Solid‐state 13C NMR characterization of insoluble organic matter from Antarctic CM2 chondrites: Evaluation of the meteoritic alteration level

Abstract— Chemical structures of the insoluble organic matter (IOM) from the Antarctic CM2 chondrites (Yamato [Y‐] 791198, 793321; Belgica [B‐] 7904; Asuka [A‐] 881280, 881334) and the Murchison meteorite were analyzed by solid‐state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Different types of carbons were characterized, such as aliphatic carbon (Ali‐C), aliphatic carbon linked to hetero atom (Hetero‐Ali‐C), aromatic carbon (Aro‐C), carboxyls (COOR), and carbonyls (C=O). The spectra of the IOM from Murchison and Y‐791198 showed two major peaks: Ali‐C and Aro‐C, while the spectra from the other meteorites showed only one major peak of Aro‐C. Carbon distribution was determined both by manual integration and deconvolution. For most IOM, the Aro‐C was the most abundant (49.8–67.8%) of all carbon types. When the ratios of Ali‐C to Aro‐C (Ali/Aro) were plotted with the atomic hydrogen to carbon ratio (H/C), a correlation was observed. If we use the H/C as a parameter for the thermal alteration event on the meteorite parent body, this result shows a different extent of thermal alteration. In addition, IOM with a lower Ali/Aro showed a lower ratio of Ali‐C to COOR plus C=O (Ali / (COOR + C=O)). This result suggests that the ratio of CO moieties to aliphatic carbon in IOM might reflect chemical oxidation that was involved in hydrothermal alteration.     

Oxygen isotope characteristics of chondrules from the Yamato‐82094 ungrouped carbonaceous chondrite: Further evidence for common O‐isotope environments sampled among carbonaceous chondrites

High‐precision secondary ion mass spectrometry (SIMS) was employed to investigate oxygen three isotopes of phenocrysts in 35 chondrules from the Yamato (Y) 82094 ungrouped 3.2 carbonaceous chondrite. Twenty‐one of 21 chondrules have multiple homogeneous pyroxene data (?¹⁷O 3SD analytical uncertainty: 0.7‰); 17 of 17 chondrules have multiple homogeneous pyroxene and plagioclase data. Twenty‐one of 25 chondrules have one or more olivine data matching coexisting pyroxene data. Such homogeneous phenocrysts (1) are interpreted to have crystallized from the final chondrule melt, defining host O‐isotope ratios; and (2) suggest efficient O‐isotope exchange between ambient gas and chondrule melt during formation. Host values plot within 0.7‰ of the primitive chondrule mineral (PCM) line. Seventeen chondrules have relict olivine and/or spinel, with some δ¹⁷O and δ¹⁸O values approaching ?40‰, similar to CAI or AOA‐like precursors. Regarding host chondrule data, 22 of 34 have Mg#s of 98.8–99.5 and ?¹⁷O of ?3.9‰ to ?6.1‰, consistent with most Acfer 094, CO, CR, and CV chondrite chondrules, and suggesting a common reduced O‐isotope reservoir devoid of ¹⁶O‐poor H₂O. Six Y‐82094 chondrules have ?¹⁷O near ?2.5‰, with Mg#s of 64–97, consistent with lower Mg# chondrules from Acfer 094, CO, CR, and CV chondrites; their signatures suggest precursors consisting of those forming Mg# ~99, ?¹⁷O: ?5‰ ± 1‰ chondrules plus ¹⁶O‐poor H₂O, at high dust enrichments. Three type II chondrules plot slightly above the PCM line, near the terrestrial fractionation line (?¹⁷O: ~+0.1‰). Their O‐isotopes and olivine chemistry are like LL3 type II chondrules, suggesting they sampled ordinary chondrite‐like chondrule precursors. Finally, three Mg# >99 chondrules have ?¹⁷O of ?6.7‰ to ?8.1‰, potentially due to ¹⁶O‐rich refractory precursor components. The predominance of Mg# ~99, ?¹⁷O: ?5‰ ± 1‰ chondrules and a high chondrule‐to‐matrix ratio suggests bulk Y‐82094 characteristics are closely related to anhydrous dust sampled by most carbonaceous chondrite chondrules.     

∼3,850 Ma tonalites in the Nuuk region,Greenland: geochemistry and their reworking within an Eoarchaean gneiss complex

The Eoarchaean (>3,600 Ma) Itsaq Gneiss Complex of southern West Greenland is dominated by polyphase orthogneisses with a complex Archaean tectonothermal history. Some of the orthogneisses have c. 3,850 Ma zircons, and they vary from rare single phase metatonalites to more common complexly banded migmatites. This is due to heterogeneous strain, in situ anatexis and granitic veining superimposed during younger tectonothermal events. In the single-phase tonalites with c. 3,850 Ma zircon, oscillatory-zoned prismatic zircon is all 3,850 Ma old, but shows patchy ancient loss of radiogenic Pb. SHRIMP spot analyses and laser ablation ICP-MS depth profiling show that thin (usually < 10 μm) younger (3,660–3,590 Ma and Neoarchaean) shells of lower Th/U metamorphic zircon are present on these 3,850 Ma zircons. Several samples with this simple zircon population occur on islands near Akilia. In contrast, migmatites usually contain more complex zircon populations, with often more than one generation of igneous zircon present. Additional zircon dating of banded gneisses across the Complex shows that samples with c. 3,850 Ma igneous zircon are not just a phenomenon restricted to Akilia and adjacent islands. For example, migmatites from Itilleq (c. 65 km from Akilia) contain variable amounts of oscillatory-zoned 3,850 Ma and 3,650 Ma zircon, interpreted, respectively, as the rock age and the time of crustal melting under Eoarchaean metamorphism. With only 110–140 ppm Zr in the tonalites and likely magmatic temperatures of >850°C, zircon solubility–melt composition relationships show that they were only one-third saturated in zircon. Any zircon entrained in the precursor magmas would thus have been highly soluble. Combined with the cathodoluminesence imaging, this demonstrates that the c. 3,850 Ma oscillatory zoned zircon crystallised out of the melt and hence gives a magmatic age. Thus the rare well-preserved tonalites and palaeosome in migmatites testify that c. 3,850 Ma quartzo–feldspathic rocks are a widespread (but probably minor) component in the Itsaq Gneiss Complex. C. 3,850 Ma zircon with negative Eu anomalies (showing growth in felsic systems) also occurs as detrital grains in rare c. 3,800 Ma metaquartzites and as inherited grains in some 3,660 Ma granites (sensu stricto). These demonstrate that still more c. 3,850 Ma rocks were present, but were recycled into Eoarchaean sediments and crustally derived granites. The major and trace element characteristics (e.g. LREE enrichment, HREE depletion, low MgO) of the best-preserved c. 3,850 Ma rocks are typical of Archaean TTG suites, and thus argue for crust formation processes involving important contributions from melting of hydrated mafic crust to the earliest Archaean. Five c. 3,850 Ma tonalites were selected as the best preserved on the basis of field criteria and zircon petrology. Four of these samples have overlapping initial ɛ_Nd (3,850 Ma) values from +2.9 to +3.6± 0.5, with the fourth having a slightly lower value of +0.6. These data provide additional evidence for a markedly LREE-depleted early terrestrial mantle reservoir. The role of c. 3,850 Ma crust should be considered in interpreting isotope signatures of the younger (3,800–3,600 Ma) rocks of the Itsaq Gneiss Complex. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Resonance capacity method for earthquake response analysis of hysteretic structures

The Resonance Capacity Method is proposed for the earthquake response analysis of hysteretic structures. Resonance Capacity is a physical quantity of structures which is related to the hysteretic energy absorbed by structures in one cycle and is equated to the acceleration, velocity and displacement amplitudes α₀, d₀ and d₀ of earthquake ground motions at resonance.¹ According to the idealized trapezoidal approximation of earthquake ground motions in the logarithmic period–velocity plane as proposed by Veletsos and Newmark,⁸ the Resonance Capacity property applies in each period range, short, medium and long, where α₀, v₀ and d₀ respectively are approximately constant. In the medium range of periods, the energy dissipated in hysteretic loops and the deformation amplitudes of a single-degree system with elasto–plastic force–deformation relationships are calculated for the case of El Centro 1940, 18 May earthquake, by this Resonance Capacity Method. The result is compared with results from conventional numerical response analyses obtained by Berg and Thomaides,¹⁴ Kato and Akiyama¹² and Veletsos and Newmark,⁸ and the general agreement is seen to be good. Therefore, it may be possible to apply this Resonance Capacity Method over the entire range of periods. By means of this method the earthquake response analysis of hysteretic systems can be performed easily, and the hysteretic energy and fatigue characteristics of structures may be taken into account directly, up to the point of fracture.     

Paleogeographic maps of the Japanese Islands: Plate tectonic synthesis from 750 Ma to the present

Abstract A series of paleogeographic maps of the Japanese Islands, from their birth at ca 750–700 Ma to the present, is newly compiled from the viewpoint of plate tectonics. This series consists of 20 maps that cover all of the major events in the geotectonic evolution of Japan. These include the birth of Japan at the rifted continental margin of the Yangtze craton ( ca 750-700 Ma), the tectonic inversion of the continental margin from passive to active ( ca 500 Ma), the Paleozoic accretionary growth incorporating fragments from seamounts and oceanic plateaux ( ca 480-250 Ma), the collision between Sino-Korea and Yangtze (250–210 Ma), the Mesozoic to Cenozoic accretionary growth (210 Ma-present) including the formation of the Cretaceous paired metamorphic belts (90 Ma), and the Miocene back-arc opening of the Japan Sea that separated Japan as an island arc (25-15 Ma).     

Strain and tilt changes measured during a water injection experiment at the Nojima Fault zone, Japan

Abstract In order to make geophysical and geological investigations of the Nojima Fault on Awaji Island, Japan, three boreholes measuring 1800 m, 800 m and 500 m deep were drilled into the fault zone. The fault is one of the seismic source faults of the 1995 Hyogo-ken Nanbu earthquake of M 7.2. A new multicomponent borehole instrument was installed at the bottom of the 800 m borehole and continuous observations of crustal strain and tilt have been made using this instrument since May 1996. A high-pressure water injection experiment within the 1800 m borehole was done in February and March 1997 to study the geophysical response, behavior, permeability, and other aspects of the fault zone. The injection site was located approximately 140 m horizontally and 800 m vertically from the instrument. Associated with the water injection, contraction of approximately 0.7 × 10⁻⁷ str (almost parallel to the fault) and tilt of approximately 1 × 10^-7 rad in the sense of upheaval toward the injection site were observed. In addition to these controlled experiments, the strainmeter and tiltmeter also recorded daily variations. We interpret strain and tilt changes to be related to groundwater discharge and increased ultra-micro seismicity induced by the injected water.     

Hybrid vibration experiments with a bridge foundation system model

In order to improve seismic design technology of bridges, it is necessary to evaluate the vibration characteristics of a bridge–soil system that consists of soil, foundation structure, pier and superstructure. However, there have been few experimental studies on seismic behavior of bridge–soil system. In this paper, we conducted the hybrid vibration experiment on seismic behavior of bridge–soil system, and examined the applicability of hybrid vibration experiment to study seismic response of bridge–soil system. Based on the experiment results, seismic response of bridge was quantitatively studied.     

Numerical study of the oxidation process of dimethylsulfide in the marine atmosphere

A box model, involving simple heterogeneous reaction processes associated with the production of non-sea-salt sulfate (nss-SO ₄ ^2– ) particles, is used to investigate the oxidation processes of dimethylsulfide (DMS or CH₃SCH₃) in the marine atmosphere. The model is applied to chemical reactions in the atmospheric surface mixing layer, at intervals of 15 degrees latitude between 60° N and 60° S. Given that the addition reaction of the hydroxyl radical (OH) to the sulfur atom in the DMS molecule is faster at lower temperature than at higher temperature and that it is the predominant pathway for the production of methanesulfonic acid (MSA or CH₃SO₃H), the results can well explain both the increasing tendency of the molar ratio of MSA to nss-SO ₄ ^2– toward higher latitudes and the uniform distribution with latitude of sulfur dioxide (SO₂). The predicted production rate of MSA increases with increasing latitude due to the elevated rate constant of the addition reaction at lower temperature. Since latitudinal distributions of OH concentration and DMS reaction rate with OH are opposite, a uniform production rate of SO₂ is realized over the globe. The primary sink of DMS in unpolluted air is caused by the reaction with OH. Reaction of DMS with the nitrate radical (NO₃) also reduces DMS concentration but it is less important compared with that of OH. Concentrations of SO₂, MSA, and nss-SO ₄ ^2– are almost independent of NO _x concentration and radiation field. If dimethylsulfoxide (DMSO or CH₃S(O)CH₃) is produced by the addition reaction and further converted to sulfuric acid (H₂SO₄) in an aqueous solution of cloud droplets, the oxidation process of DMSO might be important for the production of aerosol particles containing nss-SO ₄ ^2– at high latitudes.