Rare gas isotopes and parent trace elements in ultrabasic-alkaline-carbonatite complexes, Kola Peninsula: identification of lower mantle plume component

During the Devonian magmatism (370 Ma ago) ∼20 ultrabasic-alkaline-carbonatite complexes (UACC) were formed in the Kola Peninsula (north-east of the Baltic Shield). In order to understand mantle and crust sources and processes having set these complexes, rare gases were studied in ∼300 rocks and mineral separates from 9 UACC, and concentrations of parent Li, K, U, and Th were measured in ∼70 samples. ⁴He/³He ratios in He released by fusion vary from pure radiogenic values ∼10⁸ down to 6 × 10⁴. The cosmogenic and extraterrestrial sources as well as the radiogenic production are unable to account for the extremely high abundances of ³He, up to 4 × 10⁻⁹ cc/g, indicating a mantle-derived fluid in the Kola rocks. In some samples helium extracted by crushing shows quite low ⁴He/³He = 3 × 10⁴, well below the mean ratio in mid ocean ridge basalts (MORB), (8.9 ± 1.0) × 10⁴, indicating the contribution of ³He-rich plume component. Magnetites are principal carriers of this component. Trapped ³He is extracted from these minerals at high temperatures 1100°C to 1600°C which may correspond to decrepitation or annealing primary fluid inclusions, whereas radiogenic ⁴He is manly released at a temperature range of 500°C to 1200°C, probably corresponding to activation of ⁴He sites degraded by U, Th decay.Similar ⁴He/³He ratios were observed in Oligocene flood basalts from the Ethiopian plume. According to a paleo-plate-tectonic reconstruction, 450 Ma ago the Baltica (including the Kola Peninsula) continent drifted not far from the present-day site of that plume. It appears that both magmatic provinces could relate to one and the same deep-seated mantle source.The neon isotopic compositions confirm the occurrence of a plume component since, within a conventional ²⁰Ne/²²Ne versus ²¹Ne/²²Ne diagram, the regression line for Kola samples is indistinguishable from those typical of plumes, such as Loihi (Hawaii). ²⁰Ne/²²Ne ratios (up to 12.1) correlate well with ⁴⁰Ar/³⁶Ar ones, allowing to infer a source ⁴⁰Ar/³⁶Ar ratio of about 4000 for the mantle end-member, which is 10 times lower than that of the MORB source end-member. In (³He/²²Ne)_PRIM versus (⁴He/²¹Ne)_RAD plot the Kola samples are within array established for plume and MORB samples; almost constant production ratio of (⁴He/²¹Ne)_RAD ≅ 2 × 10⁷ is translated via this array into (³He/²²Ne)_PRIM ∼ 10. The latter value approaches the solar ratio implying the non-fractionated solar-like rare gas pattern in a plume source.The Kola UACC show systematic variations in the respective contributions of in situ-produced radiogenic isotopes and mantle-derived isotopes. Since these complexes were essentially plutonic, we propose that the depth of emplacement exerted a primary control on the retention of both trapped and radiogenic species, which is consistent with geological observations. The available data allow to infer the following sequence of processes for the emplacement and evolution of Kola Devonian UACC: 1) Ascent of the plume from the lower mantle to the subcontinental lithosphere; the plume triggered mantle metasomatism not later than ∼700 to 400 Ma ago. 2) Metasomatism of the lithosphere (beneath the central part of the Kola Peninsula), including enrichment in volatile (e.g., He, Ne) and in incompatible (e.g., U, Th) elements. 3) Multistage intrusions of parental melts, their degassing, and crystallisation differentiation ∼370 Ma ago. 4) Postcrystallisation migration of fluids, including loss of radiogenic and of trapped helium. Based on model compositions of the principle terrestrial reservoirs we estimate the contributions (by mass) of the plume material, the upper mantle material, and the atmosphere (air-saturated groundwater), into the source of parent melt at ∼2%, 97.95%, and ∼0.05%, respectively.     

Microbial respiration and diffusive transport of O2, O2, and OO in unsaturated soils: a mesocosm experiment

Although the flux of molecular O₂ between the atmosphere and the subsurface is intrinsically linked to the net soil production of greenhouse gasses, few studies have focused on the controls affecting the isotopic composition of O₂ in the subsurface. Here, we developed and tested a stable oxygen isotope tracer technique and gas transport modeling approach to evaluate O₂ cycling and fluxes from the subsurface that used an environmentally controlled soil mescosm. We measured the O₂ and δ¹⁸O₂ profiles in a model unsaturated soil zone and quantified the O₂ consumption rates and the O₂ isotope fractionation factors resulting from the combined processes of subsurface microbial (including bacteria, fungi, and protozoa) consumption of O₂ and diffusive influx of O₂ from the atmosphere. We found that at high respiration rates in the mesocosm, there appeared to be very little isotope fractionation of O₂ by soil microorganisms. Although the mesocosm respiration rates are not typical of natural soils in northern temperate climes, they may be more representative of soils in warm and moist tropical environments. Our findings caution against the indiscriminate application of laboratory-determined oxygen isotope fractionation factors to field settings. The oxygen isotope tracer and modeling approach demonstrated here may be applied to gain a better understanding of biogenic gas production and O₂ cycling in subsurface systems and soils.     

A decade of change in the Skidaway River estuary I. Hydrography and nutrients

The Skidaway River estuary is a tidally-dominated subtropical estuary in the southeastern USA surrounded by extensiveSpartina salt marshes. Weekly smapling at high and low tide began in 1986 for hydrography, nutrients, chlorophylla, particulate matter, and microbial and plankton biomass and composition; hydrographic and nutrient data during 1986–1996 are reported here. Salinity varied inversely with river discharge and exhibited variability at all time scales but with no long-term trend. Water temperature typically ranged over 25°C and was without apparent long-term frend. Seasonal cycles in concentrations of NO₃, NH₄, PO₄, Si(OH)₄, and DON were observed, with annual maxima generally occurring in late summer. Superimposed on seasonal cycles, all five nutrients exhibited steady increases in minimum, mean, and maximum concentrations; mean concentrations increased c. 50–150% during the decade. Nutrient concentrations were highly correlated with water temperature over the ten-year period, but weakly related to salinity and discharge. Nutrients were strongly correlated with one another, and the relative ratios among inorganic nutrients showed little long-term trend. Correlations among temperature and nutrient concentrations exhibited considerable inter-annual variability. Major spikes in organic and inorganic nutrient concentrations coincided with significant rainfall events; concentrations increased hyperbolically with rainfall. Although pristine compared to more heavily impacted waterways primarily outside the region, residential development and population density have been increasing rapidly during the past 15–20 years. Land use is apparently altering nutrient loading over the long-term (months-years), and superimposed on this are stochastic meteorological events that accelerate these changes over the short term (days-weeks).     

Lithosphere structure of European sedimentary basins from regional three-dimensional gravity modelling

A three-dimensional (3D) density model, approximated by two regional layers—the sedimentary cover and the crystalline crust (offshore, a sea-water layer was added), has been constructed in 1° averaging for the whole European continent. The crustal model is based on simplified velocity model represented by structure maps for main seismic horizons—the “seismic” basement and the Moho boundary. Laterally varying average density is assumed inside the model layers. Residual gravity anomalies, obtained by subtraction of the crustal gravity effect from the observed field, characterize the density heterogeneities in the upper mantle. Mantle anomalies are shown to correlate with the upper mantle velocity inhomogeneities revealed from seismic tomography data and geothermal data. Considering the type of mantle anomaly, specific features of the evolution and type of isostatic compensation, the sedimentary basins in Europe may be related into some groups: deep sedimentary basins located in the East European Platform and its northern and eastern margins (Peri-Caspian, Dnieper–Donets, Barents Sea Basins, Fore–Ural Trough) with no significant mantle anomalies; basins located on the activated thin crust of Variscan Western Europe and Mediterranean area with negative mantle anomalies of −150 to −200×10⁻⁵ ms⁻² amplitude and the basins associated with suture zones at the western and southern margins of the East European Platform (Polish Trough, South Caspian Basin) characterized by positive mantle anomalies of 50–150×10⁻⁵ ms⁻² magnitude. An analysis of the main features of the lithosphere structure of the basins in Europe and type of the compensation has been carried out.     

Analysis of the resolution function in seismic prestack depth imaging

We consider the problem of estimating subsurface quantities such as velocity or reflectivity from seismic measurements. Because of a limited aperture and band-limited signals, the output from a seismic prestack reconstruction method is a distorted or blurred image. This distortion can be computed using the concept of resolution function, which is a quantity readily accessible in the Fourier space of the model. The key parameter is the scattering wavenumber, which at a particular image point is defined by the incident and scattered ray directions in a given background model. Any location in any background model can be considered. In general, the resolution function will depend on the following four quantities: the background velocity model, the frequency bandwidth, the wavefield type and the acquisition geometry.
We first establish the resolution function for a general scattering model assuming local reaction. We then adapt this result for two well-known scattering models: Born and Kirchhoff. For each of these approximations the corresponding resolution function is derived and discussed. Finally, by employing a simple synthetic data example we demonstrate the ability of the resolution function to predict the image distortions.     

Remote sensing parameterization of the processes of energy and water cycle over desertification areas

In order to understand the processes of land surface-atmosphere interaction over desertification area, it is indispensable to utilize of satellite remote sensing. Two scenes of Landsat TM were used to produce a set of maps of surface reflectance, MSAVI, vegetation coverage, surface temperature, net radiation, soil heat flux, sensible heat flux and latent heat flux. Statistical analysis based on these maps revealed some quantitative significant land surface characteristics. Future developments of the method are also discussed.     

Kosa (yellow sand) components in precipitation collected at central Japan

In east Asia, acidic gases derived from fossil fuel combustion have increased in the past decades. On the other hand, the Asian dust, also called Kosa (yellow sand) is transported following windstorms from arid lands in the Asian continent. Many researchers have been interested in the reaction between acidic aerosols and Kosa aerosols as well as the long-range transport of these emissions. To investigate the characteristics of chemical components in precipitation on a long-term basis over Japan, precipitation was sequentially collected from April 1984 to March 1997 at Kanazawa located near the coast of the Sea of Japan. Precipitation samples were collected at 1 mm intervals for the first 5 mm rainfall and all volume of rainwater after 6 mm for all precipitation events with an automatic wet only precipitation collector. According to the analyses of precipitation including Kosa aerosols during Kosa periods, the reaction in the air between Kosa and acidic components during the long-range transport was discussed.     

Damage and recovery of the Gurbantunggut Desert vegetation following engineering activities

The fragile ecological environment of the Gurbantunggut Desert is damaged/disturbed by human activities relating to the development of oil-gas resources and the constructions of desert road and great engineering in the Jungger Basin. It was mainly represented: soil compaction, vegetation cleaning, burial of vegetation, oil polluting, and soil disturbance. With investigation and experiment, we found that when the way and intensity of engineering activities disturbing the eco-environment does not make its ecological stability disintegrated, the desert vegetation has a capacity of natural recovery. To speed and strengthen the process of vegetation recovery efficient assistant measurements, including stabilizing mobile sands promptly and sowing seeds of shrub and herb plants in good time will be needed.     

Expansion and contraction of Chinese deserts during the Quaternary

Episodic dune formations during the Quaternary are found in many deserts of China. The causes of desert expansions on different time scales are not the same. Desert extension at about 1.1 and 0.9 Ma ago were the response to the active tectonic movements, whereas the desert evolutions on the ten-thousand years time scale were the response to the orbital scale climatic changes. Spatial scale studies on desert evolution indicate that desert margins shifted greatly during the last glacial maximum (LGM) and the Holocene optimum, its changing from 125°E of the LGM to 105°E of the climatic optimum. Historical desertification in the semiarid China is not a response to climate drought but largely associated with the human impacts (mainly over-cultivation) since about 2300 years ago, which leads to the reworking of the underlying LGM sands.     

Utilization of water resources,ecological balance and land desertification in the Tarim Basin,Xinjiang

Because of the human exploitation and utilization of water resources in the Tarim Basin, the water resources consumption has changed from mainly natural ecosystem to artificial oasis ecosystem, and the environment has changed correspondingly. The basic changes are: desertification and oasis development coexist, both “the human being advance and the desert retreat” and “the desert advance and the human being retreat” coexist, but the latter is dominant. In the upper reaches, water volume drawing to irrigated agricultural areas has increased, artificial oases have been enlarging and moving from the deltas in the lower reaches of many rivers to the piedmont plains. In the middle and lower reaches of the Tarim River, the stream flow has decreased, old oases have declined, natural vegetations have been degenerating, desertification has been enlarging, and the environment has deteriorated. The transition regions, which consist of forestlands, grasslands and waters between the desert and the oases, have been decreasing continuously, their shelter function to the oases has been weakened, and the desert is threatening the oases seriously.