Spatial Variability of Trends in the Rainfall-Runoff Relationship: A Mesoscale Study in the Mosel Basin

The spatial variability of observed trends in rainfall structure over the last 5 decades and its effects on the spatial variability of maximum daily water levels in the Grand-Duchy of Luxembourg (Europe) were investigated in 9 sub-basins of the Mosel river. Over the past 25 years, an increase in westerly atmospheric circulation types during winter months has caused an increase in winter rainfall totals, duration and intensity. More specifically, the spatial variability of trends having affected winter rainfall totals, duration and intensity have led to spatially varying positive trends in maximum daily water levels. Observed trends in rainfall characteristics and maximum daily water levels during winter show closely linked spatial patterns that are strongly related to the topography of the study area.     

Magnetic properties of urban soil profile and their significance for traffic pollution-Case study of the capital airport expressway in Beijing

An expressway-side soil profile 22 cm long was sampled from the grassland of the expressway linking Beijing and the Capital International Airport. Magnetic measurements, geochemical and multivariate statistic analyses were performed on the soil samples. The results reveal that the soil profile can be divided into two parts with significant difference in magnetic proxies and heavy metal concentration. The uppermost soil horizon (0–8 cm) represents the pollution-rich layer with higher concentration of ferrimagnetic phases and metallic elements. The values of xare very high with an average of 141.60 × 10⁻⁸ m³·kg⁻¹ in the layer. We explain that the anthropogenic dust input from traffic is the predominant cause for strong signals of magnetic phases and heavy metals. Below the profile depth of 8 cm, there is minor pollution in the soil with lower concentration of magnetic minerals and heavy metals compared to the natural background values. χ remains quite stable and relatively low with an average of 49.44 × 10⁻⁸ m³·kg⁻¹. S-ratio also generally decreases with depth, and it changes from 0.93 in the 0–8 cm layer to 0.87 below the depth of 8 cm. It indicates that the soil samples are overwhelmingly predominated by ferrimagnetic minerals in the upper part soil, while the contribution of imperfect antiferromagnetic components is stronger in the lower part. Rock magnetic experiments show MD magnetite as the main magnetic carrier both in the upper and lower parts. Themagnetic grain size in the upper part is, however, a bit coarser than that in the lower part. Cluster analysis shows a positive correlation between magnetic properties (χ, ARM, SIRM) and heavy metal pollutants of Pb, Zn, Cu. Fuzzy C-means cluster analysis can clearly help divide the soil profile into two different layers and distinguish their characteristics. It can be concluded that these magnetic concentration-related parameters can be used as proxies for pollution investigation in a fast, sensitive, low-cost and highly efficient approach to screening heavy metal pollution. __________ Translated from Quaternary Sciences, 2007, 27(6): 1113-1120 [译自:第四纪研究]     

Soft-sediment deformation of Late Pleistocene sediments along the southwestern coast of the Baltic Sea (NE Germany)

A 1,460-m-long profile of a Late Glacial subglacial, glacio-fluvial, glacio-limnic and glacio-deltaic sequence exposed at a cliff section on Usedom Island (SW Baltic Sea coast) is described. The sequence is up to 31 m thick and shows sedimentary structures typical of a glacial setting. Soft-sediment deformation is encountered and is associated with changes in lithology. These deformations include liquefaction, slumping, and faulting. As the most plausible cause, earthquake-induced shaking is discussed. The associated neotectonic activity is seen as a consequence of the postglacial isostatic crustal rebound. As the deglaciation earthquake ratio diminishes with time and as the rebound is phasing out, no large earthquakes are anticipated for northern Germany, although in conclusion the lithosphere of the North German Basin has to be regarded as weakened by repeated ice loading and deloading.     

First results of the micrometeoroid experiment s 215 on the HEOS 2 satellite

The experiment measures the mass, speed and approximate influx direction of the micrometeoroids. They are detected by the plasma produced during their impact on the sensor. In the first year after launch 173 particles were registrated.The temporal distribution of the particles indicates three different categories. Category 1 consists of 3 large groups of particles (“swarms”) each of which encountered the detector within some tens of minutes. Category 2 includes 8 small groups of particles each of which was detected within hours. Category 3 is made up by the remaining particles which are randomly distributed. The swarms are of very recent origin, possibly supplied by (1) meteoroids grazing the Earth's atmosphere, (2) ejecta from the Moon, and (3) collisions of dust particles. The groups may be dissipated swarms or particles from the outer zone of swarms. The randomly distributed particles consist of sporadic interplanetary particles and completely dissipated groups.The comparison of both the “particle rates” (number of detected particles per day) and the cumulative particle flux curves for the Earth's apex, antiapex, ecliptic north and south directions shows that the rates vary only within a factor of 2, whereas the particle flux is extremely anisotropic. The flux for the apex direction at 10^?12 g is 7 × 10^?5 m^?2 s^?1 which is 1 to 2 orders of magnitude higher than the flux values for the other directions.     

首钢工业区土壤剖面重金属含量及其结合态的磁指示作用的研究

对取自首都钢铁厂附近的土壤样芯进行了重金属含量、形态分析和的磁学测量.探讨了利用磁参数追踪和指示重金属污染和有机结合态和铁锰氧化结合态重金属的可行性.结果表明:土壤样芯中Cu、Pb、Zn、Fe和Mn的含量与χ、SIRM和ARM存在着十分相似的垂向变化特征,且相关关系显著(0.98>R>0.86).进一步对磁化率和Cu、Pb、Zn、Fe和Mn各结合态进行相关分析表明:五种元素的有机结合态与铁锰结合态和磁化率呈显著相关关系(0.98>R>0.56),而交换态和残渣态重金属与磁化率基本不存在相关关系.反映了磁性矿物和和重金属在赋存状态的本质联系.表明了磁性测量可作为工业区土壤重金属污染及有机结合态与铁锰结合态重金属记录信息提取的辅助手段.     

An Inter-Laboratory Assessment of the Thorium Isotopic Composition of Synthetic and Rock Reference Materials

We present a concerted international effort to cross-calibrate five synthetic Th isotope reference materials (UCSC Th "A", OU Th "U", WUN, IRMM-35 and IRMM-36), and six rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2, USGS BHVO-2, LV18) using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We then compare our new values with a compilation of literature mass spectrometric data for these reference materials and derive recommended "consensus"²³⁰Th/²³²Th values for each. We also present isotope dilution U and Th concentration data for four rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2).     

Natural and synthetic ferroglaucophane

Amphiboles approximating the composition of the ferroglaucophane end member, Na₂Fe₃Al₂Si₈O₂₂(OH)₂, have not been found in nature prior to 1969. Chemical, physical and petrologic data of four specimens of that mineral are given, two from Southern Italy and two from New Caledonia (Black, 1970). The ferroglaucophane end member was synthesized in seeded runs at 500° C, 5000 bars fluid pressure with oxygen fugacity defined by the wüstite-magnetite (WM) buffer. X-ray data and cell dimensions (a=9.686 Å, b=17.89, c=5.317, β=103° 45.2′ V=894.9 ų) are presented along with microprobe data that confirm the end member composition. Under these conditions of synthesis the ferroglaucophane grew metastably, however. Stability relations of the synthetic end member and of one natural specimen were investigated in a temperature range from 250° C to 500° C and at 3 and 5 kb with different oxygen buffers. At relatively low oxygen fugacities (WM buffer, QFM buffer) ferroglaucophane breaks down above 350–360° C. Under more oxidizing conditions (HM buffer) ferroglaucophane may not be stable even at very low temperatures. Mineral facies and chemical bulk composition of rocks that would favor the natural occurrence of ferroglaucophane are discussed. As assemblages with ferroglaucophane can have crystallized only below a very specific upper temperature limit, it is proposed to direct some attention towards that mineral.     

A general reduction scheme for reactive transport in porous media

We present a method to transform the governing equations of multispecies reactive transport in porous media. The reformulation leads to a smaller problem size by decoupling of equations and by elimination of unknowns, which increases the efficiency of numerical simulations. The reformulation presented here is a generalization of earlier works. In fact, a whole class of transformations is now presented. This class is parametrized by the choice of certain transformation matrices. For specific choices, some known formulations of reactive transport can be retrieved. Hence, the software based on the presented transformation can be used to obtain efficiency comparisons of different solution approaches. For our efficiency tests, we use the MoMaS benchmark problem on reactive transport.     

Biogenic hydrocarbons in fluid inclusions from the aberfoyle tin-tungsten deposit, Tasmania, Australia

Trace components in fluid inclusions from the Aberfoyle tin-tungsten deposit in Tasmania, Australia, were examined by thermal decrepitation-mass spectrometry. The technique involves the decrepitation of fluid inclusions by stepwise heating in the source of a mass spectrometer. In addition to water, other species identified were carbon dioxide and hydrocarbons. Detailed analysis of these hydrocarbons showed that they ranged in carbon number from C₁ up to at least C₃₃ and probably comprised, in part, biological marker compounds, previously unreported in such high-temperature environments. Their presence suggests that the fluid responsible for mineralisation was not entirely magmatic but contained a non-magmatic component evolved through fluid-rock interaction in the sedimentary country rocks.