National-scale estimation of potentially harmful element ambient background concentrations in topsoil using parent material classified soil:stream–sediment relationships

Regulatory authorities require estimates of ambient background concentrations (ABCs) of potentially harmful elements (PHEs) in topsoil; such data are currently not available in many countries. High resolution soil geochemical data exist for only part of England and Wales, whilst stream sediment data cover the entire landscape. A novel methodology is presented for estimating soil equivalent ABCs for PHEs from high-resolution (HR) stream sediment geochemical data grouped by common parent materials (PM), using arsenic (As) as an example. Geometric mean (GM) values for local PM groups are used to investigate different approaches for transforming sediment to soil equivalent concentrations. Holdout validation is used to assess: (i) the optimum number of samples for calculating local GM values, and (ii) the optimum scale at which to group data when using linear regression analysis to estimate GM soil ABCs from local sediment geochemical values. Holdout validation showed that the smallest differences were generally observed when five observations were used to calculate the GM and that these should be grouped over the smallest possible area in order to encompass soils over PMs with elevated GM As concentrations. Geometric mean ABCs are estimated and mapped for As in mineral soil across all of England and Wales within delineations of PM polygons. Errors for the estimation of soil equivalent GM As ABCs based on sediment data for an independent validation set were of a similar magnitude to those from holdout validation applied to the original data suggesting the approach is robust. The estimates of soil equivalent ABCs suggest that As exceeds the regulatory threshold used in risk assessments for residential land use (20 mg kg⁻¹) across 16% of the landscape of England and Wales. The applicability of the method for cognate landscapes, and potential refinements is discussed.     

Integration and magnitude homogenization of the Egyptian earthquake catalogue

The aim of the present work is to compile and update a catalogue of the instrumentally recorded earthquakes in Egypt, with uniform and homogeneous source parameters as required for the analysis of seismicity and seismic hazard assessment. This in turn requires a detailed analysis and comparison of the properties of different available sources, including the distribution of events with time, the magnitude completeness, and the scaling relations between different kinds of magnitude reported by different agencies. The observational data cover the time interval 1900–2004 and an area between 22°–33.5° N and 25°–36° E. The linear regressions between various magnitude types have been evaluated for different magnitude ranges. Using the best linear relationship determined for each available pair of magnitudes, as well as those identified between the magnitudes and the seismic moment, we convert the different magnitude types into moment magnitudes M _W, through a multi-step conversion process. Analysis of the catalogue completeness, based on the M _W thus estimated, allows us to identify two different time intervals with homogeneous properties. The first one (1900–1984) appears to be complete for M _W ≥ 4.5, while the second one (1985–2004) can be considered complete for magnitudes M _W ≥ 3.     

The Origin of Associated Basic and Acid Rocks in the Lebombo--Nuanetsi Igneous Province, Southern Africa, as implied by Strontium Isotopes

Whole rock Rb–Sr measurements were made on associatedbasic and acid intrusives and extrusives from the northern andsouthern ends of the Lebombo monocline with a view to determineif the acid rocks came from the mantle or from the crust. Inthe south, in Swaziland (now called Ngwame) and Zululand, rhyolitesand granophyres (age 202 14 m.y.) have an initial Si⁸⁷–Sr⁸⁶ratio of 0.7042 0.0005; in the north, in the Nuanetsi syncline,rhyolites (age 206 13 m.y.) and granites from ring complexes(age 177 7 m.y.) have initial ratios of 0.7081 0.0008 and0.7085 0.0007, respectively. The initial ratios of the basicrocks, basalts and gabbros, vary in both areas and have a rangefrom 0.7042 to 0.7125 which can be explained by crustal contamination.The low initial ratios and isotopic homogeneity of the acidmagmas over long distances (160 km) in Swaziland and Zululandare interpreted as implying that they were derived from themantle.     

Sur la présence de nickel dans un gisement de bauxite près de Mégare

Résumé L'exploitation récente d'un gisement de bauxite près de Mégare (Grèce) a fait apparaître sur les calcaires de base une concentration verte d'oxyde de nickel relativement élevée. La présence dans le gisement d'argiles rouges, renfermant de fortes proportions d'oxyde de fer avec des teneurs relativement faibles en alumine et des traces d'oxyde de nickel, induit à penser qu'il s'agit d'un produit latéritique dérivé d'une roche ultrabasique et transporté ultérieurement sur la région calcaire karstifiée avec ses remplissages bauxitiques. L'étude se termine par une hypothèse sur la genèse de ce gîte singulier.

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The recent mining of a bauxite deposit near Megara (Greece) has shown on the footwall limestone a relatively high concentration of a green nickel oxide. The occurrence in the same deposit of red clays with a rather high percentage of iron oxide and a low content of alumina, together with some traces of nickel, induces to think that this material is composed of a lateritic soil derived from an ultrabasic rock and subsequently transported on karstified limestone with its bauxitic fillings. — The study ends with an hypothesis on the genesis of this unusual deposit.