Biogenic hydrocarbons in fluid inclusions from the aberfoyle tin-tungsten deposit, Tasmania, Australia

Trace components in fluid inclusions from the Aberfoyle tin-tungsten deposit in Tasmania, Australia, were examined by thermal decrepitation-mass spectrometry. The technique involves the decrepitation of fluid inclusions by stepwise heating in the source of a mass spectrometer. In addition to water, other species identified were carbon dioxide and hydrocarbons. Detailed analysis of these hydrocarbons showed that they ranged in carbon number from C₁ up to at least C₃₃ and probably comprised, in part, biological marker compounds, previously unreported in such high-temperature environments. Their presence suggests that the fluid responsible for mineralisation was not entirely magmatic but contained a non-magmatic component evolved through fluid-rock interaction in the sedimentary country rocks.     

Development of Emission Models and Improvement of Emission Data for Germany

Measurements and model developments with the objective to improve the quality and resolution of estimations of anthropogenic emissions are described. Measurement results on a chassis dynamometer were used to determine VOC profiles for exhaust gas emissions of passenger cars for different vehicle and fuel types and different driving modes. Further measurements resulted in emission factors and VOC profiles for lignite burning in residential stoves. Using remote sensing techniques benzene emission factors of gas stations and the efficiency of gasoline vapour recovery systems were measured.To improve the quality and the spatial and temporal resolution of emission data, emission models were improved or modified. This was done by elaborating and applying new methods for important emission source categories (e.g., solvent use, road traffic, small combustion) as well as including new data sources in the calculation routines (e.g. emission statements, land use data, import/export indices of solvents). Simultaneously considerable progress was made improving temporal and spatial allocation functions and VOC profiles. With these improvements a large number of anthropogenic emission data sets for 14 different grid projections in Germany and Europe have been generated. An emission scenario for Germany for 2010 suggests that considering air quality directives from the EU and Germany which are in force or in pipeline, German emissions of VOC and NO_x will decrease, but still exceed the national emission ceilings of the EU-NEC directive.     

An Inter-Laboratory Assessment of the Thorium Isotopic Composition of Synthetic and Rock Reference Materials

We present a concerted international effort to cross-calibrate five synthetic Th isotope reference materials (UCSC Th "A", OU Th "U", WUN, IRMM-35 and IRMM-36), and six rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2, USGS BHVO-2, LV18) using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We then compare our new values with a compilation of literature mass spectrometric data for these reference materials and derive recommended "consensus"²³⁰Th/²³²Th values for each. We also present isotope dilution U and Th concentration data for four rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2).     

Latitudinal and longitudinal variability of mesospheric winds and temperatures during stratospheric warming events

Continuous MF and meteor radar observations allow detailed studies of winds in the mesosphere and lower thermosphere (MLT) as well as temperatures around the mesopause. This height region is characterized by a strong variability in winter due to enhanced planetary wave activity and related stratospheric warming events, which are distinct coupling processes between lower, middle and upper atmosphere. Here the variability of mesospheric winds and temperatures is discussed in relation with major and minor stratospheric warmings as observed during winter 2005/06 in comparison with results during winter 1998/99.Our studies are based on MF radar wind measurements at Andenes (69°N, 16°E), Poker Flat (65°N, 147°W) and Juliusruh (55°N, 13°E) as well as on meteor radar observations of winds and temperatures at Resolute Bay (75°N, 95°W), Andenes (69°N, 16°E) and Kühlungsborn (54°N, 12°E). Additionally, energy dissipation rates have been estimated from spectral width measurements using a 3 MHz Doppler radar near Andenes. Particular attention is directed to the changes of winds, turbulence and the gravity wave activity in the mesosphere in relation to the planetary wave activity in the stratosphere.Observations indicate an enhancement of planetary wave 1 activity in the mesosphere at high latitudes during major stratospheric warmings. Daily mean temperatures derived from meteor decay times indicate that strong warming events are connected with a cooling of the 90 km region by about 10–20 K. The onset of these cooling processes and the reversals of the mesospheric circulation to easterly winds occur some days before the changes of the zonal circulation in the stratosphere start indicating a downward propagation of the circulation disturbances from the MLT region to the stratosphere and troposphere during the stratospheric warming events. The short-term reversal of the mesospheric winds is followed by a period of strong westerly winds connected with enhanced turbulence rates and an increase of gravity wave activity in the altitude range 70–85 km.     

On the constancy of the light curve of CC comae

New photoelectric measurements were obtained in 1980. Variability of the light curve was found, which affects mostly the minima. No period change could be detected. An estimation of the uncertainty of the parameters of the system showed an effect on the ratio of the radii of about 10%.     

First results of the micrometeoroid experiment s 215 on the HEOS 2 satellite

The experiment measures the mass, speed and approximate influx direction of the micrometeoroids. They are detected by the plasma produced during their impact on the sensor. In the first year after launch 173 particles were registrated.The temporal distribution of the particles indicates three different categories. Category 1 consists of 3 large groups of particles (“swarms”) each of which encountered the detector within some tens of minutes. Category 2 includes 8 small groups of particles each of which was detected within hours. Category 3 is made up by the remaining particles which are randomly distributed. The swarms are of very recent origin, possibly supplied by (1) meteoroids grazing the Earth's atmosphere, (2) ejecta from the Moon, and (3) collisions of dust particles. The groups may be dissipated swarms or particles from the outer zone of swarms. The randomly distributed particles consist of sporadic interplanetary particles and completely dissipated groups.The comparison of both the “particle rates” (number of detected particles per day) and the cumulative particle flux curves for the Earth's apex, antiapex, ecliptic north and south directions shows that the rates vary only within a factor of 2, whereas the particle flux is extremely anisotropic. The flux for the apex direction at 10^?12 g is 7 × 10^?5 m^?2 s^?1 which is 1 to 2 orders of magnitude higher than the flux values for the other directions.     

Low-field magnetic susceptibility: a proxy method of estimating increased pollution of different environmental systems

 A need for rapid and inexpensive (proxy) methods of outlining areas exposed to increased pollution by atmospheric particulates of industrial origin caused scientists in various fields to use and validate different non-traditional (or non-chemical) techniques. Among them, soil magnetometry seems to be a suitable tool, at least in some cases. This method is based on the knowledge that ferrimagnetic particles, namely magnetite, are produced from pyrite during combustion of fossil fuel. Besides the combustion processes, magnetic particles can also originate from road traffic, for example, or can be included in various waste-water outlets. Magnetite, Fe₃O₄, ranks among the main ferrimagnetic minerals and its identification in various ecosystems can contribute to fast and simple outlining of areas and sites exposed to higher pollution impact. Here the method of magnetic mapping of anthropogenic pollution will be introduced using a review of our recent case studies on different ecosystems in the Czech Republic and Germany. Received: 20 June 1998 · Accepted: 9 November 1998