High-resolution observations of dissolved isoprene in surface seawater in the Southern Ocean during austral summer 2010–2011

We measured dissolved isoprene (2-methyl-1,3-butadiene; C₅H₈) concentrations in a broad area of the southern Indian Ocean and in the Indian sector of the Southern Ocean from 35°S to 64°S and from 37°E to 111°E during austral summer 2010–2011. Isoprene concentrations were continuously measured by use of a proton-transfer-reaction mass spectrometer combined with a bubbling-type equilibrator. Concentrations of isoprene and its emission flux throughout the study period ranged from 0.2 to 395 pmol L^?1 and from 181 to 313 nmol m^?2 day^?1, respectively, the averages being generally higher than those of previous studies. Although we found a significant linear positive relationship between isoprene and chlorophyll-a concentrations (r ² = 0.37, n = 36, P < 0.001), the correlation coefficient was lower than previously reported. In contrast, in the high-latitude area (>53°S) we identified a significant negative correlation (r ² = 0.59, n = 1263, P < 0.001) between isoprene and the temperature-normalized partial pressure of carbon dioxide (n-pCO₂), used as an indicator of net community production in this study. This suggests that residence times and factors controlling variations in isoprene and n-pCO₂ are similar within a physically stable water column.     

Interpretation of undisturbed hydrogeochemical conditions in Neogene sediments of the Horonobe area, Hokkaido, Japan

Empirical, geostatistical and geochemical modeling techniques were used to determine whether chemical, isotopic and mineralogical data collected in surface-based borehole investigations at the Horonobe Underground Research Laboratory (URL) site in Hokkaido, Japan were representative of the natural environment before it was disturbed by borehole drilling, hydraulic testing and sampling. Water samples collected either by pumping groundwaters to the surface from borehole sections that had been isolated by inflatable packers or by squeezing porewaters from drillcores sampled from the same borehole and sampling depth were found to be similar in certain respects (m_Na+, m_Cl−, δ¹⁸O and δD) but not others (m_SO42−, m_Ca2+, m_Mg2+ and m_K+). The inconsistencies suggest that a majority of the porewater samples were contaminated as a result of pyrite oxidation and dissolution of carbonate minerals during sampling, storage and/or squeezing of the drillcores. Multivariate geostatistical analyses support this hypothesis, and further suggest that uncontaminated porewaters and groundwaters can be divided into three representative groups: a low salinity, low δ¹⁸O and low δD group; a moderate salinity, low Ca-Mg group; and a high salinity, high K and moderate Ca-Mg group. The groundwaters also contain high concentrations of dissolved gases, including CH₄(g), CO₂(g), H₂S(g) and various hydrocarbons, which exsolve from the groundwaters as they are pumped to the surface for sampling. The effects of such degassing on the chemistry of groundwater samples was evaluated by using a reaction-path model to simulate the titration of gases collected at the surface back into the samples. Results suggest that undisturbed groundwaters are slightly more acidic than their sampled counterparts, and contain roughly equivalent activities of dissolved CH₄(aq) and carbonate species. Redox potentials calculated using the corrected groundwater compositions and assuming equilibrium for the CH₄(aq)/CO₂(aq) redox couple are significantly more negative than those determined in situ in one borehole using a downhole chemical probe, and those that can be inferred from the ubiquitous presence of small amounts of framboidal pyrite and siderite in siliceous biogenic sediments of the Horonobe area. The empirical, geostatistical and geochemical modeling techniques considered in this study can be adapted for use in characterizing the hydrogeochemical environment of a site that will eventually be selected to host a geologic repository for high-level nuclear waste in Japan.     

Improved Estimates of Wide-Ranging Sea Surface Temperature from GMS S-VISSR Data

We have developed an algorithm to estimate the wide-ranging Sea Surface Temperature (SST) data from the GMS-5 (Geostationary Meteorological Satellite) S-VISSR (Stretched-Visible Infrared Spin Scan Radiometer). Better SST estimates are realized by averaging the temporal variation of the VISSR calibration table and decreasing noise of the split-window terms using a spatial filter. The effects of the satellite zenith angle were examined in detail for better estimates, and VISSR-derived SSTs with root-mean-square (rms) error of 0.8 K were achieved using a new algorithm. The accuracy of SST estimates has been improved by using the temporal-spatial average of the split-window terms. Using the new techniques, we demonstrate that the hourly wide-ranging SST image data can be used to study the daily variations of SSTs in the Northern and Southern Pacific Oceans.     

On the Polyps of the Common Jellyfish Aurelia aurita in Kagoshima Bay

There is the natural habitat of polyps of the common jellyfish Aurelia aurita in the Taniyama area, Kagoshima Bay. We examined the attachment substrata, density, colony structure and strobilation of the polyps. The polyps were observed only on the horizontal undersurface of floating piers. They attached specifically to Mytilus shells, solitary ascidians, calcareous polychaete tubes, muddy amphipod tubes and the gap space that fouling animals peeled off the substrata. The polyp colonies were distributed in patches. Spatial distribution patterns of the polyps within their colonies were uniform. Strobilation occurred during late December to March, when water temperatures were 16–17°C, and a large number of ephyrae were released. An increase in man-made structures such as floating piers in coastal areas may lead to bloomings of Aurelia aurita medusae. This revised version was published online in July 2006 with corrections to the Cover Date.     

The definition of the ecliptic

The ecliptic as a mean orbital plane of the Sun in Le Verrier's theory is a mean orbital plane determined from the secular parts of the longitude of the ascending node and the inclination of the Sun with respect to a reference plane. On the other hand, the ecliptic in Newcomb's theory is so chosen that the latitude with respect to his ecliptic does not have cosg nor sing whereg is the mean anomaly of the Sun. The two definitions are really different in spite of their apparent similarity. Standish (1981) defined the ecliptic from a kinematical point of view, and it is shown that the ecliptic defined by Standish (in the rotating sense) does coincide with the ecliptic defined by Newcomb.     

Particle acceleration in the 1981 April 1 flare

The large microwave burst of 1981 April 1, which was accompanied by both hard X-ray and γ-ray emissions, was analyzed to study the acceleration of particles in the impulsive phase. The analysis suggests the following results. (1) Electrons were accelerated up to energies of several hundred keV in a low loop. On the other hand, electrons were accelerated to relativistic energy without injection of pre-accelerated electrons near the top of a large loop where energetic ions were also probably accelerated. (2) The mechanism for accelerating electrons to relativistic energy and also ions was different from that for accelerating electrons up to energies of several hundred KeV and was closely related with upward motion of a flare loop.     

Mass dispersal and angular momentum transfer during collisions between rubble-pile asteroids. II. Effects of initial rotation and spin-down through disruptive collisions

Expanding on our previous N-body simulation of impacts between initially non-rotating rubble-pile objects [Takeda, T., Ohtsuki, K., 2007. Icarus 189, 256-273], we examine effects of initial rotation of targets on mass dispersal and change of spin rates. Numerical results show that the collisional energy needed to disrupt a rubble-pile object is not sensitive to initial rotation of the target, in most of the parameter range studied in our simulations. We find that initial rotation of targets is slowed down through disruptive impacts for a wide range of parameters. The spin-down is caused by escape of high-velocity ejecta and asymmetric re-accumulation of fragments. When these effects are significant, rotation is slowed down even when the angular momentum added by an impactor is in the same direction as the initial rotation of the target. Spin-down is most efficient when the impact occurs in the equatorial plane of the target, because in this case most of the ejected fragments originate from the equatorial region of the target and a significant amount of angular momentum can be easily removed. In the case of impacts from directions inclined relative to the target's equatorial plane, spin-down still occurs with reduced degree, unless impacts occur onto the pole region from the vertical direction. Our results suggest that such spin-down through disruptive impacts may have played an important role in spin evolution of asteroids through collisions in the gravity-dominated regime.     

Location and parameters of a microwave millisecond spike event

A typical microwave millisecond spike event on November 2, 1997 was observed by the radio spectrograph of National Astronomical Observatories (NAOs) at 2.6–3.8 GHz with high time and frequency resolution. This event was also recorded by Nobeyama Radio Polarimeters (NoRP) at 1–35 GHz and Radio Heliograph (NoRH) at 17 GHz. The source at 17 GHz is located in one foot-point of a small bright coronal loop of YOHKOH SXT and SOHO EIT images with strong photospheric magnetic field in SOHO MDI magnetograph. It is assumed that the electron cyclotron maser instability and gyro-resonance absorption dominate, respectively, the rising and decay phase of the spike event. For different harmonic number of gyro-frequency or magnetic field strength, a fitting program with free plasma parameters is used to minimize the difference between the observational and theoretical values of the exponential growth and decay rates for a given spike. The plasma parameters at third harmonic number are more comparable to their typical values in solar corona. Hence, it is able to provide a diagnosis for the source parameters (magnetic field, density, and temperature), the properties of radiations (wave vector and propagation angle), and the properties of non-thermal electrons (density, pitch angle, and energy). The results are also comparable with the diagnosis of the gyro-synchrotron radiation model, the frequency drift rates and a dipole magnetic field model, as well as the YOHKOH SXT and SOHO MDI data. This study is supported by the NFSC project nos. 10333030 and 10273025, and “973” program with no. G2000078403.     

Gas capture and rare gas retention by accreting planets in the solar nebula

In this paper, the physico-chemical effects of the nebula gas on the planets are reviewed from a standpoint of planetary formation in the solar nebula.The proto-Earth growing in the nebula was surrounded by a primordial atmosphere with a solar chemical composition and solar isotopic composition. When the mass of the proto-Earth was greater than 0.3 times the present Earth mass, the surface was molten because of the blanketing effect of the atmosphere. Therefore, the primordial rare gasses contained in the primordial atmosphere dissolved into the molten Earth material without fractionation and in particular the dissolved neon is expected to be conserved in the present Earth material. Hence, if dissolved neon with a solar isotopic ratio is discovered in the Earth material, it will indicate that the Earth was formed in the nebula and that the dissolved rare gases were one of the sources which degassed to form the present atmosphere.