractions can be quantified and predictive scenarios show the potential impact of different management strategies on future groundwater resources.

     

A computer program for interpreting vertical magnetic anomalies of spheres and horizontal cylinders

Summary A common computer program for the interpretation of vertical magnetic anomalies of spheres and horizontal cylinders has been developed. The input consists of the observed anomalies noted against their distances measured from an arbitrary point in the profile and a code number for each model. The program is written so that the positions and magnitudes of the maximum and minimum anomalies are located and their ratios and signs are used to define the initial parameters of the model under consideration. The errors resulting from these approximate values are derived and are solved for the increments to be given to the initial values. The process is repeated until the sum of the squares of the errors is less than 0.25% of the sum of the squares of the observed anomalies. The method has been tested on various theoretical examples and the results justify the validity of the programme.     

Characterization of deep saline aquifers in the Bécancour area,St. Lawrence Lowlands,Québec,Canada: implications for CO2 geological storage

The present paper provides a case study of the assessment of the potential for CO₂ storage in the deep saline aquifers of the Bécancour region in southern Québec. This assessment was based on a hydrogeological and petrophysical characterization using existing and newly acquired core and well log data from hydrocarbon exploration wells. Analyses of data obtained from different sources provide a good understanding of the reservoir hydrogeology and petrophysics. Profiles of formation pressure, temperature, density, viscosity, porosity, permeability, and net pay were established for Lower Paleozoic sedimentary aquifers. Lateral hydraulic continuity is dominant at the regional scale, whereas vertical discontinuities are apparent for most physical and chemical properties. The Covey Hill sandstone appears as the most suitable saline aquifer for CO₂ injection/storage. This unit is found at a depth of more than 1 km and has the following properties: fluid pressures exceed 14 MPa, temperature is above 35 °C, salinity is about 108,500 mg/l, matrix permeability is in the order of 3 × 10^?16 m² (0.3 mDarcy) with expected higher values of formation-scale permeability due to the presence of natural fractures, mean porosity is 6 %, net pay reaches 282 m, available pore volume per surface area is 17 m³/m², rock compressibility is 2 × 10^?9 Pa^?1 and capillary displacement pressure of brine by CO₂ is about 0.4 MPa. While the containment for CO₂ storage in the Bécancour saline aquifers can be ensured by appropriate reservoir characteristics, the injectivity of CO₂ and the storage capacity could be limiting factors due to the overall low permeability of aquifers. This characterization offers a solid basis for the subsequent development of a numerical hydrogeological model, which will be used for CO₂ injection capacity estimation, CO₂ injection scenarios and risk assessment.     

Validating and assessing the sensitivity of the climate model with an ocean general circulation model developed at the Institute of Atmospheric Physics,Russian Academy of Sciences

A new version of the Institute of Atmospheric Physics, Russian Academy of Sciences (IAP RAS), climate model (CM) has been developed using an ocean general circulation model instead of the statistical-dynamical ocean model applied in the previous version. The spatial resolution of the new ocean model is 3° in latitude and 5° in longitude, with 25 unevenly spaced vertical levels. In the previous version of the oceanic model, as in the atmospheric model, the horizontal resolution was 4.5° in latitude and 6° in longitude, with four vertical levels (the upper quasi-homogeneous layer, seasonal thermocline, abyssal ocean, and bottom friction layer). There is no correction for the heat and momentum fluxes between the atmosphere and ocean in the new version of the IAP RAS CM. Numerical experiments with the IAP RAS CM have been performed under current initial and boundary conditions, as well as with an increasing concentration of atmospheric carbon dioxide. The main simulated atmospheric and oceanic fields agree quite well with observational data. The new version’s equilibrium temperature sensitivity to atmospheric CO₂ doubling was found to be 2.9 K. This value lies in the mid-range of estimates (2–4.5 K) obtained from simulations with state-of-the-art models of different complexities.     

Isotope Constraints on the Aquatic Carbon Budget: Langat Watershed,Malaysia

Langat River drains a tropical watershed in the southwest of the Malaysian Peninsula. The watershed is heavily urbanized in its downstream portion. Water samples were collected from May 2010 to December 2011, at three localities along the main stem river, 1 location at its Semenyih tributary and from an upstream groundwater source. Concentration and δ¹³C data of riverine DIC and DOC indicate the dominance of C3 plant-derived material as the primary source of carbon, with δ¹³C_DIC values enriched in ¹³C relative to that of the C3 source. This enrichment is likely due to CO₂ outgassing, as calculated concentrations of riverine CO₂ are significantly higher than ambient atmospheric values, with methanogenic activity a theoretically possible contributing factor, particularly at the upstream location. The Langat River therefore acts as a net source of CO₂, with a total sub-basin flux of 19.7 × 10³ t C year^?1. This is comparable to the sum of riverine DOC, DIC and POC loss rates from the sub-basin, calculated as 24.5 × 10³ t C year^?1, and highlights the significance of CO₂ evasion from water bodies to the atmosphere for balancing the budget of the terrestrial carbon cycle. The DIC and DOC concentration and δ¹³C data also suggests that in the more urbanized downriver areas, much of the organic carbon input may be anthropogenicaly derived due to ubiquity of sewage treatment plants and landfill sites. Such human-induced perturbations to riverine carbon cycling should be taken into account in future studies of urbanized watersheds.     

Analysis of a “flickering” Geminid fireball

Abstract— In the early morning hours of December 13, 2002, a bright Geminid fireball with an absolute magnitude of ?9.2 ± 0.5 was observed from Southern Saskatchewan, Canada. The fireball displayed distinct small‐scale oscillations in brightness, or flickering, indicative of the parent meteoroid being both non‐spherical and rotating. Using the light curve derived from a calibrated radiometer, we determine a photometric mass of 0.429 ± 0.15 kg for the meteoroid, and we estimate from its initial rotation rate of some 6 Hz that the meteoroid was ejected from the parent body (3200) Phaethon some 2500 ± 500 years ago. We find that 70% of Geminid fireballs brighter than magnitude ?3 display distinct flickering effects, a value that is in stark contrast to the 18% flickering rate exhibited by sporadic fireballs. The high coincidence of flickering and the deep atmospheric penetration of Geminid fireballs are suggestive of Geminid meteoroids having a highly resilient structure, a consequence, we suggest, of their having suffered a high degree of thermal processing. The possibility of Gemind material surviving atmospheric ablation and being sampled is briefly discussed, but the likelihood of collecting and identifying any such material is admittedly very small.     

Equations of kinetic and available potential energy evolution in wave-number frequency space

The equations of kinetic and available potential energy for the analysis of the growth and decay of atmospheric waves in wave-number-frequency space are derived. The effects of linear and nonlinear interactions of waves in the velocity and temperature fields, the conversions between the available potential and kinetic energies, and the Reynolds and molecular stresses on wave growth and decay are discussed.