Low‐temperature crystallization of MgSiO3 glasses under electron irradiation: Possible implications for silicate dust evolution in circumstellar environments

Abstract— Synthetic MgSiO₃ glasses were irradiated at room temperature by 300 keV electrons in a transmission electron microscope (TEM). One of the samples had been previously irradiated by 50 keV He+ ions. Electron irradiation induces the nucleation and growth of randomly oriented nanometer‐sized crystallites. The crystallites first consist of MgO and subsequently of forsterite (Mg₂SiO₄). Both are seen to form within an amorphous SiO₂ matrix. The rate of crystallization of the samples has been monitored by conventional TEM imaging and electron diffraction. The sample that had been pre‐irradiated with He+ ions is found to transform faster than the as‐quenched glass. The crystallization of metastable MgSiO₃ glasses is explained by ionizing radiation‐induced elemental diffusion that allows the reorganization of matter into a more favourable thermodynamic state. These results show that ionizing radiation interactions could account for crystal formation as observed in infrared spectroscopy in some young stellar environments.     

Facies and architecture of an estuarine tidal bar (the Trompeloup bar, Gironde Estuary, SW France)

This study describes the sedimentary facies and internal architecture of a modern estuarine tidal bar present in the bay-head delta of a wave- and tide-dominated estuary, the Gironde Estuary, in southwest France. Based on 51 cores (2 to 5 m long), this work demonstrates that such bars are composite sedimentary bodies made up of individual sigmoidal sand units isolated from one another by thick muddy layers. The bar appeared in the study area around 1874. Since then, its evolution has been characterized by phases of rapid downstream bar migration alternating with periods of bar abandonment. During the periods of active bar progradation, which commonly last between 10 and 20 years, the bar progrades up to 7 km seaward and forms a narrow (200–800 m wide) sand ridge up to 6 m thick. During abandonment phases which also last around 10–20 years, the bar is starved of sand and a mud layer (1 to 3 m thick) is deposited. The vertical succession formed by the seaward progradation of the tidal bar records these alternating phases of growth and abandonment. A typical vertical succession in the bar system is 8 m thick and comprises several superimposed, upward-coarsening units of cross-stratified sand, deposited during phases of seaward progradation, separated by a thick layer of thinner-bedded mud and sand laminae deposited during phases of bar abandonment. When a tidal bar builds up to the supratidal zone, marshes accumulate and the bar becomes a permanent island in the estuary. The large-scale architecture of the bar is thus made of an alternation of potential sandy reservoir units and muddy internal seals. The reservoir units are characterized by a sigmoidal shape. The muddy layer, which is deposited between the two sigmoidal units, is a thick, continuous potential internal seal. This complex internal architecture is due to the fact that there is a considerable amount of mud present in the bay-head delta of the Gironde Estuary. It is thought to be representative of the architecture of tidal bars in the inner part of wave- and tide-dominated estuaries.     

Limited Consequences of Seagrass Decline on Benthic Macrofauna and Associated Biotic Indicators

Marine phanerogams are ecosystem engineers, as their presence induces major environmental changes that impact on the benthic fauna. Consequently, modifications to the structure of benthic communities would be expected to be associated with seagrass decline. Since 2005, Zostera noltii seagrass beds in Arcachon Bay (France), the largest in Europe, have undergone a severe decline. Twelve stations distributed throughout the lagoon were sampled in 2002, and all were found to be densely planted at that time. Subsequently, the same stations were revisited in 2010 and seagrass cover had drastically decreased by that time. Based on benthic macrofauna, multidimensional scaling (MDS) analysis identified four groups. Years were separated. In 2002, two groups were distinct in relation to the water body, since in 2010 separation between the two other groups was related to seagrass occurrence. When looking at community structure and dominant species there were moderate differences within and between years, independent of seagrass decline. Seagrass loss did not drastically modify the species composition as they were preserved in the remaining seagrass patches. However, there was a drop in macrofauna abundance in unvegetated muddy compared with abundance in the remaining seagrass areas. Epifauna was particularly affected by seagrass decline. Among biotic indicators based on macrofauna, multivariate indicator MISS (Macrobenthic Index in Sheltered Systems) was in agreement with the similarity of macrofauna structure among groups, while other tested indicators performed badly in relation to seagrass occurrence. However, no index detected seagrass loss, highlighting the necessity of maintaining a separate survey on seagrass cover.     

The effect of dynamic–thermodynamic icebergs on the Southern Ocean climate in a three-dimensional model

Melting icebergs are a mobile source of fresh water as well as a sink of latent heat. In most global climate models, the spatio-temporal redistribution of fresh water and latent heat fluxes related to icebergs is parameterized by an instantaneous more or less arbitrary flux distribution over some parts of the oceans. It is uncertain if such a parameterization provides a realistic representation of the role of icebergs in the coupled climate system. However, icebergs could have a significant climate role, in particular during past abrupt climate change events which have been associated with armada’s of icebergs. We therefore present the interactive coupling of a global climate model to a dynamic thermodynamic iceberg model, leading to a more plausible spatio-temporal redistribution of fresh water and heat fluxes. We show first that our model is able to reproduce a reasonable iceberg distribution in both hemispheres when compared to recent data. Second, in a series of sensitivity experiments we explore cooling and freshening effects of dynamical icebergs on the upper Southern Ocean and we compare these dynamic iceberg results to the effects of an equivalent parameterized iceberg flux.In our model without interactive icebergs, the parameterized fluxes are distributed homogeneously South of 55°S, whereas dynamic icebergs are found to be concentrated closer to shore except for a plume of icebergs floating North–East from the tip of the Antarctic Peninsula. Compared to homogeneous fluxes, the dynamic icebergs lead to a 10% greater net production of Antarctic bottom water (AABW). This increased bottom water production involves open ocean convection, which is enhanced by a less efficient stratification of the ocean when comparing to a homogeneous flux distribution.Icebergs facilitate the formation of sea-ice. In the sensitivity experiments, both the fresh water and the cooling flux lead to a significant increase in sea-ice area of 12% and 6%, respectively, directly affecting the highly coupled and interactive air/sea/ice system. The consequences are most pronounced along the sea-ice edge, where this sea-ice facilitation has the greatest potential to affect ocean stratification, for example by heat insulation and wind shielding, which further amplifies the cooling and freshening of the surface waters.     

Microstructural defects in experimentally shocked diopside: A TEM characterization

Transmission electron microscopy was used for characterizing the defect microstructure induced by shock experiments in a single crystal of diopside. The shock-induced defects found in the crystal can be divided in four distinct types:

1. A high density and pervasive distribution of dislocations in glide configuration (glide systems (100)[0
2. Mechanical twin lamellae, mostly parallel to (100), the (001) twin lamellae are less abundant. li]3)
3. Heterogeneously distributed tiny molten zones (3 to 20 μm size) which, after cooling, appear as a glass with a chemical composition very close to the one of the original diopside.

The present TEM study reveals that the defect micro-structure in shocked diopside consists of a large variety of shock-induced defects. Especially, the amorphous PDFs which were never observed in statically deformed diopside seem to be an important characteristic micro-structural defects in shocked silicate minerals. Although the presence of amorphous PDFs is not yet confirmed for naturally shocked clinopyroxene, we strongly suggest that these features can serve as a diagnostic tool for recognizing impact phenomena on all planetary bodies of our solar system.     

Preliminary study on the preservation of giant clam (Tridacnidae) shells from the Balobok Rockshelter archaeological site,south Philippines

Tridacnidae shells, a valuable archive of past environments, are common in the Balobok Rockshelter archaeological site on Sanga‐Sanga Island in the south Philippines. This site was occupied during the mid‐Holocene (ca. 5000–8800 ¹⁴C yr B.P.), a period of Neolithic cultural expansion in the Philippines. This paper focuses on the preservation of two shell specimens, Hippopus hippopus and Tridacna maxima, unearthed from two mid‐Holocene layers within the rockshelter. The shells' mineralogy and microstructure (prismatic and crossed‐lamellar) were studied using micro‐Fourier transform infrared spectroscopy and scanning electron microscopy to determine if the samples were suitable as paleoenvironmental records. Both shells are still aragonitic but aragonite crystals of both microstructure types are partly dissolved. This dissolution, characteristic of meteoric water alteration, precludes their utility in paleoenvironmental geochemical studies. Nevertheless, these shells are abundant in archaeological sites in the region and may be better preserved in other depositional contexts; more studies on Philippine Tridacnidae shell diagenesis are needed. © 2011 Wiley Periodicals, Inc.