Hydrothermal gases offshore Milos Island, Greece

Hydrothermal fluids emerge from the seafloor of Paleohori Bay on Milos. The gases in these fluids contain mostly CO₂ but CH₄ concentrations up to 2% are present. The stable carbon isotopic composition of the CO₂ (near 0%) indicates an inorganic carbon source (dissociation of underlying marine carbonates). The carbon and hydrogen isotopes of most CH₄ samples are enriched in the heavy species (δ¹³C = −9.4 to −17.8‰; δD = −102 to −189‰) which is believed to be characteristic for an abiogenic production of CH₄ by CO₂-reduction (Fischer-Tropsch reactions). Depletions in the deuterium content of three CH₄ samples (to −377%) are probably caused by unknown subsurface rock alteration processes. Secondary hydrogen isotope exchange processes between methane, hydrogen and water are most likely responsible for calculated unrealistic methane formation temperatures.

We show that excess helium, slightly enriched in ³He, is present in the hydrothermal fluids emerging the seafloor of Paleohori Bay. When the isotopic ratio of the excess component is calculated a ³He/⁴He_excess of 3.6 · 10⁻⁶ is obtained: This indicates that the excess component consists of about one third of mantle helium and two thirds of radiogenic helium. We infer that the mantle-derived component has been strongly diluted by radiogenic helium during the ascent of the fluids to the surface.     

Pétrographie et Datations K-Ar des Transformations Minérales Affectant le Gîte Uranifère de Bertholène (Aveyron — France)

Résumé La minéralisation uranifère de Bertholène est encaissée dans un orthogneiss, à proximité de sa couverture permo-carbonifère. Les variations de faciès observées dans la zone du gisement trahissent d'importantes transformations minéralogiques des roches. L'étude pétrographique révèle deux stades majeurs: 1. Important phénomène d'albitisation oblitérant localement la texture et la minéralogie initiale de l'orthogneiss. 2. Phénomènes plus tardifs d'hydrolyse de l'albite et d'argilisation. La minéralisation uranifère est mise en place lors de ce dernier stade. Les datations K-Ar de fraction fines et de phases minérales séparées permettent de préciser l'âge des transformations: 1. Les phénomènes d'albitisation sont datés à 200–210 Ma. 2. L'âge des phénomènes d'argilisation et de la mise en place des minéralisation est fixé à 170–175 Ma. Ces deux âges, déjà connus en plusieurs autres points du Sud du Massif Central comme épisodes de métamorphisme, de diagenèse, ou de mise en place de minéralisations diverses apparaissent d'une grande importance régionale.

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The Bertholène uranium deposit is located within an orthogneiss not far away from its Permo-Carboniferous sedimentary cover. Variations in texture and coloration in the deposit and its vicinity result from a radical alteration of the country rock mineralogy. Two major stages of transformation are revealed by petrographic study: 1. An important albitization process, locally obliterating the orthogneiss initial texture and mineralogy — 2. A later stage of argillization and albite hydrolysis during which the uranium deposit was formed. K-Ar datings of fine fractions and hand-picked mineral phases enabled the following ages to be established: 1. The age of the albitization process is 200–210 M.Y. 2. The uranium deposit formation and the process of argillization are 170–175 M.Y. old. These two ages, already reported from several other locations in the South of the Massif Central, as epochs of metamorphism, diagenesis or ore bodies formation seem of great regional importance.

     

Single Particle Characterisation of the Aerosol in the Marine Boundary Layer and Free Troposphere over Tenerife, NE Atlantic, during ACE-2

In the framework of the 2nd Aerosol Characterization Experiment (ACE-2), in June and July 1997, size segregated samples were collected for single particle analysis on the island of Tenerife, in both the marine boundary layer (MBL) and the free troposphere (FT), to study the characteristics of the North Atlantic aerosol. A systematic assessment was made of the aerosol under background conditions and when the environment was perturbed by European emissions and/or Saharan dust. The aerosol particles were analysed by automated and manual SEM-EDX, followed by cluster analysis to identify the different particle types and their abundance. Basing on back trajectory calculations, particle numbers and volume concentrations, different periods can be identified regarding the origin of the sampled air masses. In the FT, the air masses were classified as clean Atlantic, Saharan dust from Africa or pollution from Europe. In the MBL, air masses were classified as clean, polluted or perturbed by emissions from Europe. For both the FT and MBL samples, the main changes in chemical composition were observed between the fine and coarse mode aerosol. The FT fine mode aerosol is dominated by S-poor aluminosilicates (62%) in the event of the dust samples or sulphates, carbonaceous particles (20%) and S-rich aluminosilicates (46%) in the polluted samples. For the larger fractions, a strong decreasing trend was observed for the sulphates (less than 20%) and carbonaceous particles (10%) in the polluted samples. The MBL fine mode was completely dominated by S-rich particles (polluted 55% and perturbed 59%), and to a lesser extent, carbonaceous and aged sea salt particles. In the coarse mode, the polluted air mass is dominated by sea salt particles (62%). Contrary to the fine fraction, the polluted air mass in the coarse fraction contained 5.3% of S-rich particles. The combined interpretation of the data from the analysis of size-fractioned particles and the calculated backward trajectories for air masses coming from Europe, Africa and the Atlantic, results in better insights on aerosol chemistry, especially for the comparison of the particle composition in the FT and the MBL.     

Impact of a Saturation-Dependent Dissipation Source Function on Operational Hindcasts of Wind-Waves in the Australian Region

The impact of a modified parametric form of the dissipation source function S ds on the skill of an operational spectral wind-wave model is investigated. Numerical experiments are made with a version of the WAM model presently used operationally by the Australian Bureau of Meteorology to produce sea-state forecasts within the Australian region. Performances of wave hindcasts obtained using several alternative forms of this newly proposed dissipation source function are compared to those produced with forms of S ds commonly used operationally. A new ad hoc technique to compare modelled and observed wave spectra is introduced to assess the quality of calculated one-dimensional frequency spectra.

Our results indicate that wave model performance in terms of integral spectral parameters, such as the significant wave height H s , may benefit from improved parameterisations of the dissipation source term S ds . On the other hand, we also found that model performance was relatively poor in terms of predictions of the one-dimensional frequency spectrum, regardless of the chosen form of S ds . These results suggest that further refinements of the dissipation source term are strongly dependent on improved parametrisations of the nonlinear interactions source term S nl .     

Groundwater Level Prediction/Forecasting and Assessment of Uncertainty Using SGS and ARIMA Models: A Case Study in the Bauru Aquifer System (Brazil)

Natural Resources Research - Best water management practices should involve the prediction of the availability of groundwater resources. To predict/forecast and consequently manage these water...     

The CM carbonaceous chondrite regolith Diepenveen

A carbonaceous chondrite was recovered immediately after the fall near the village of Diepenveen in the Netherlands on October 27, 1873, but came to light only in 2012. Analysis of sodium and poly‐aromatic hydrocarbon content suggests little contamination from handling. Diepenveen is a regolith breccia with an overall petrology consistent with a CM classification. Unlike most other CM chondrites, the bulk oxygen isotopes are extremely ¹⁶O rich, apparently dominated by the signature of anhydrous minerals, distributed on a steep slope pointing to the domain of intrinsic CM water. A small subset plots closer to the normal CM regime, on a parallel line 2 ‰ lower in δ¹⁷O. Different lithologies in Diepenveen experienced varying levels of aqueous alteration processing, being less aqueously altered at places rather than more heated. The presence of an agglutinate grain and the properties of methanol‐soluble organic compounds point to active impact processing of some of the clasts. Diepenveen belongs to a CM clan with ~5 Ma CRE age, longer than most other CM chondrites, and has a relatively young K‐Ar resetting age of ~1.5 Ga. As a CM chondrite, Diepenveen may be representative of samples soon to be returned from the surface of asteroid (162173) Ryugu by the Hayabusa2 spacecraft.     

Improved imaging of a karst aquifer using focused source electromagnetic and differentially normalized method: a qualitative analysis

Geophysical investigations using conventional techniques applied to groundwater exploration can often present strong limitations involving high financial costs, complex acquisition logistics and high ambiguity in results. Dispersion of the electric current flow, induced polarization) effects, cultural noises and shallow lateral heterogeneities represent the main problems faced by geoelectric methods in these types of surveys. Moreover, elements such as intrusions and mineralization at different depths may be responsible for signal attenuation as well as high resistivity in unsaturated zones and complex three-dimensional formations or clayey zones cause variations in the electric current. The focused source electromagnetic and differentially normalized method approaches can help to solve some these issues. Aiming at a higher signal-to-noise ratio, the focused source electromagnetic method and approaches of the differentially normalized method, first applied to petroleum exploration, are tested on a groundwater target, in a karst environment sectioned by a diabase dyke. We performed the processing and analysis on real IP resistivity profiling data acquired with two-way dipole-dipole array, guided by magnetic data acquired on the same profile, mapping a diabase dyke. The inversion of focused source electromagnetic method/differentially normalized method was not performed, instead that we converted the induced polarization–resistivity data to a differential signal to qualitatively prove the presence of aquifer. Joint interpretation of focused source electromagnetic method curves and inverted two-dimensional induced polarization–resistivity sections allowed for precise delineation of a conductive zone associated with the karst aquifer, le magnetics allowed for the definition of a neighbour dyke. The techniques have great potential in the aid of groundwater exploration, contributing substantially to the reduction of interpretation ambiguity. Focused source electromagnetic method/differentially normalized method/ approaches show that a simple linear combination of the conventional geoelectric data is able to remove the geological noise and provide the vertical focusing of the electric current.     

Wave observations from an array of directional buoys over the southern Brazilian coast

It is well known that the majority of buoy measurements are located around the US coast and along some Europeans countries. The lack of long-term and densely spaced in situ measurements in the Southern Hemisphere in general, and the South Atlantic in particular, hinders several investigations due to the lack of detailed metocean information. Here, we present an effort to overcome this limitation, with a dense network of buoys along the Brazilian coast, equipped with several meteorological and oceanographic sensors. Out of ten currently operational buoys, three are employed to present the main characteristics of waves in the Southern part of the network. For the first time, sensor characteristics and settings are described, as well as the methods applied to the raw wave data. Statistics and distributions of wave parameters, swell propagating events, comparison with a numerical model and altimeters and a discussion about the occurrence of freak waves are presented.     

Automated watershed subdivision for simulations using multi-objective optimization

A qualitative trial-and-error approach is commonly used to define watershed subdivisions through varying a single topographic threshold value. A methodology has been developed to quantitatively determine spatially variable threshold values using topography and a user-defined landscape reference layer. Optimization and topographic parameterization algorithms were integrated to create solutions that minimize the number of sub-watersheds and maximize the agreement between the discretized watershed and the reference layer. The system was evaluated using different reference datasets such as soil type, land management, and landscape form. Comparison of simulated results indicated that the scenario using land management as the reference layer yielded results closer to the scenario subdivided using a constant topographic threshold but with approximately 10 times more sub-catchments and therefore indicating customization of the watershed subdivision to the user-defined reference layer. The proposed optimization technology could be used in adequately applying watershed modeling technology in developing conservation practice implementation plans.     

Impact of climate and hydrology on juvenile fish recruitment towards estuarine nursery grounds in the context of climate change

Larvae of various coastal fish undergo immigration from spawning grounds towards estuarine nurseries. Several environmental factors can have an important impact on survival at this stage making it crucial for recruitment. Generalized linear models were applied in order to investigate the relation between river drainage, sea surface temperature (SST), NAO index and the North-South wind component intensity, over the two months prior to the estuarine colonization peak, and the densities of Platichthys flesus, Dicentrarchus labrax, Diplodus vulgaris and Diplodus bellottii in the nursery grounds based on a discontinuous historical dataset (from 1978 to 2006), for the Tagus estuary. The relation between SST over the 12 months prior to the estuarine colonization peak and fish densities in the nurseries was also investigated, as it integrates the periods of spawning stock maturation, spawning and larval immigration. While SST over the prior 12 months was negatively correlated with the abundance of P. flesus, it was positively correlated with the abundance of D. bellottii. Abundance of D. vulgaris was positively correlated with SST in the two months prior to the estuarine colonization peak, while the abundance of D. labrax was positively correlated with river drainage. The relations between SST and the abundance of P. flesus, a cold-water species with declining densities, and the subtropical species D. bellottii and D. vulgaris, which are increasing in abundance, are indicative of species abundance alterations related to climate warming. Dicentrarchus labrax will probably also be affected by climate change because of lowered precipitation and consequently river drainage.