Partitioning and budget of Li, Be and B in high-pressure metamorphic rocks

Partitioning and budget of Li, Be and B in high-pressure metamorphic rocks from the island of Syros (Greece) were studied, using secondary ion mass spectrometry, inductively coupled plasma optical emission spectrometry and prompt gamma neutron activation analysis. Partitioning between coexisting mineral phases was found to be rather constant and independent of element concentrations. For several mineral pairs, apparent partition coefficients vary in a narrow range, while concentrations vary by more than an order of magnitude. Hence, it was possible to establish sets of inter-mineral partition coefficients for Li, Be and B among 15 different high-pressure minerals. This data set provides important information on the behaviour of the light elements in different lithologies within subducting slabs from the onset of metamorphism to the eclogite stage. It is essential for modelling trace-element and isotope fractionation during subduction and dehydration of oceanic crust.     

Geodynamische Interpretation Ostkretas

The phenomenon of “Stockwerk“-tectonics characterizes Eastern Crete. Autochthonous bedded limestone (“Plattenkalk”) is overlain by the allochthonous units of the “Phyllitic-Series”, the Tripolitza- und Pindos-Series. The “Phyllitic-Series” were recognized as a mélange. The mélange is due to gravity-sliding tectonics under an overburden pressure. Geological evolution and geophysical data across the section Santorin-Crete were interpreted. Instead of a mobile crust hypothesis of moving plates with subduction zones a fixed crust hypothesis of vertical uplift and corresponding subsidence is suggested. The nappe transport by forces of gravity is a secondary effect.     

A transmitting boundary for the dynamic finite element analysis of cross anisotropic soils

The problem of the transmitting boundary used in the dynamic finite element analysis of layered axisymmetric soil models with non-axisymmetric displacements is considered. Each layer is modelled as a homogeneous, viscoelastic cross anisotropic medium with a vertical axis of material symmetry.     

Carbon in olivine single crystals analyzed by the 12C(d,p)13C method and by photoelectron spectroscopy

Carbon subsurface concentration profiles in olivine single crystals from San Carlos, Arizona, and the Sergebet Island. Red Sea, containing total carbon between 60–180 wt.-ppm, were analyzed by means of the ¹²C(d. p)¹³C nuclear reaction and by x-ray induced photoelectron spectroscopy (XPS) in combination with acid etching and with Ar⁺ ion sputtering respectively, between 200–930 K. The (d, p) analysis reveals equilibrium subsurface C profiles extending 1–2 μm or more into the bulk. Their steepness is a function of temperature. Typical mean C concentrations at 300 K in the resolvable layers, 0–0.6, 0.6–1.2, and 1.2–1.8 μm. are 1.8, and 0.6 wt.-%, corresponding to enrichment factors over the mean bulk C concentration of the order of 100, 40 and 30 respectively. In the topmost atomic layers analyzed by XPS the carbon is enriched by a factor of the order of 1000, decreasing with increasing temperature. The results suggest that the carbon is in a truly dissolved state and highly mobile, subject to a reversible subsurface segregation. Most probably local lattice strain associated with the solute C species provide the driving force for this diffusional process. The C diffusion coefficient was determined from the (d, p) data below 300 K: D= 10^?13 exp(?7.8/RT) [m²· sec^?1; KJ · mole^?1] and from XPS data between 450–925 K: D = 10^?14 exp(-6/RT) [m² · sec^?1; KJ · mole^?1] The estimated error of the preexponential factors is ± one order of magnitude, that of the activation energies ±3.5 and ±2 KJ mole^?1 respectively.     

Structural and other contributions to the third-law entropies of silicates

The true third-law entropies of many minerals are frequently quite different from those values derived from calorimetric measurements. The discrepancy can usually be attributed to neglected residual or unextracted entropies related either to site-mixing and molecular disorders or to the lack of significant magnetic ordering at those temperatures reached by the heat capacity measurements. A literature review indicates that many silicates present site-mixing and vacancies in one or several of their crystallographic sites. The effect on entropy is well known in feldspars, but residual entropies of similar or greater magnitudes are also present in many amphiboles, micas, chlorites, zeolites, scapolites, feldspathoids, and other silicates. Less conspicuously, disorder in water molecules or hydrogen bonding may be responsible for yet another frequently overlooked entropy contribution. Unextracted entropy results from limited heat capacity measurements so that magnetic ordering effects to be expected in minerals with transition metals are either not registered or only incompletely recorded. In some cases, significant magnetic ordering probably only takes place at temperatures well below 15 K.The discussion in this paper centers on the causes resulting in discrepancies between calorimetric and third-law entropies. A set of tables reproduces the crystallographic information for most important rock-forming silicates and indicates the entropy contribution arising from site-mixing and vacancies, and possible magnetic ordering in those substances with transition metals. In addition, most elements appear in several isotopic forms, and it is this effect that gives rise to isotopic site-mixing and thus to another configurational entropy. It can on the whole be neglected. A discussion centered on the system fayalite-iron oxides (wüstite, hematite, magnetite) indicates the uncertainties involved in deriving third-law entropies from either equilibrium data or calorimetric investigations, which is especially relevant when dealing with substances presenting vacancies (wüstite), transition metals, and the possibility of magnetic ordering. The published entropies of many minerals are probably only approximations to true third-law values and should be checked against structural and magnetic information.     

Photometric Solution of the O-type Eclipsing Binary V1007 Sco

A Cosmological model with a viscous fluid in Kaluza-Klein metric is obtained assuming a time-dependent equation of state. The solution is in fact a generalization of an earlier work by Hajj and Boutros for a perfect fluid. It is also found that dimensional reduction of the extra space takes place such that the five-dimensional universe naturally evolves into an effective four-dimensional one. The dynamical behavior of the model is examined and it is also found that with a decrease in extra space the observable 3D space entropy increases thus accounting for the large value of entropy observable at present.     

Testing the blast wave model with Swift GRBs

The complex structure of the light curves of Swift Gamma-Ray Bursts (GRBs) has made the identification of breaks, and the interpretation of the blast wave caused by the burst, more difficult than in the pre- Swift era. We aim to identify breaks, which are possibly hidden, and to constrain the blast wave parameters; electron energy distribution, p , density profile of the circumburst medium, k , and the continued energy injection index, q . We do so by comparing the observed multiwavelength light curves and X-ray spectra of our sample to the predictions of the blast wave model. We can successfully interpret all of the bursts in our sample of 10, except two, within this framework and we can estimate, with confidence, the electron energy distribution index for 6 of the sample. Furthermore, we identify jet breaks in a number of the bursts. A statistical analysis of the distribution of p reveals that, even in the most conservative case of least scatter, the values are not consistent with a single, universal value. The values of k suggest that the circumburst density profiles are not drawn from only one of the constant density or wind-like media populations.