SELENE project status

SELENE (Selenological and Engineering Explorer) project started as a joint mission of the former ISAS (Institute of Space and Astronautical Science) and the former NASDA (National Space Development Agency: the two organizations were merged into JAXA in 2002) of Japan in 1998. The launch target is rescheduled for 2006 due to delay of completion of launch vehicle, H-IIA. The SELENE project is now under a sustained design phase. The flight model components were manufactured, and the interface tests between the bus-system and the mission instruments were completed by the end of March 2004. The functional checks and calibration for the flight model components are being carried out at present. From the beginning of 2005, the final assembly tests will start.     

High-pressure transformations of ilmenite to perovskite, and lithium niobate to perovskite in zinc germanate

In-situ X-ray powder diffraction measurements conducted under high pressure confirmed the existence of an unquenchable orthorhombic perovskite in ZnGeO₃. ZnGeO₃ ilmenite transformed into perovskite at 30.0 GPa and 1300±150 K in a laser-heated diamond anvil cell. After releasing the pressure, the lithium niobate phase was recovered as a quenched product. The perovskite was also obtained by recompression of the lithium niobate phase at room temperature under a lower pressure than the equilibrium phase boundary of the ilmenite–perovskite transition. Bulk moduli of ilmenite, lithium niobate, and perovskite phases were calculated on the basis of the refined X-ray diffraction data. The structural relations among these phases are considered in terms of the rotation of GeO₆ octahedra. A slight rotation of the octahedra plays an important role for the transition from lithium niobate to perovskite at ambient temperature. On the other hand, high temperature is needed to rearrange GeO₆ octahedra in the ilmenite–perovskite transition. The correlation of quenchability with rotation angle of GeO₆ octahedra for other germanate perovskites is also discussed.     

Long-term high-frequency measurements of dibromomethane in the atmosphere at algae-rich and algae-poor coastal sites

Dibromomethane (CH₂Br₂), a natural stratospheric ozone depleting substance, is mostly emitted from the ocean, but the relative importance of coastal (or macroalgae) and open ocean emissions is unknown. We made long-term high-frequency measurements of CH₂Br₂ concentrations at two remote coastal sites in Japan, on the subtropical Hateruma Island (poor in macroalgae) and at Cape Ochiishi (rich in macroalgae). CH₂Br₂ concentrations at Hateruma showed prominent seasonal variation, being lower in summer (around 0.94 ppt) than in winter (around 1.23 ppt). In contrast, CH₂Br₂ concentrations at Ochiishi were highly variable, often exceeding 2 ppt in the summer but with minimum baseline concentrations close to those from Hateruma; in the winter the concentrations were almost constant at about 1.3 ppt. Analysis of the data suggested that (1) emissions from macroalgae were not likely to extend offshore, but instead were localized near the shore, (2) strong macroalgal emissions of CH₂Br₂ were almost limited to the summer, but it was not reflected in the seasonality of the baseline concentrations of CH₂Br₂ in the atmosphere, and therefore (3) macroalgal or coastal emissions of CH₂Br₂ in the temperate zone might have a rather limited contribution to the global CH₂Br₂ sources. These findings are especially important for the understanding of the tropospheric and stratospheric bromine budget.     

Geochemical relation between gas hydrates and water venting in the seismic blanking zone on the northern Cascadia continental margin offshore Vancouver Island, Canada

The isotopic composition (δD and δ¹⁸O) and chloride concentration (Cl⁻) of pore waters from the northern Cascadia continental margin offshore Vancouver Island were measured to characterize the relations between the water flow regime and the distribution, formation and dissociation of gas hydrates. The δD values of pore waters in gas hydrate-bearing sediments are slightly higher ( 1‰) than those of seawater as the result of gas hydrate dissociation during core recovery and handling. Within the seismic blanking zone, the δD values were slightly lower (− 1‰) than values measured from sites outside the blanking area (0‰). We attribute these differences to 1) distillation of D-rich water during hydrate formation in the center of the blanking zone and 2) limited migration of pore water between inside and outside of the blanking zone due to different fluid fluxes. In contrast, the δ¹⁸O values and Cl⁻ concentrations do not show significant spatial variation due to decreased isotopic fractionation of oxygen and small fraction of chloride relative to hydrogen isotope during gas hydrate formation. The δD value of pore water, therefore, appears to be a sensitive indicator of gas hydrate occurrence. We estimate that gas hydrate occupied at least 2.0 to 6.3% of sediment pore space using δD distribution in this area.     

Thermodynamic properties of chlorite and berthierine derived from calorimetric measurements

In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al_0.975FeIII_0.182FeII_1.422Mg_0.157Li_0.035Mn_0.002)(Si_1.332Al_0.668)O₅(OH)₄] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si_2.633Al_1.367)(Al_1.116FeIII_0.215Mg_2.952FeII_1.712Mn_0.012Ca_0.011)O₁₀(OH)₈]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature.     

The basement geology of Japan from A to Z

The Precambrian and lower Paleozoic units of the Japanese basement such as the Hida Oki and South Kitakami terranes have geological affinities with the eastern Asia continent and particularly strong correlation with units of the South China block. There are also indications from units such as the Hitachi metamorphics of the Abukuma terrane and blocks in the Maizuru terrane that some material may have been derived from the North China block. In addition to magmatism, the Japanese region has seen substantial growth due to tectonic accretion. The accreted units dominantly consist of mudstone and sandstone derived from the continental margin with lesser amounts of basaltic rocks associated with siliceous deep ocean sediments and local limestone. Two main phases of accretionary activity and related metamorphism are recorded in the Jurassic Mino–Tanba–Ashio, Chichibu, and North Kitakami terranes and in the Cretaceous to Neogene Shimanto and Sanbagawa terranes. Other accreted material includes ophiolitic sequences, e.g. the Yakuno ophiolite of the Maizuru terrane, the Oeyama ophiolite of the Sangun terrane, and the Hayachine–Miyamori ophiolite of the South Kitakami terrane, and limestone‐capped ocean plateaus such as the Akiyoshi terrane. The ophiolitic units are likely derived from arc and back‐arc basin settings. There has been no continental collision in Japan, meaning the oceanic subduction record is more complete than in convergent orogens seen in intracontinental settings making this a good place to study the geological record of accretion. Hokkaido lacks most of the Paleozoic history recognized in Honshu, Shikoku, Kyushu, and the Ryukyu Islands to the south and its geology reflects the Cenozoic development of two convergent domains with volcanic arcs, their approach, and eventual collision. The Hidaka terrane reveals a cross section through a volcanic arc and the main accretionary complex of the convergent system is represented by the Sorachi–Yezo terrane.     

Triplications for the converted wave in transversely isotropic media with a tilted symmetry axis

In seismic data processing, serious problems could be caused by the existence of triplication and need to be treated properly for tomography and other inversion methods. The triplication in transversely isotropic medium with a vertical symmetry axis has been well studied and concluded that the triplicated traveltime only occurs for S wave and there is no triplication for P and converted PS waves since the P wave convexity slowness always compensates the S wave slowness concavity. Compared with the vertical symmetry axis model, the research of the triplication in transversely isotropic medium with a tilted symmetry axis is still keeping blank. In order to analyse the triplication for the converted wave in the tilted symmetry axis model, we examine the traveltime of the triplication from the curvature of averaged P and S wave slowness. Three models are defined and tested in the numerical examples to illustrate the behaviour of the tilted symmetry axis model for the triplicated traveltime with the change of the rotation angle. Since the orientation of an interface is related to the orientation of the symmetry axis, the triplicated traveltime is encountered for the converted wave in the tilted symmetry axis model assuming interfaces to be planar and horizontal. The triplicated region is influenced by the place and level of the concave curvature of the P and S wave slowness.     

Effect of bed roughness on turbulent boundary layer and net sediment transport under asymmetric waves

This paper presents an investigation of the roughness effects in the turbulent boundary layer for asymmetric waves by using the baseline (BSL) k–ω model. This model is validated by a set of the experimental data with different wave non-linearity index, N_i (namely, N_i = 0.67, N_i = 0.60 and N_i = 0.58). It is further used to simulate asymmetric wave velocity flows with several values of the roughness parameter (a_m/k_s) which increase gradually, namely from a_m/k_s = 35 to a_m/k_s = 963. The effect of the roughness tends to increase the turbulent kinetic energy and to decrease the mean velocity distribution in the inner boundary layer, whereas in the outer boundary layer, the roughness alters the turbulent kinetic energy and the mean velocity distribution is relatively unaffected. A new simple calculation method of bottom shear stress based on incorporating velocity and acceleration terms is proposed and applied into the calculation of the rate of bed-load transport induced by asymmetric waves. And further, the effect of bed roughness on the bottom shear stress and bed-load sediment transport under asymmetric waves is examined with the turbulent model, the newly proposed method, and the existing calculation method. It is found that the higher roughness elements increase the magnitude of bottom shear stress along a wave cycle and consequently, the potential net sediment transport rate. Moreover, the wave non-linearity also shows a big impact on the bottom shear stress and the net sediment transport.