Unique isoprene oxidation products demonstrate chlorine atom chemistry occurs in the Houston,Texas urban area

As part of the 2000 Texas Air Quality Study (TexAQS), we studied the isoprene oxidation process under ambient conditions to discern the presence of chlorine atom (Cl) chemistry in the Houston, Texas urban area. By measuring chloromethylbutenone (CMBO) and an isomer of chloromethylbutenal (CMBA), we clearly observed sixteen episodes of active Cl chemistry during the 24-day experiment. Estimated median Cl concentration during each of these episodes was between the detection limit of ~10² atoms cm⁻³ and 50 _{- 30} ^{+ 70} ×10⁴ 50_{ - 30}^{ + 70} \times {10^4} atoms cm⁻³. Cl concentration during all the episodes averaged 7.6 _{- 2.0} ^{+ 4.7} ×10⁴ 7.6_{ - 2.0}^{ + 4.7} \times {10^4} atoms cm⁻³ and thus amounted to less than 3% of the OH concentration during the same periods. During the episodes, the fraction of oxidation chemistry initiated by Cl ranged from 3–43% and was strongly dependent on the quantity and type of hydrocarbons present in the atmosphere. Because of its intermittent presence and low concentration, Cl is not a broadly influential oxidant in the Houston, Texas urban area.     

Airborne radar and in-situ observations of a shallow stratus with drizzle

Observations were made of a shallow stratus of upslope origin using an aircraft equipped with insitu probes and with a vertically-pointing radar of 3-mm wavelength. A cloud layer of 300 m thickness was found below the inversion; an additional layer of 100 m thickness was located within the inversion. The coldest temperature within the cloud was -2°C and the cloud contained no ice particles. Drizzle drops up to 180 Am were present in both cloud layers.The observations reveal precipitation and air motion structures of approximately 1 km horizontal dimensions. The origin of this organization appears to be weak convection. In addition, mixing played an important role in forming the cloud droplet and drizzle drop size distributions.     

Review of Lagrangian stochastic models for trajectories in the turbulent atmosphere

We review the theoretical basis for, and the advantages of, random flight models for the trajectories of tracer particles in turbulence. We then survey their application to calculate dispersion in the principal types of atmospheric turbulence (stratified, vertically-inhomogeneous, Gaussian or non-Gaussian turbulence in the surface layer and above), and show that they are especially suitable for some problems (e.g., quantifying ground emissions).     

Coastal processes and cliff recession between Gabicce and Pesaro (northern Adriatic Sea): a case history

Cliff recession on the high rocky coast between Gabicce and Pesaro Adriatic sea causes a wide range of mass movement processes on the whole slope, affecting both the bedrock and the overburden. The outcropping late Miocene rock formations are represented by marls, marly limestones, dark laminated mudstones and bedded sandstones and marls. Mass movements are common because of stratification and discontinuities in the rocks that, together with the presence of groundwater and weathering processes, reduce the overall strength of the slopes. A model for the evolution of this coastal area is proposed, which involves cyclic basal erosion, followed by mass movement that favours debris accumulation at the base of the cliff. The longshore currents have to then remove the material before a new cycle can begin.     

Factors and characteristics of the spatial correlation of the annual runoff of the Upper Ob basin rivers

The main features of the spatial and temporal oscillations of the annual runoff of the rivers in the Upper Ob basin, which is characterized by various landscape and hydrologic conditions, are discussed. It is found that the coefficients of pair correlation of the annual runoff have been decreasing since the late 1990s-early 2000s. Correlation functions for mountain areas should be constructed separately for river basins ranked according to the prevailing type of river feed. The coefficients of pair correlation can be described by multiple regression equations, which, apart from the distance between the centers of gravity of the basins, may include landscape characteristics such as the difference in their average elevation and forest cover.