Fluid inclusion and stable isotope characteristics of the Karalar (Gazipaşa,Antalya) barite-galena deposits,Southern Turkey

The Karalar galena-barite deposits are typical examples of the carbonate-hosted barite-galena deposits widely occurring in the Central Tauride Belt. These deposits are located in Permian limestones as ore veins along fault zones that are discordant to the bedding planes and as thin veinlets within hardly brecciated bottom zones of Permian limestones. The ore deposits contain mainly barite and galena and small amounts of sphalerite, pyrite, fahlore, limonite, quartz, and calcite. Barites occur during the earlier episode of mineralization and were mylonitized before the formation of galena. Galena and other minerals occur epigenetically with barite along porous zones between brecciated barite crystals and are especially abundant in the hardly mylonitized zones. Fluid inclusion studies indicate that the ore deposits of the area were developed by hydrothermal fluids with following characteristics: they contained NaCl, CaCl₂, and MgCl₂; the salinity of the fluids was relatively high and their temperature was low during the crystallization of barites in the earlier episode of mineralization; and the salinity of the fluids decreased and their temperature increased during the crystallization of sulfide minerals through the later episode of mineralization. δ₁₈O and the δD results indicate that the water in the mineralizing fluid was of meteoric origin. The deposits were formed by deep meteoric water circulating through marine sediments. Shallow circulating and slightly warmed fluids dissolved Ba and sulfate from marine sediments of the basement and transported them to the mineralization environment during the early episode, while deep circulating and more heated fluids dissolved Pb, Zn, and other elements from the basement and reached the environment during the later episode of mineralization. The text was submitted by the authors in English.     

Elpasolite from hyperalkaline pegmatite of the Khibiny pluton, Kola Peninsula. Symmetry of elpasolite

Elpasolite, K₂NaAlF₆, has been found for the first time in a pegmatite related to peralkaline foid syenite at Mt. Koashva, Khibiny alkaline pluton, Kola Peninsula, Russia, as pale pink octahedral crystals up to 2 mm in size within cavities in the natrolite core of pegmatite in association with amicite, sodalite, aegirine, pectolite, catapleiite, sitinakite, lemmleinite-K, and vinogradovite. The chemical composition determined with an electron microprobe is as follows, wt %: 31.53 K; 9.22 Na; 11.20 Al; 47.21 F; total is 99.16. The empirical formula is K_1.96Na_0.98Al_1.01F_6.05. The infrared spectrum is given. The crystal structure has been refined to R = 0.030, space group Fm $ \bar 3 Elpasolite, K₂NaAlF₆, has been found for the first time in a pegmatite related to peralkaline foid syenite at Mt. Koashva, Khibiny alkaline pluton, Kola Peninsula, Russia, as pale pink octahedral crystals up to 2 mm in size within cavities in the natrolite core of pegmatite in association with amicite, sodalite, aegirine, pectolite, catapleiite, sitinakite, lemmleinite-K, and vinogradovite. The chemical composition determined with an electron microprobe is as follows, wt %: 31.53 K; 9.22 Na; 11.20 Al; 47.21 F; total is 99.16. The empirical formula is K_1.96Na_0.98Al_1.01F_6.05. The infrared spectrum is given. The crystal structure has been refined to R = 0.030, space group Fm m, a = 8.092 ?. The result of a special X-ray powder diffraction study confirmed the suggestion made by Morss (1974) that reflections violating space group Fm m in some published X-ray powder patterns of natural elpasolite are Kβ-lines. Original Russian Text ? I.V. Pekov, N.V. Chukanov, N.N. Kononkova, N.V. Zubkova, M.Kh. Rabadanov, D.Yu. Pushcharovsky, 2007, published in Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 2007, No. 6, pp. 76–84.     

Rare earth elements in tourmaline and chlorite from tin-bearing assemblages: Factors controlling fractionation of REE in hydrothermal systems

The REE distribution in minerals from tin-bearing ore-magmatic systems of the Russian Far East, including the Komsomolsk, Khingan, and Badzhal districts in the Amur region and the Kavalerovo, Lesozavodsk, Voznesenka, Furmanovo, and other districts in Primorsky krai, has been studied. The main attention was focused on tourmaline and chlorite; in addition, associated biotite, feldspar, apatite, fluorite, and carbonates were examined. The major factors affecting the REE distribution in the studied minerals are the temperature, Eh, and pH of the mineral-forming medium; crystal chemistry; partition coefficients of REE between fluid and minerals; and complexation that disturbs the coherent behavior of REE. Fluid evolution at different stages is characterized.     

Normative quartz as an indicator of the mass transfer intensity during the postmagmatic alteration of the Botuobinskaya pipe kimberlites (Yakutia)

The intensity of postmagmatic processes in the Botuobinskaya pipe kimberlites was estimated from the calculated content of normative secondary quartz (Q). Several simple algorithms are proposed to calculate the Q content from chemical analyses of kimberlites. Ten groups of altered kimberlites have been recognized from the Q contents. The contents of MgO, some trace elements, and LREE in the groups, the contents of Cr and Ca of crimson garnets, the diamond contents of kimberlites, and the average weight of diamonds decrease as the Q content increases. It is shown that the negative SiO₂–MgO correlation is the most effective indicator of the postmagmatic alteration of kimberlites. As the degree of their secondary alteration increases, the kimberlites transform into an assemblage of quartz and clay minerals enriched in some trace elements and almost completely lacking REE and diamonds.     

Melt inclusions in eclogite garnet: experimental study of natural processes

Experiment with poikilitic garnet at 3 GPa and 800 °C showed dehydration melting of its mineral inclusions, which is accompanied by the growth of (sub)euhedral garnet crystals inside the inclusion and/or xenomorphic garnets replacing the host mineral. The newly formed and host garnets differ drastically in composition. The inclusion surface is complicated by specific wedge-like protrusions or thin branches composed of melt or its crystallization products. The above features have been discovered in polymineral inclusions in garnet from low-temperature (650 °C) eclogite from the Yukon-Tanana terrane, Canada. The inclusions are interpreted as the crystallization products of in situ formed melt.     

New data on the correlation of skarn and gold mineralization at the Tardan deposit (northeastern Tuva)

Gold mineralization of the Tardan deposit is of different spatial occurrences and is related to different hydrothermal-metasomatic formations, the main ones being skarn-magnetite bodies, metasomatites of mineralized crush zones, and metasomatites of argillizitic-rock association. The formation of gold mineralization was a multistage process related to the repeated magmatism of the Tannu-Ola complex. It took place in a wide temperature range (400–150 °C), which determined the diversity of produced mineral assemblages. The gold mineralization associated with magnetite bodies shows a spatial correlation with magnesian and calcareous skarns and is localized in plagiogranites and gabbro-diorites of the Tannu-Ola complex intruded in the Late Ordovician. Gold mineralization that occurs in crush zones and along the fault sutures in moderate- and low-temperature hydrothermal-metasomatic rocks (propylites, beresites, serpentinites, and argillizites) formed somewhat later than skarns as a result of the intrusion of granite dike bodies. Comparative analysis of different types of gold mineralization showed both a change of mineral assemblages of the gold mineralization during the ore formation and some geochemical difference between gold and gold-bearing ores. In passing from early to late occurrences of native gold, its fineness decreases, the contents of admixtures correspondingly increase, and the gold composition changes. Gold of high-temperature rocks is rich in Cu (up to 17%), and gold of low-temperatures rocks has higher contents of Ag and Hg.     

Soil-to-dwelling radon isotope ratio in the Baikal region

Relations between indoor and soil gas radon were experimentally studied in villages of the Baikal region. On the basis of the obtained data, the soil-to-indoor radon ratio was calculated, which can be used for prediction of radon pollution in buildings of the same kind.     

Climatic changes and alluvial-sedimentation settings in southeastern Transbaikalia in the Middle-Late Holocene (by the example of the Ilya floodplain)

Climatic changes in southeastern Transbaikalia in the Middle and Late Holocene and their influence on alluvial sedimentation environments are reconstructed from the results of study of the Ilya floodplain sediments (Alkhanai National Park). At the beginning of the Subboreal period, the regional climate became more arid, which led to a significant increase in steppe species communities in the landscapes. Intense climate aridization also took place at the beginning and at the end of the Subatlantic period of the Holocene. The alluvial-sedimentation rate increased during the weakening of aridization and decreased during cooling and the intensification of aridization. The obtained regional data are compared with data on the adjacent areas and the global climatic changes in the Northern Hemisphere.     

Magnetic-field variations in the active region NOAA 10486 and their relationship to X-ray flares and coronal mass ejections

SOHO/MDI magnetograms are used to analyze the time variations in the magnetic parameters of the active region (AR) NOAA 10486, which was part of a large activity complex that passed over the solar disk from October 26 to 31, 2003, during solar cycle 23. The results are compared with X-ray flares in the AR and the parameters of coronal mass ejections associated with the AR. The time variations in the distributions of themagnetic-field strengths associated with the total magnetic flux (Fa), the flux imbalance between the northern and southern polarities (Im), the complexity of the field, as a measure of the mutual overlapping of the opposite polarities (Co), and the tilt angle of the magnetic axis (An) are considered. The time variations in the free energy accumulated in current sheets of ARs were traced using a parameter introduced for this purpose (Sh). The following results were obtained. First, the parameters Fa, Im, Co, An, and Sh quantitatively describe the current state of the AR and can be used to trace and analyze the dynamical evolution of its magnetic field. Second, variations in the magnetic-field-strength distributions and the mean values of Fa, Im, Co, An, and Sh are associated with flares and coronal mass ejections, and the variations have considerable amplitudes. Third, the parameter Sh characterizing the degree to which the magnetic field is non-potential in regions adjacent to the main neutral line increases before eruptive events, and is thus particular interest for monitoring the states of ARs in real time. Fourth, the magnetic field of the AR manifests a sort of quasi-elasticity, so that the field structure is restored after active events, on average, within 1–3 h.     

Intrayear irregularities of the Earth’s rotation

The methods of celestial mechanics can be used to construct a mathematical model for the perturbed rotational motions of the deformable Earth that can adequately describe the astrometric measurements of the International Earth Rotation Service (IERS). This model describes the gravitational and tidal influences of the Sun and Moon. Fine resonant interactions of long-period zonal tides (annual, semiannual, monthly, and biweekly) with the diurnal and semidiurnal tides are revealed. These interactions can be reliably confirmed via a spectral analysis of the IERS data. Numerical modeling of tidal irregularities of the Earth’s axial rotation was carried out, focusing on the analysis and forecasting of variations of the day length occurring within short time intervals of a year or shorter (intrayear variations).