水体溶解态黑碳的分子标志物苯多羧酸的气相色谱-质谱分析

苯多羧酸分子标志物法是定量水体中溶解态黑碳的常用方法,然而由于部分苯多羧酸,尤其是硝基苯多羧酸商业化标准品的缺失,采用该方法定量溶解态黑碳仍需进一步完善和优化。本文通过已有的苯多羧酸商业化标准品,建立了气相色谱-质谱联用仪(GC-MS)分离和定量 9 种缺少商业化标准品苯多羧酸的分析方法。并首次将菲-D10 作为溶解态黑碳的替代物,指示苯多羧酸法定量溶解态黑碳过程中的损失率。结果表明,该方法具有良好的重现性(RSD=10.34%),方法检出限为 0.67~5.38 ng/L。本文采用该方法分析了大亚湾表层水体溶解态黑碳的分布特征,其浓度范围为 30.38~46.19 μg/L,平均值为(38.93±6.17)μg/L,空间分布表现为从湾内到外海递减的趋势。     

中国东北深源地震机理

深源地震机理的研究有助于深入了解板块构造的驱动机制和动力学特征。对中国唯一的深震区--东北深震区的深震分布特征和震源机制解进行了综述和初步研究,初步探索了地震的发震机理、动力源以及地震的空间分布与西北太平洋俯冲板块的关系。分析结果显示：（1）震源深度在SEE NWW方向上有依次加深的趋势,而在SSW NNE方向上却没有明显变化,震源机制解的应力状态以下倾的压缩应力为主,说明中国东北深震的发生与西北太平洋板块向欧亚大陆的俯冲直接相关;（2）从日本海沟到我国东北,震源深度依次加深且几乎是从日本海沟沿直线倾斜下来,说明我国东北深震是日本海深震序列的一部分,同属于环太平洋地震带;（3）通过与东北深震区地球物理资料的对比,发现该区亚稳态橄榄石楔（Metastable Olivine Wedge,MOW）与深源地震的发生存在很好的相关性,由此推断东北深震的发生很可能是由橄榄石的相变引起的。     

Precipitation variability and its relationship to hydrologic variability in Alberta

By applying wavelet‐based empirical orthogonal function (WEOF) analysis to gridded precipitation (P) and empirical orthogonal function (EOF) analysis to gridded air temperature (T), potential evapotranspiration (PET), net precipitation (P‐PET) and runoff (Q), this paper examines the spatial, temporal and frequency patterns of Alberta's climate variability. It was found that only WEOF‐based precipitation patterns, possibly modulated by El Nino Southern Oscillation (ENSO) and Pacific Decadal Oscillation(PDO), delineated Alberta into four major regions which geographically represent northern Alberta Boreal forests, southern Alberta grasslands and Aspen Parklands and the Rocky Mountains and Foothills. The leading mode of wavelet‐based precipitation variability WPC1 showed that between 1900 and 2000, a wet climate dominated northern Alberta with significant 4–8, 11 and 25‐year periodic cycles, while the second mode WPC2 showed that between 1960 and 2000, southern Alberta grasslands were characterized by decreasing precipitation, dominated by 11‐year cycles, and the last two modes WPC3 and WPC4 were characterized by 4–7 and 25‐year cycles and both delineated regions where moisture from the Pacific Ocean penetrated the Rocky Mountains, accounted for much of the sub‐alpine climate. These results show that WEOF is superior to EOF in delineating Alberta precipitation variability to sub‐regions that more closely agree with its eco‐climate regions. Further, it was found that while WPC2 could not explain runoff variations in southern Alberta, WPC1, WPC3 and WPC4 accounted for runoff variability in their respective sub‐regions. Copyright © 2009 John Wiley & Sons, Ltd.     

Crustal Deformation Background Simulation of the Kekexili M_S8.1 Earthquake Happening in 2001

Using the GPS velocity data from 27 stations around the Eastern Kunlun fault as constraints,we first invert the slip velocities of the Eastern Kunlun fault,the north boundary fault of the Qaidam basin,the Mani-Yushu fault and the Margai Caka fault before the Kekexili MS8.1 earthquake with a 3-D elastic half-space dislocation model. The deformation field calculated from the slip movement of these faults can be considered the deformation background field of the earthquake. Based on the deformation background field with tectonic implications,we have obtained the strain field and earthquake moment accumulation field. The results show that there are two obvious high moment accumulation rate regions,one of which is the Dongdatan-Xidatan segment of the Eastern Kunlun fault where the M_S8.1 earthquake occurred in 2001.     

The spatial and temporal distribution of heavy metals in sediments of Victoria Harbour, Hong Kong

Victoria Harbour has received substantial loadings of pollutants from industrial and municipal wastewater discharged since the 1950s. Inputs of contaminants have declined dramatically during the last two decades as a result of better controls at the source and improved wastewater treatment facilities. To assess the spatial and temporal changes of metal contaminants in sediments in Victoria Harbour, core and grab sediments were collected. The central harbour areas were generally contaminated with heavy metals. The spatial distribution of trace metals can probably be attributed to the proximity of major urban and industrial discharge points, and to the effect of tidal flushing in the harbour. In the sediment cores, the highest concentrations of trace metals were observed to have accumulated during the 1950s-1980s, corresponding with the period of rapid urban and industrial development in Hong Kong. From the late 1980s, there has been a major decline in the concentrations of trace metals, due to a reduction in industrial activities and to the enactment of wastewater pollution controls in the territory. The Pb isotopic compositions of the sediments revealed the anthropogenic inputs of Pb to the harbour. The (206)Pb/(207)Pb ratios varied from 1.154 to 1.190, which were lower than those of background geological materials in Hong Kong ((206)Pb/(207)Pb: 1.201-1.279). The data also indicated that the Pb in the harbour sediments most likely originated from mixed sources, including the leaded gasoline used in the past and other anthropogenic sources.     

矿物药物质基础研究现状及展望

在深入研究近年来矿物药方面的文献报道基础上,介绍了矿物药微量元素的研究、检测方法的研究、毒理和药理等方面的研究现状。针对矿物药名实、配伍研究中存在的不足,提出矿物药名实鉴定,复方制剂中元素含量以及矿物药配伍等方面的研究方向,阐述了矿物药研究的广阔前景。     

青藏高原东北缘4个强震重点监视区库仑破裂应力的近百年变化和危险性分析

针对青藏高原东北缘地区前人基于多学科研究资料圈定的4个未来强震重点监视区,构建了顾及到中下地壳黏弹性弛豫效应的区域岩石圈模型;考虑1920-2010年期间发生在本区域及其周边的18次Ｍ_s≥７级强震在这一区域的黏弹性静态库仑破裂应力变化,和长期构造背景加载下的应力积累情况,定量分析了每个重点监视区近百年来的库仑破裂应力变化,并在此基础上初步分析了各重点监视区的未来发震危险性程度。结果表明：西秦岭断裂带监视区和六盘山断裂带监视区均处于长期构造背景场和历史地震影响共同加载应力的状况;而海原断裂带监视区和东昆仑断裂带监视区,如果不考虑长期构造背景的应力加载,则处于地震影响的卸载状况。考虑到这4个重点监视区的大震平均复发周期及上次大震事件的离逝时间,认为西秦岭断裂带监视区的未来强震危险性程度最高,海原断裂带次之,然后是东昆仑断裂带和六盘山断裂带。     

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Investigation of dynamic processes in the period of formation and development of the blocking anticyclone over European Russia in summer 2010

The blocking anticyclone (BA) observed in the summer of 2010 over the European part of Russia led to enormous economical damage, substantially increased the mortality of the population, and had serious negative consequences for human health. Dynamic processes in the troposphere, i.e., wave trains, which could contribute to anticyclone formation and sustenance, are investigated. In order to study these wave trains, three-dimensional Plumb vectors have been calculated and analyzed. It is shown that, in June 2010, three wave trains propagated eastward in the troposphere over the Atlantics. The first two wave trains, having reached Europe, continued to propagate in eastern and southeastern directions. Only the third wave train, upon reaching Europe, continued to propagate toward the northeast and, on June 17–19, entered northwestern Russia. The anticyclone, which started to form on June 18 precisely in this region, subsequently developed into a stable BA observed over European Russia up to mid-August. The propagation direction of the wave trains could change due to the formation of a double structure of the zonal flow in the troposphere. The wave trains are revealed in the middle of June in regions with increased cloudiness over the northwestern part of the Atlantic Ocean and over the northwestern and northern parts of the central United States. Eastwardpropagating wave trains, which could contribute to the intensification of the corresponding BAs that brought anomalously high temperatures to European Russia, were also revealed in July and August of 2010 and 1972. The calculated 10-day backward trajectories are analyzed to determine the character of motions of air particles that penetrated into the anticyclone over the region of Moscow during the 2010 summer in the period of its development.     

Observational Studies of the X-Ray Quasi-Periodic Oscillations of a Solar Flare

We study an M2.6 flare observed with RHESSI on 22 August 2005. The light curves of the hard X-rays (counts and photon fluxes), the derived number fluxes, as well as the energy fluxes of energetic electrons all presented a damped quasi-periodic oscillation. The modulation depth of the hard X-rays increased with the energies. For the energy fluxes of energetic electrons, the modulation depth can be as high as 90%. During the oscillations, however, the plasma temperature had no apparent change. No correspondence was found between the motions of the flare loops and the quasi-periodic oscillations. We conclude that an oscillation with a high modulation depth for a period of about four minutes cannot be easily explained with the existing mechanisms.