Micro-scale S isotope studies of the Kharaelakh intrusion, Noril’sk region, Siberia: Constraints on the genesis of coexisting anhydrite and sulfide minerals

The coexistence of magmatic anhydrite and sulfide minerals in non-arc-related mafic magmas has only rarely been documented. Likewise the S isotope fractionation between sulfate and sulfide in mafic rocks has infrequently been measured. In the Kharaelakh intrusion associated with the world-famous Noril’sk ore district in Siberia coexisting magmatic anhydrite and sulfide minerals have been identified. Sulfur isotope compositions of the anhydrite-sulfide assemblages have been measured via both ion microprobe and conventional analyses to help elucidate the origin of the anhydrite-sulfide pairs. Magmatic anhydrite and chalcopyrite are characterized by δ³⁴S values between 18.8‰ and 22.8‰, and 9.3‰ and 13.2‰, respectfully. Coexisting anhydrite and chalcopyrite show Δ values that fall between 8.5‰ and 11.9‰. Anhydrite in the Kharaelakh intrusion is most readily explained by the assimilation of sulfate from country rocks; partial reduction to sulfide led to mixing between sulfate-derived sulfide and sulfide of mantle origin. The variable anhydrite and sulfide δ³⁴S values are a function of differing degrees of sulfate reduction, variable mixing of sulfate-derived and mantle sulfide, incomplete isotopic homogenization of the magma, and a lack of uniform attainment of isotopic equilibrium during subsolidus cooling. The δ³⁴S values of sulfide minerals have changed much less with cooling than have anhydrite values due in large part to the high sulfide/sulfate ratio. Variations in both sulfide and anhydrite δ³⁴S values indicate that isotopically distinct domains existed on a centimeter scale. Late stage hydrothermal anhydrite and pyrite also occur associated with Ca-rich hydrous alteration assemblages (e.g., thomsonite, prehnite, pectolite, epidote, xonotlite). δ³⁴S values of secondary hydrothermal anhydrite and pyrite determined by conventional analyses are in the same range as those of the magmatic minerals. Anhydrite-pyrite Δ values are in the 9.1-10.1‰ range, and are smaller than anticipated for the low temperatures indicated by the silicate alteration assemblages. The small Δ values are suggestive of either sulfate-sulfide isotopic disequilibrium or closure of the system to further exchange between ∼550 and 600 °C. Our results confirm the importance of the assimilation of externally derived sulfur in the generation of the elevated δ³⁴S values in the Kharaelakh intrusion, but highlight the sulfur isotopic variability that may occur in magmatic systems. In addition, our results confirm the need for more precise experimental determination of sulfate-sulfide sulfur isotope fractionation factors in high-T systems.     

Albitisation related to the Triassic unconformity in igneous rocks of the Morvan Massif (France)

The Carboniferous Morvan Massif, in the northern part of the French Massif Central, consists of granite and some rhyolite. A Triassic erosional unconformity has developed on the massif which is covered by Mesozoic sediments of the Paris Basin. The igneous rocks of the Morvan Massif show a strong alteration with pseudomorphic replacement of the primary plagioclases into albite, pseudomorphic replacement of primary biotite into chlorite and minor precipitation of neogenic minerals like albite, chlorite, apatite, haematite, calcite and titanite. The geometry and arrangement of these alterations give significant constraints about their development. Some of the altered facies develop in a pervasive manner; others are restricted to centimetric to metric-wide joints that imply fluid-flow phenomena. Moreover, the alteration facies are arranged in a clear succession with strongly altered facies at the top and weakly altered facies towards the depth, which point to a genetic relationship with the Triassic unconformity. Regional distribution of the alterations, which affect the Carboniferous igneous and volcanic formations beneath the Jurassic sedimentary cover, also leads to associate these alterations with the Triassic unconformity. Dating of the alterations provides even a further constraint, alterations are of Triassic age, that means the same age as the unconformity. Taking into account all these geological constraints, it is proposed that albitisation of the Morvan Massif was developed under low temperature subsurface conditions in relation to the Triassic palaeosurface.     

Hydrothermal gases offshore Milos Island, Greece

Hydrothermal fluids emerge from the seafloor of Paleohori Bay on Milos. The gases in these fluids contain mostly CO₂ but CH₄ concentrations up to 2% are present. The stable carbon isotopic composition of the CO₂ (near 0%) indicates an inorganic carbon source (dissociation of underlying marine carbonates). The carbon and hydrogen isotopes of most CH₄ samples are enriched in the heavy species (δ¹³C = −9.4 to −17.8‰; δD = −102 to −189‰) which is believed to be characteristic for an abiogenic production of CH₄ by CO₂-reduction (Fischer-Tropsch reactions). Depletions in the deuterium content of three CH₄ samples (to −377%) are probably caused by unknown subsurface rock alteration processes. Secondary hydrogen isotope exchange processes between methane, hydrogen and water are most likely responsible for calculated unrealistic methane formation temperatures.

We show that excess helium, slightly enriched in ³He, is present in the hydrothermal fluids emerging the seafloor of Paleohori Bay. When the isotopic ratio of the excess component is calculated a ³He/⁴He_excess of 3.6 · 10⁻⁶ is obtained: This indicates that the excess component consists of about one third of mantle helium and two thirds of radiogenic helium. We infer that the mantle-derived component has been strongly diluted by radiogenic helium during the ascent of the fluids to the surface.     

Resolution of GPR bowtie antennas: An experimental approach

Since target reflections directly depend on the emitted pulse characteristics, a key factor for carrying out a successful GPR survey is to know as much as possible about the transmission features of the antennas used. This information is very important in order to choose the right antennas and set the appropriate configuration parameters for a specific survey. With this in mind this paper deals with the development of a set of laboratory experiments on the resolution capabilities of three bowtie antennas at frequencies of 500, 800 and 1000 MHz. Results from these measurements give a first estimation of the resolution of the antennas under test, showing the advantage of performing experiments rather than relying only on theoretical assumptions. The results are also expressed in terms of the central wavelength for each antenna and compared with some theoretical estimations proposed in the specialized bibliography.     

Volcanic-sedimentary features in the Serra Geral Fm., Paraná Basin,southern Brazil: Examples of dynamic lava-sediment interactions in an arid setting

The formation of volcanic–sedimentary interaction features in extreme arid environments is not a commonly described process. Specifically the occurrence of dynamically mixed sediments and juvenile igneous clasts as peperites, for water has been considered one major important factor in the processes of magma dismantling and mingling with unconsolidated sediment to form such deposits. The study area, located in south Brazil, shows a sequence of lava flows and intertrapic sandstone layers from the Paraná Basin, associated with the formation of clastic dykes, flow striations, peperite and ‘peperite-like’ breccias. Four processes are suggested for the genesis of the peperites: (a) fragmentation of the flow front and base; (b) sand injection; (c) dune collapse; (d) magma cascade downhill. The continued flow of a lava, while its outer crust is already cooling, causes it to break, especially in the front and base, fragments falling in the sand and getting mixed with it, generating the flow front ‘peperite-like’ breccia. The weight of the lava flow associated to shear stress at the base cause sand to be injected inwards the flow, forming injection clastic dykes in the cooled parts and injection peperite in the more plastic portions. The lava flow may partially erode the dune, causing the dune to collapse and forming the collapse ‘peperite-like’ breccia. The shear stress at the base of a flowing lava striates the unconsolidated sand, forming the flow striations. The sand that migrates over a cooled, jointed lava flow may get caught in the cavities and joints, forming the filling clastic dykes. These deposits are analogous to those found in the Etendeka, NW Namibia, and show that sediment–lava interactions in arid settings are widespread throughout the Paraná-Etendeka province during the onset of flood volcanism.     

Pétrographie et Datations K-Ar des Transformations Minérales Affectant le Gîte Uranifère de Bertholène (Aveyron — France)

Résumé La minéralisation uranifère de Bertholène est encaissée dans un orthogneiss, à proximité de sa couverture permo-carbonifère. Les variations de faciès observées dans la zone du gisement trahissent d'importantes transformations minéralogiques des roches. L'étude pétrographique révèle deux stades majeurs: 1. Important phénomène d'albitisation oblitérant localement la texture et la minéralogie initiale de l'orthogneiss. 2. Phénomènes plus tardifs d'hydrolyse de l'albite et d'argilisation. La minéralisation uranifère est mise en place lors de ce dernier stade. Les datations K-Ar de fraction fines et de phases minérales séparées permettent de préciser l'âge des transformations: 1. Les phénomènes d'albitisation sont datés à 200–210 Ma. 2. L'âge des phénomènes d'argilisation et de la mise en place des minéralisation est fixé à 170–175 Ma. Ces deux âges, déjà connus en plusieurs autres points du Sud du Massif Central comme épisodes de métamorphisme, de diagenèse, ou de mise en place de minéralisations diverses apparaissent d'une grande importance régionale.

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The Bertholène uranium deposit is located within an orthogneiss not far away from its Permo-Carboniferous sedimentary cover. Variations in texture and coloration in the deposit and its vicinity result from a radical alteration of the country rock mineralogy. Two major stages of transformation are revealed by petrographic study: 1. An important albitization process, locally obliterating the orthogneiss initial texture and mineralogy — 2. A later stage of argillization and albite hydrolysis during which the uranium deposit was formed. K-Ar datings of fine fractions and hand-picked mineral phases enabled the following ages to be established: 1. The age of the albitization process is 200–210 M.Y. 2. The uranium deposit formation and the process of argillization are 170–175 M.Y. old. These two ages, already reported from several other locations in the South of the Massif Central, as epochs of metamorphism, diagenesis or ore bodies formation seem of great regional importance.

     

Single Particle Characterisation of the Aerosol in the Marine Boundary Layer and Free Troposphere over Tenerife, NE Atlantic, during ACE-2

In the framework of the 2nd Aerosol Characterization Experiment (ACE-2), in June and July 1997, size segregated samples were collected for single particle analysis on the island of Tenerife, in both the marine boundary layer (MBL) and the free troposphere (FT), to study the characteristics of the North Atlantic aerosol. A systematic assessment was made of the aerosol under background conditions and when the environment was perturbed by European emissions and/or Saharan dust. The aerosol particles were analysed by automated and manual SEM-EDX, followed by cluster analysis to identify the different particle types and their abundance. Basing on back trajectory calculations, particle numbers and volume concentrations, different periods can be identified regarding the origin of the sampled air masses. In the FT, the air masses were classified as clean Atlantic, Saharan dust from Africa or pollution from Europe. In the MBL, air masses were classified as clean, polluted or perturbed by emissions from Europe. For both the FT and MBL samples, the main changes in chemical composition were observed between the fine and coarse mode aerosol. The FT fine mode aerosol is dominated by S-poor aluminosilicates (62%) in the event of the dust samples or sulphates, carbonaceous particles (20%) and S-rich aluminosilicates (46%) in the polluted samples. For the larger fractions, a strong decreasing trend was observed for the sulphates (less than 20%) and carbonaceous particles (10%) in the polluted samples. The MBL fine mode was completely dominated by S-rich particles (polluted 55% and perturbed 59%), and to a lesser extent, carbonaceous and aged sea salt particles. In the coarse mode, the polluted air mass is dominated by sea salt particles (62%). Contrary to the fine fraction, the polluted air mass in the coarse fraction contained 5.3% of S-rich particles. The combined interpretation of the data from the analysis of size-fractioned particles and the calculated backward trajectories for air masses coming from Europe, Africa and the Atlantic, results in better insights on aerosol chemistry, especially for the comparison of the particle composition in the FT and the MBL.     

Impact of a Saturation-Dependent Dissipation Source Function on Operational Hindcasts of Wind-Waves in the Australian Region

The impact of a modified parametric form of the dissipation source function S ds on the skill of an operational spectral wind-wave model is investigated. Numerical experiments are made with a version of the WAM model presently used operationally by the Australian Bureau of Meteorology to produce sea-state forecasts within the Australian region. Performances of wave hindcasts obtained using several alternative forms of this newly proposed dissipation source function are compared to those produced with forms of S ds commonly used operationally. A new ad hoc technique to compare modelled and observed wave spectra is introduced to assess the quality of calculated one-dimensional frequency spectra.

Our results indicate that wave model performance in terms of integral spectral parameters, such as the significant wave height H s , may benefit from improved parameterisations of the dissipation source term S ds . On the other hand, we also found that model performance was relatively poor in terms of predictions of the one-dimensional frequency spectrum, regardless of the chosen form of S ds . These results suggest that further refinements of the dissipation source term are strongly dependent on improved parametrisations of the nonlinear interactions source term S nl .     

Geological model for Boulder 1 at Station 2, South Massif,Valley of Taurus-Littrow

It appears possible to establish a preliminary geological model for the origin and evolution of the breccias of Boulder 1 at Station 2 in the Valley of Taurus-Littrow based on firm and probable geological constraints. The crystallization of plagioclase and other ANT-suite phases now present as clasts appears to have occurred in the lunar crust about 4.5 b.y. ago during the ‘melted shell stage’ of lunar history as that history is presently modeled. The original rocks containing these phases, which now make up the gray competent breccias of Boulder 1, were greatly modified by impact processes during the ‘cratered highland stage’ and the early part of the ‘large basin stage’, up to about 4.0 b.y. ago. About 4.0 b.y. ago, pigeonite basalts with KREEP affinities appear to have been intruded into the pre-Serenitatis crust from which the light friable breccias of Boulder 1 were later derived. During the large basin stage, three major dynamic events profoundly influenced the present character of the Boulder 1 materials. These events probably occurred as follows: (1) formation of gray competent breccia containing ANT-suite clasts in the hot ejecta blanket of an old large basin event, such as Tranquillitatis, that took place about 4.0 b.y. ago; (2) rebrecciation and redeposition of the gray competent breccia, mixed with light friable breccia and pigeonite basalt, in a relatively cool ejecta deposit, possibly produced by the northern Serenitatis event; (3) uplift and exposure of the Boulder 1 materials in the South Massif by the southern Serenitatis event about 3.90 b.y. ago.     

Albedo control of seasonal South Polar cap recession on Mars

Over the last few decades, General Circulation Models (GCM) have been used to simulate the current martian climate. The calibration of these GCMs with the current seasonal cycle is a crucial step in understanding the climate history of Mars. One of the main climatic signals currently used to validate GCMs is the annual atmospheric pressure cycle. It is difficult to use changes in seasonal deposits on the surface of Mars to calibrate the GCMs given the spectral ambiguities between CO₂ and H₂O ice in the visible range. With the OMEGA imaging spectrometer covering the near infra-red range, it is now possible to monitor both types of ice at a spatial resolution of about 1 km. At global scale, we determine the change with time of the Seasonal South Polar Cap (SSPC) crocus line, defining the edge of CO₂ deposits. This crocus line is not symmetric around the geographic South Pole. At local scale, we introduce the snowdrop distance, describing the local structure of the SSPC edge. Crocus line and snowdrop distance changes can now be used to calibrate GCMs. The albedo of the seasonal deposits is usually assumed to be a uniform and constant parameter of the GCMs. In this study, albedo is found to be the main parameter controlling the SSPC recession at both global and local scale. Using a defrost mass balance model (referred to as D-frost) that incorporates the effect of shadowing induced by topography, we show that the global SSPC asymmetry in the crocus line is controlled by albedo variations. At local scale, we show that the snowdrop distance is correlated with the albedo variability. Further GCM improvements should take into account these two results. We propose several possibilities for the origin of the asymmetric albedo control. The next step will be to identify and model the physical processes that create the albedo differences.