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51.
Juan Huang Yanli Feng Jian Li Bin Xiong Jialiang Feng Sheng Wen Guoying Sheng Jiamo Fu Minghong Wu 《Journal of Atmospheric Chemistry》2008,61(1):1-20
The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering
winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls
were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of
19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m−3 respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with
peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer
and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed
obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected
in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution
of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher
concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants
from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou,
the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in
Shanghai was even worse than expected. 相似文献
52.
General purpose Computational Fluid Dynamics (CFD) solvers are frequently used in small-scale urban pollution dispersion simulations
without a large extent of ver- tical flow. Vertical flow, however, plays an important role in the formation of local breezes,
such as urban heat island induced breezes that have great significance in the ventilation of large cities. The effects of
atmospheric stratification, anelasticity and Coriolis force must be taken into account in such simulations. We introduce a
general method for adapting pressure based CFD solvers to atmospheric flow simulations in order to take advantage of their
high flexibility in geometrical modelling and meshing. Compressibility and thermal stratification effects are taken into account
by utilizing a novel system of transformations of the field variables and by adding consequential source terms to the model
equations of incompressible flow. Phenomena involving mesoscale to microscale coupled effects can be analyzed without model
nesting, applying only local grid refinement of an arbitrary level. Elements of the method are validated against an analytical
solution, results of a reference calculation, and a laboratory scale urban heat island circulation experiment. The new approach
can be applied with benefits to several areas of application. Inclusion of the moisture transport phenomena and the surface
energy balance are important further steps towards the practical application of the method. 相似文献
53.
An evaluation of oceanic containment strategies for anthropogenic carbon dioxide is presented. Energy conservation is also addressed through an input hydrocarbon-fuel consumption function. The effectiveness of the proposed countermeasures is determined from atmospheric CO2 concentration predictions. A previous box model with a diffusive deep ocean is adapted and applied to the concept of fractional CO2 injection in 500 m deep waters. Next, the contributions of oceanic calcium carbonate sediment dissolution, and of deep seawater renewal, are included. Numerical results show that for CO2 direct removal measures to be effective, large fractions of anthropogenic carbon dioxide have to be processed. This point favors fuel pre-processing concepts. The global model also indicates that energy conservation, i.e. a hydrocarbon-fuel consumption slowdown, remains the most effective way to mitigate the greenhouse effect, because it offers mankind a substantial time delay to implement new energy production alternatives. 相似文献
54.
Climatic regime shift and decadal anomalous events in China 总被引:15,自引:0,他引:15
Climatic time series from historical documents and instrumental records from China showed temporal and regional patterns in
the last two to three centuries, including two multidecadal oscillations at quasi-20-year and quasi-70-year timescales revealed
by signal analysis from wavelet transform. Climatic anomalous events on the decadal timescale were identified based on the
two oscillations when their positive (or negative) phases coincide with each other to amplify amplitude. The coldest event
occurred in the decade of 1965–1975 in eastern China, while the periods of 1920–1930, 1940–1950, and 1988–2000 appeared to
be warmer in most parts of China. For the precipitation series in northern China, the dry anomalous event was found in the
late 1920s, while the wet anomalous event occurred in the 1950s. A severe drought in 1927–1929 in northern China coincided
with the anomalous warm and dry decade, caused large-scale famine in nine provinces over northern China. Climatic anomalous
events with a warm-dry or cold-wet association in the physical climate system would potentially cause severe negative impacts
on natural ecosystem in the key vulnerable region over northern China. The spatial pattern of summer rainfall anomalies in
the eastern China monsoon region showed an opposite variations in phase between the Yellow River Valley (North China) and
the mid-low Yangtze River Valley as well as accompanied the shift of the northernmost monsoon boundary. Climatic regime shifts
for different time points in the last 200 years were identified. In North China, transitions from dry to wet periods occurred
around 1800, 1875, and 1940 while the transitions from wet to dry periods appeared around 1840, 1910, and the late 1970s.
The reversal transition in these time points can also be found in the lower Yangtze River. Climatic regime shifts in China
were linked to the interaction of mid- and low latitude atmospheric circulations (the westerly flow and the monsoon flow)
when they cross the Tibetan Plateau in East Asia. 相似文献
55.
Meng-Dawn Cheng 《Journal of Atmospheric Chemistry》2018,75(1):1-16
Although a large volume of monitoring and computer simulation data exist for global coverage of HF, study of HF in the troposphere is still limited to industry whose primary interest is the safety and risk assessment of HF release because it is a toxic gas. There is very limited information on atmospheric chemistry, emission sources, and the behavior of HF in the environment. We provide a comprehensive review on the atmospheric chemistry of HF, modeling the reactions and transport of HF in the atmosphere, the removal processes in the vertical layer immediately adjacent to the surface (up to approximately 500 m) and recommend research needed to improve our understanding of atmospheric chemistry of HF in the troposphere. The atmospheric chemistry, emissions, and surface boundary layer transport of hydrogen fluoride (HF) are summarized. Although HF is known to be chemically reactive and highly soluble, both factors affect transport and removal in the atmosphere, the chemistry can be ignored when the HF concentration is at a sufficiently low level (e.g., 10 ppmv). At a low concentration, the capability for HF to react in the atmosphere is diminished and therefore the species can be mathematically treated as inert during the transport. At a sufficiently high concentration of HF (e.g., kg/s release rate and thousands of ppm), however, HF can go through a series of rigorous chemical reactions including polymerization, depolymerization, and reaction with water to form molecular complex. As such, the HF species cannot be considered as inert because the reactions could intimately influence the plume’s thermodynamic properties affecting the changes in plume temperature and density. The atmospheric residence time of HF was found to be less than four (4) days, and deposition (i.e., atmosphere to surface transport) is the dominant mechanism that controls the removal of HF and its oligomers from the atmosphere. The literature data on HF dry deposition velocity was relatively high compared to many commonly found atmospheric species such as ozone, sulfur dioxide, nitrogen oxides, etc. The global average of wet deposition velocity of HF was found to be zero based on one literature source. Uptake of HF by rain drops is limited by the acidity of the rain drops, and atmospheric particulate matter contributes negligibly to HF uptake. Finally, given that the reactivity of HF at a high release rate and elevated mole concentration cannot be ignored, it is important to incorporate the reaction chemistry in the near-field dispersion close to the proximity of the release source, and to incorporate the deposition mechanism in the far-field dispersion away from the release source. In other words, a hybrid computational scheme may be needed to address transport and atmospheric chemistry of HF in a range of applications. The model uncertainty will be limited by the precision of boundary layer parameterization and ability to accurately model the atmospheric turbulence. 相似文献
56.
Thomas K. Flesch Lowry A. Harper Raymond L. Desjardins Zhiling Gao Brian P. Crenna 《Boundary-Layer Meteorology》2009,132(1):11-30
Inverse-dispersion calculations can be used to infer atmospheric emission rates through a combination of downwind gas concentrations
and dispersion model predictions. With multiple concentration sensors downwind of a compound source (whose component positions
are known) it is possible to calculate the component emissions. With this in mind, a field experiment was conducted to examine
the feasibility of such multi-source inferences, using four synthetic area sources and eight concentration sensors arranged
in different configurations. Multi-source problems tend to be mathematically ill-conditioned, as expressed by the condition
number κ. In our most successful configuration (average κ = 4.2) the total emissions from all sources were deduced to within 10% on average, while component emissions were deduced
to within 50%. In our least successful configuration (average κ = 91) the total emissions were calculated to within only 50%, and component calculations were highly inaccurate. Our study
indicates that the most accurate multi-source inferences will occur if each sensor is influenced by only a single source.
A “progressive” layout is the next best: one sensor is positioned to “see” only one source, the next sensor is placed to see
the first source and another, a third sensor is placed to see the previous two plus a third, and so on. When it is not possible
to isolate any sources κ is large and the accuracy of a multi-source inference is doubtful. 相似文献
57.
Mohd Rizaludin Mahmud Mazlan Hashim Mohd Nadzri Mohd Reba 《Asia-Pacific Journal of Atmospheric Sciences》2017,53(3):375-384
We investigated the potential of the new generation of satellite precipitation product from the Global Precipitation Mission (GPM) to characterize the rainfall in Malaysia. Most satellite precipitation products have limited ability to precisely characterize the high dynamic rainfall variation that occurred at both time and scale in this humid tropical region due to the coarse grid size to meet the physical condition of the smaller land size, sub-continent and islands. Prior to the status quo, an improved satellite precipitation was required to accurately measure the rainfall and its distribution. Subsequently, the newly released of GPM precipitation product at half-hourly and 0.1° resolution served an opportunity to anticipate the aforementioned conflict. Nevertheless, related evidence was not found and therefore, this study made an initiative to fill the gap. A total of 843 rain gauges over east (Borneo) and west Malaysia (Peninsular) were used to evaluate the rainfall the GPM rainfall data. The assessment covered all critical rainy seasons which associated with Asian Monsoon including northeast (Nov. - Feb.), southwest (May - Aug.) and their subsequent inter-monsoon period (Mar. - Apr. & Sep. - Oct.). The ability of GPM to provide quantitative rainfall estimates and qualitative spatial rainfall patterns were analysed. Our results showed that the GPM had good capacity to depict the spatial rainfall patterns in less heterogeneous rainfall patterns (Spearman’s correlation, 0.591 to 0.891) compared to the clustered one (r = 0.368 to 0.721). Rainfall intensity and spatial heterogeneity that is largely driven by seasonal monsoon has significant influence on GPM ability to resolve local rainfall patterns. In quantitative rainfall estimation, large errors can be primarily associated with the rainfall intensity increment. 77% of the error variation can be explained through rainfall intensity particularly the high intensity (> 35 mm d-1). A strong relationship between GPM rainfall and error was found from heavy (~35 mm d-1) to violent rain (160 mm d-1). The output of this study provides reference regarding the performance of GPM data for respective hydrology studies in this region. 相似文献
58.
Seasonal change in body length of important small copepods and relationship with environmental factors in Jiaozhou Bay,China 总被引:1,自引:0,他引:1
Differences among species in prosome length and in species’ response to environmental factors do exist. Therefore, it is useful to examine prosome length for different copepod species in variable environments. Seasonal variations in prosome length of four small copepods and their copepodite stages in the Jiaozhou Bay were compared and the relative influence of temperature, salinity, and chlorophyll concentration were examined. Two peaks were found in the mean prosome length of Paracalanus parvus (in early winter and May). For Acartia bifilosa, the maximum values of all copepodites occurred mainly from February to April, and decreased to the bottom in July. Prosome length of Acartia pacifica peaked when it first appeared in June, then reached to the minimum in July. Parvocalanus crassirostris only appeared from late summer to autumn and the mean prosome length showed no clear changes. Correlations of adult prosome length with environmental factors were evaluated. For the four species, temperature was negatively correlated to prosome length except for P. crassirostris. But the different species varied markedly in their responds to temperature. A. bifilosa showed a more definite trend of size variation with temperature than P. parvus and A. pacifica. Correlations of prosome length with salinity were significantly positive for almost all the small copepods. The relationship between chlorophyll concentration and prosome length was complicated for these copepods, but for P. parvus, chlorophyll concentration was also an important affecting factor. Furthermore, investigation needs to be done on food quality for some copepod. These results are essential to estimate the biomass and the production, and to understand these small copepods’ population dynamics in this human-affected bay. 相似文献
59.
Sulfotransferase (ST) is the first enzyme discovered in association with paralytic shellfish poisoning (PSP) toxin biosynthesis in toxic dinoflagellates. This study investigates the ST activity in crude enzyme extraction of a toxic dinoflagellate species, Alexandrium tamarense CI01. The results show that crude enzyme can transfer a sulfate group from 3’-phosphoadenosine 5’-phosphosulfate (PAPS) to N-21 in the carbamoyl group of gonyautoxin 2/3 (GTX2/3) to produce C1/C2, but is inactive toward STX to produce GTX5. The crude enzyme is optimally active at pH 6.0 and 15°C. The activity is enhanced by Co2 , Mg2 , Mn2 and Ca2 individually, but is inhibited by Cu2 . Moreover, the activity shows no difference when various sulfur compounds are used as sulfate donors. These results demonstrate that the ST specific to GTX2/3 is present in the cells of A. tamarense CI01 and is involved in PSP toxin biosynthesis. In addition, the ST from different dinoflagellates is species-specific, which explains well the various biosynthesis pathways of the PSP toxins in toxic dinoflagellates. 相似文献
60.