Molecular parameters of maturation in the Toarcian shales,Paris Basin,France—III. Changes in aromatic steroid hydrocarbons

Three series of monoaromatic steroid hydrocarbons (basepeak = m/z 239, 253 and 267) and four series of triaromatic steroid hydrocarbons (basepeak = m/z 217, 231, 245 and 259) have been recognised by computerised gas chromatography-mass spectrometry in a variety of samples of Lower Toarcian shales from the Paris Basin. An increase in the extent of aromatisation of the monoaromatic steroid hydrocarbons in the m/z 253 series (measured by the abundance of monoaromatic components relative to triaromatic components in the m/z 231 series) is observed with increasing maturity. Variations between reported maximum burial depth and extent of aromatisation are explicable partly in terms of new maximum burial depth information for some of the shales. The extent of carbon-carbon bond cracking in the side chains of the aromatic steroid hydrocarbons has only begun to be significant in certain of the deepest samples.     

土壤剖面中粉煤灰垂向迁移的磁响应

对浙江省安吉县梅溪发电厂粉煤灰贮灰场附近的土壤短剖面进行环境磁学、元素含量及粒度研究.借助模糊聚类分析,分辨出粉煤灰原位堆积、富集、迁移深度及未受污染土壤特征.剖面上部0～14cm为粉煤灰的原位反映,多畴磁铁矿主导了该段样品磁性.其中11～14cm处磁性矿物和金属元素有所富集.14～21cm为粉煤灰在土壤中的迁移深度.迁移段土壤中亚铁磁性矿物及Pb、Zn等金属含量介于底部未污染土壤与上部粉煤灰原位堆积层之间.单畴斜交反铁磁性矿物及来源于上部粉煤灰的多畴磁铁矿共同主导了该段土壤的磁性特征.21cm以下土壤基本未受粉煤灰污染,单畴斜交反铁磁性矿物是其主要磁性矿物.指标聚类分析表明,亚铁磁性矿物主要赋存在粗粉砂中,单畴磁晶粒主要存在于细粉砂中.χ、ARM、SIRM与Cu、Mn、Pb、Zn呈显著相关.结合多元统计分析,磁参数可用于追踪、识别粉煤灰在土壤剖面中的垂向迁移.     

The very short period W UMa system V 1022 Ophiuchi

Photoelectric light curves of V1022 Oph inB andV are presented. It has been confirmed that it is a W UMa type eclipsing binary with one of the shortest periods known (P<0.^d25). Some general properties of the system have been derived.Based on observations made at the European Southern Observatory (La Silla/Chile)     

Till mélange at Amsdorf, central Germany: sediment erosion, transport and deposition in a complex, soft-bedded subglacial system

Glacial mélange in the open-cast mine at Amsdorf, central Germany, consists of several square meters of large, sorted sediment blocks embedded in till. The blocks are composed of largely intact to slightly deformed glaciofluvial and glaciolacustrine sand, silt and clay, initially deposited in a proglacial lake (2–3 km up-ice) and subsequently overridden by a glacier. The blocks typically have cuboid to subrounded outlines, are randomly distributed in the till, and the contacts with the surrounding till are distinctly sharp. Underneath the mélange are varved clays which exhibit strong deformations occasionally intervening with entirely undisturbed areas. It is suggested that the blocks were entrained into debris-rich basal-ice by bulk freeze-on when the glacier sole was lowered onto the bottom of an overridden lake. After entrainment the blocks were transported englacially and re-deposited (with far-traveled till matrix) as a melt-out till from stagnant ice. The glacier moved mainly by sliding enhanced by low-permeability varved clays in the substratum. The glacier is believed to have been of a polythermal type. These results show that bulk freeze-on can lead to entrainment of soft sediment blocks at least 20 m² in size, and that these blocks can be englacially transported with little or no deformation for several kilometers and more. The occurrence of deformed and undeformed clays under the till mélange indicates a possible mosaic of coupled and decoupled ice, the latter caused by a thin, transient subglacial water film separating the bed from the glacier.     

Recent southern Indian Ocean climate variability inferred from a Law Dome ice core: new insights for the interpretation of coastal Antarctic isotopic records

Stable isotopes in water have been measured along a very high accumulation ice core from Law Dome on the east Antarctic coast. These enable a detailed comparison of the isotopic records over sixty years (1934–1992) with local (Antarctic station data) and remote meteorological observations (atmospheric reanalyses and sea-surface temperature estimates) on a seasonal to inter-annual time scale. Using both observations and isotopic atmospheric general circulation model (GCM) results, we quantify the relationships between stable isotopes (d ¹⁸O, dD and deuterium excess; d = dD –8 × d ¹⁸O) with site and source temperature at seasonal and decadal time scales, showing the large imprint of source conditions on Law Dome isotopes. These calibrations provide new insights for the quantitative interpretation of temporal isotopic fluctuations from coastal Antarctic ice cores. An abrupt change in the local meridional atmospheric circulation is clearly identified from Law Dome deuterium excess during the 1970s and analysed using GCM simulations.     

On the potential of MetOp ASCAT‐derived soil wetness indices as a new aperture for hydrological monitoring and prediction: a field evaluation over Luxembourg

In situ soil moisture data from the Bibeschbach experimental catchment in Luxembourg are used to evaluate relative surface soil moisture observed with the MetOp‐A Advanced Scatterometer (ASCAT). Filtered and bias‐corrected surface soil wetness indices (SWIs) derived from coarse‐resolution (25 km) C‐band scatterometer observations are shown to be highly correlated (r = 0.86) with catchment‐averaged soil moisture measured in the field. The combination of ASCAT and ENVISAT Advanced Synthetic Aperture Radar (ASAR) data sets yields high‐resolution (1 km) relative surface soil moisture that is equally well correlated with in situ measurements. It is concluded that for soil moisture monitoring applications at a catchment scale, the two soil moisture products are equivalent. The best correlation between the SWI derived from ASCAT and ASCAT‐ASAR with in situ soil moisture observations at ca. 5 cm depth is obtained with a characteristic time length parameter T equal to 288 h. These results suggest that satellite‐derived surface soil wetness may serve as proxy for soil storage that enables the monitoring of abrupt switches in river system dynamics to appear when an effective field capacity is exceeded and rapid subsurface stormflow is initiated. In catchments where soil moisture is the main controlling factor of rapid subsurface flow, MetOp ASCAT–derived SWI has the potential to monitor how a river system approaches a critical threshold. Copyright © 2011 John Wiley & Sons, Ltd.     

Damage phenomenon and petrophysical properties of sandstones at the Phnom Bakheng Temple (Angkor,Cambodia): first investigations and possible conservation measures

Sandstones, clay in the form of bricks and laterite are the building materials used by the Khmer to construct the imposing and magnificent temples in Southeast Asia. Many of these monuments suffer from fracturing, sanding, contour scaling, crust formation and salt weathering. The affinity to weathering is closely connected to the type of material. Two sandstone types classified as feldspathic arenite and quartz arenite of Angkor as well as two arkosic sandstones from Thailand are described and investigated in this study. Important petrophysical properties determined for the different sandstones consist of hydric expansion, thermal expansion, pore radii distribution and ultrasonic velocity. Different investigations such as capillary water uptake, surface hardness, hygroscopic water sorption, and salt resistance tests were undertaken in the laboratory to characterize the various rock types. Observations and quantified damage mapping were done onsite at the Phnom Bakheng Temple. Contour scaling in the form of weathering crusts is one of the main deterioration features observable at the Angkor monuments. Comparisons are made between the building stone, the crust material from the Phnom Bakheng Temple and fresh stone material used for restoration. Significant differences in hydric and especially in thermal expansion of the crust and sandstone have been determined. The results seem to indicate that extensional processes occur, which can be considered a force for detachment (i.e., contour scaling, flaking). In an experimental trial, the hydric and thermal expansion of the weathering crust and the building stone was significantly reduced by using a weak acid for the crust and a swelling inhibitor for the original building stone.     

The Namuskluft and Dreigratberg sections in southern Namibia (Kalahari Craton,Gariep Belt): a geological history of Neoproterozoic rifting and recycling of cratonic crust during the dispersal of Rodinia until the amalgamation of Gondwana

This paper presents combined U/Pb, Th/U and Hf isotope analyses on detrital and magmatic zircon grains together with whole-rock geochemical analyses of two basement and eight sedimentary rock samples from the Namuskluft and the Dreigratberg in southern Namibia (Gariep Belt). The sedimentary sections evolved during the Cryogenian on the SW part of the Kalahari Craton and where therefore deposited in an active rift setting during the break-up of Rodinia. Due to insufficient palaeomagnetic data, the position of the Kalahari Craton within Rodinia is still under discussion. There are possibilities to locate Kalahari along the western side of Australia/Mawsonland (Pisarevski et al. in Proterozoic East Gondwana: supercontinent assembly and break-up, Geological Society, London, 2003; Evans in Ancient Orogens and modern analogues. Geological Society, London, 2009; and others) or together with the Congo-Sao Francisco and Rio de la Plata Cratons (Li et al. in Prec Res 45: 203–2014, 2008; Frimmel et al. in Int J Earth Sci (Geol Rundsch) 100: 323–354, 2011; and others). It is sill unclear which craton rifted away from the Kalahari Craton during the Cryogenian. Although Middle to Upper Cryogenian magmatic activity is known for the SE Kalahari Craton (our working area) (Richtersveld Suite, Rosh Pinah Fm), all the presented samples show no U/Pb zircon ages younger than ca. 1.0 Ga and non-older than 2.06 Ga. The obtained U/Pb ages fit very well to the exposed basement of the Kalahari Craton (1.0–1.4 Ga Namaqua Province, 1.7–2.0 Ga Vioolsdrif Granite Suite and Orange River Group) and allow no correlation with a foreign craton such as the Rio de la Plata or Australia/Mawsonland. Lu–Hf isotopic signatures of detrital zircon point to the recycling of mainly Palaeoproterozoic and to a smaller amount of Archean crust in the source areas. εHf(t) signatures range between ?24 and +14.8, which relate to T_DM model ages between 1.05 and 3.1 Ga. Only few detrital zircon grains derived from magmas generated from Mesoproterozoic crustal material show more juvenile εHf(t) signatures of +14, +8 to +4 with T_DM model ages of 1.05–1.6 Ga. During Neoproterozoic deposition, only old cratonic crust with an inherited continental arc signature was available in the source area clearly demonstrated by Hf isotope composition of detrital zircon and geochemical bulk analysis of sedimentary rocks. The granodiorites of the Palaeoproterozoic basement underlying Namuskluft section are ca. 1.9 Ga old and show εHf(t) signatures of ?3 to ?5.5 with T_DM model ages of 2.4–2.7 Ga. These basement rocks demonstrate the extreme uplift and deep erosion of the underlying Kalahari Craton at its western margin before general subsidence during Cryogenian and Ediacaran time. The sedimentary sequence of the two examined sections (Namuskluft and Dreigratberg) proposes the presence of a basin and an increasing subsidence at the SW part of the Kalahari Craton during the Cryogenian. Therefore, we propose the initial formation of an intra-cratonic sag basin during the Lower Cryogenian that evolved later to a rift basin at the cratonic margin due to increasing crustal tension and rifting together with the opening of the Adamastor Ocean. As the zircons of the sedimentary rocks filling this basin show neither rift-related U/Pb ages nor an exotic craton as a possible source area, the only plausible sedimentary transport direction providing the found U/Pb ages would be from the E or the SE, directly from the heart of the Kalahari Craton. Due to subsidence and ongoing sedimentation from E/SE directions, the rift-related magmatic rocks were simply covered by the input of old intra-cratonic material that explains the absence of Neoproterozoic zircon grains in our samples. The geochemical analyses show the erosion of a continental arc and related sedimentary rocks with an overall felsic provenance. The source area was a deeply eroded and incised magmatic arc that evolved on continental crust, without any evidence for a passive margin. All of this can be explained by the erosion of rocks related to the Namaqua Belt, which represents one of the two major peaks of zircon U–Pb ages in all analysed samples. Therefore, the Namaqua Belt was well exposed during the Cryogenian, available to erosion and apart from the also well-exposed Palaeoproterozoic basement of the Kalahari Craton one potential source area for the sedimentary rocks in the investigated areas.     

Geologic constraints on the origin of red organic‐rich material on Ceres

The geologic context of red organic‐rich materials (ROR) found across an elongated 200 km region on Ceres is evaluated with spectral information from the multispectral framing camera (FC) and the visible and near‐infrared mapping spectrometer (VIR) of Dawn. Discrete areas of ROR materials are found to be associated with small fresh craters less than a few hundred meters in diameter. Regions with the highest concentration of discrete ROR areas exhibit a weaker diffuse background of ROR materials. The observed pattern could be consistent with a field of secondary impacts, but no appropriate primary crater has been found. Both endogenic and exogenic sources are being considered for these distinctive organic materials.