Minor element and Ca isotope composition of calcareous dinoflagellate cysts of cultured Thoracosphaera heimii

We investigated the influences of temperature, salinity and pH on the calcium isotope as well as trace and minor element (uranium, strontium, magnesium) to Ca ratios on calcium carbonate cysts of the calcareous dinoflagellate species Thoracosphaera heimii grown in laboratory cultures. The natural habitat of this species is the photic zone (preferentially at the chlorophyll maximum depth) of temperate to tropical oceans, and it is abundant in deep-sea sediments over the entire Cenozoic. In our experiments, temperatures ranged from 12 to 30 °C, salinity from 36.5 to 38.8 and pH from 7.9 to 8.4. The δ^44/40Ca of T. heimii cysts resembles that of other marine calcifiers, including coccolithophores, foraminifers and corals. However, its temperature sensitivity is considerably smaller and statistically insignificant, and T. heimii might serve as a recorder of changes in seawater δ^44/40Ca over geologic time. The Sr/Ca ratios of T. heimii cysts show a pronounced temperature sensitivity (0.016 mmol/mol °C^? 1) and have the potential to serve as a palaeo-sea surface temperature proxy. No clear temperature- and pH-dependences were observed for Mg/Ca. U/Ca seems to be influenced by temperature and pH, but the correlations change sign at 23 °C and pH 8.2, respectively.     

Formation of mesosiderites by fragmentation and reaccretion of a large differentiated asteroid

Abstract— We propose that mesosiderites formed when a 200–400 km diameter asteroid with a molten core was disrupted by a 50–150 km diameter projectile. To test whether impacts can excavate core iron and mix it with crustal material, we used a low‐resolution, smoothed‐particle hydrodynamics computer simulation. For 50–300 km diameter differentiated targets, we found that significant proportions of scrambled core material (and hence potential mesosiderite metal material) could be generated. For near‐catastrophic impacts that reduce the target to 80% of its original diameter and about half of its original mass, the proportion of scrambled core material would be about 5 vol%, equivalent to ～10 vol% of mesosiderite‐like material. The paucity of olivine in mesosiderites and the lack of metal‐poor or troilite‐rich meteorites from the mesosiderite body probably reflect biased sampling. Mesosiderites may be olivine‐poor because mantle material was preferentially excluded from the metal‐rich regions of the reaccreted body. Molten metal globules probably crystallized around small, cool fragments of crust hindering migration of metal to the core. If mantle fragments were much hotter and larger than crustal fragments, little metal would have crystallized around the mantle fragments allowing olivine and molten metal to separate gravitationally. The rapid cooling rates of mesosiderites above 850 °C can be attributed to local thermal equilibration between hot and cold ejecta. Very slow cooling below 400 °C probably reflects the large size of the body and the excellent thermal insulation provided by the reaccreted debris. We infer that our model is more plausible than an earlier model that invoked an impact at ～1 km/s to mix projectile metal with target silicates. If large impacts cannot effectively strip mantles from asteroidal cores, as we infer, we should expect few large eroded asteroids to have surfaces composed purely of mantle or core material. This may help to explain why relatively few olivine‐rich (A‐type) and metal‐rich asteroids (M‐type) are known. Some S‐type asteroids may be scrambled differentiated bodies.     

Isotopic composition of lead in moss and soil of the European Arctic

Moss, O and C horizons of podzols, mainly forming complementary sample triplets, as well as filter residues of molten snow from northern Norway, northern Finland and NW Russia have been analyzed by TIMS for their Pb isotopic composition in order to study the impacts of local geogenic/anthropogenic sources and long range atmospheric transport on the Pb balance in the European Arctic. Samples were taken along two N-S transects covering an area of ∼188.000 km², including both pristine environments in the W and certain regions towards the E severely contaminated by heavy metal emissions originating from large nickel smelters and processing plants in NW Russia.The lead in moss and O horizon samples clearly reflects atmospheric deposition, as it displays overall uniform isotope ratios and is decoupled from the geogenic background, i.e. the underlying mineral soils in the C horizon. Moss and O horizon samples from the eastern N-S transect are isotopically indistinguishable from those taken along the western transect but their Pb concentrations tend to be ∼2 times higher. This points to considerable contamination originating from the nearby Russian industrial and urban centers. However, isotopic signals of emissions from individual industrial point sources cannot be unambiguously identified because they lack characteristic isotope signatures. Pb derived from gasoline additives is swamped by Pb from other sources and can also be excluded as a major contributor to the environmental Pb in the European Arctic.Overall, the Pb isotopic signatures of moss and O horizon overlap values recorded in atmospheric lead all over central and southern Europe, more than 2000 km south of the study area. This may be taken as indicating continent-wide mixing of Pb derived from similar sources in the atmosphere or as reflecting economic globalization, or both. O horizon samples, which accumulate lead over 20-30 yr, conform to a distinct Pb isotope reference line in ²⁰⁷Pb/²⁰⁶Pb vs. ²⁰⁸Pb/²⁰⁶Pb space (“European Standard Pollution,” ESP) defined by atmospheric Pb considered to be representative for the technical civilization in Europe. Conversely, the Arctic moss samples with a lifetime of <3 yr display a deviating linear trend reflecting a recent change of atmospheric input towards significantly more radiogenic Pb derived from Mississippi Valley-type ores in the U.S., fully compatible with signatures found in epiphytic lichens from Canada, but also in Pb from urban waste incinerators in central Europe. Considering the elevated Pb concentrations in moss collected along the eastern N-S transect, this congruence indicates that the Pb in moss of the European Arctic most probably originates from the nearby Russian centers of urbanization and not from transatlantic transport. We therefore suspect imported industrial goods and their subsequent attrition to be a more plausible explanation for the appearance of MVT lead in Europe.     

Surface ocean temperatures in the north-east Atlantic during the last 500 000 years: evidence from foraminiferal census data

Abstract Changes in North Atlantic sea surface temperature (SST) are regarded as a key element of the climate during the Quaternary. However, there are relatively few long-term records providing quantitative SST estimates from this region. Using planktic foraminiferal-derived SSTs together with changes on species level and iceberg-rafted debris, the last 500 ka were studied. Pronounced SST changes, as determined from the last glacial–interglacial cycle, characterize most colder periods. Peak interglacial temperatures were found for marine isotope stages (MIS) 1, 5e and 11, the latter two being the warmest. The warm substages within MIS 7 and 9 are marked by enhanced dissimilarity coefficients, indicating that SSTs obtained for these times appear to be overestimated. This is corroborated by differences within the species assemblage, which show enhanced cold water components. It is therefore concluded that detailed analysis down to species level is a crucial prerequisite to better reconstructions of SST.     

The stability of fission tracks in epidote and vesuvianite

The stability of fission tracks in epidote and vesuvianite (idiocrase) was studied at different temperatures for several periods of time. The tracks in epidote are almost as heat-resistant as those in garnet; in vesuvianite they are much less stable. These results are in line with the rule that tracks in minerals with high lattice energies need higher activation energies to fade than in minerals with low lattice energies.     

Maribo—A new CM fall from Denmark

Abstract– Maribo is a new Danish CM chondrite, which fell on January 17, 2009, at 19:08:28 CET. The fall was observed by many eye witnesses and recorded by a surveillance camera, an all sky camera, a few seismic stations, and by meteor radar observatories in Germany. A single fragment of Maribo with a dry weight of 25.8 g was found on March 4, 2009. The coarse‐grained components in Maribo include chondrules, fine‐grained olivine aggregates, large isolated lithic clasts, metals, and mineral fragments (often olivine), and rare Ca,Al‐rich inclusions. The components are typically rimmed by fine‐grained dust mantles. The matrix includes abundant dust rimmed fragments of tochilinite with a layered, fishbone‐like texture, tochilinite–cronstedtite intergrowths, sulfides, metals, and carbonates often intergrown with tochilinite. The oxygen isotopic composition: (δ¹⁷O = ?1.27‰; δ¹⁸O = 4.96‰; Δ¹⁷O = ?3.85‰) plots at the edge of the CM field, close to the CCAM line. The very low Δ¹⁷O and the presence of unaltered components suggest that Maribo is among the least altered CM chondrites. The bulk chemistry of Maribo is typical of CM chondrites. Trapped noble gases are similar in abundance and isotopic composition to other CM chondrites, stepwise heating data indicating the presence of gas components hosted by presolar diamond and silicon carbide. The organics in Maribo include components also seen in Murchison as well as nitrogen‐rich components unique to Maribo.