Surface and groundwater pollution by organochlorine compounds in a typical soybean system from the south Pampa,Argentina

Organochlorine pesticides (OCPs) use has been restricted or forbidden in Argentina since 1998 and technical endosulfan is the last currently used OCPs on the soybean-wheat production. As they persist in soil for several years after application, OCPs constitute a source of environmental pollution. This work aims to assess OCPs contamination of groundwater (Gw) and streamwater (Sw) in the Quequén Grande River watershed from south Argentinean Pampas in relation to the hydrogeological characteristics. OCPs were analyzed in Sw, Gw, surface bottom sediments, soils and borehole cutting sediments (Cs) by gas chromatograph-electron capture detector. Pesticide distribution in Cs was dependent on the characteristic of the non-saturated zone. Leached pesticides over 3 m in Cs showed the pattern: HCHs = endosulfan > chlordanes > DDTs, and from 3 to 6 m heptachlor was the main group as a consequence of the past use of this compound in the area, mainly on potato crops. Endosulfan reaches Gw during application season as well as during flooding events while a retard effect was observed for Sw. Levels of α- and β-isomers were in certain cases above national (7 ng L⁻¹) and international (3 ng L⁻¹) limits for aquatic biota protection. As the endosulfan sulfate metabolite was present in Gw and Sw and due to its high toxicity, it should be considered in the establishment of water quality criteria for human and environmental protection.     

Dynamic modeling of forest conversion: Simulation of past and future scenarios of rural activities expansion in the fringes of the Xingu National Park,Brazilian Amazon

The present work is committed to simulate the expansion of agricultural and cattle raising activities within a watershed located in the fringes of the Xingu National Park, Brazilian Amazon. A spatially explicit dynamic model of land cover and land use change was used to provide both past and future scenarios of forest conversion into such rural activities, aiming to identify the role of driving forces of change in the study area. The employed modeling platform – Dinamica EGO – consists in a cellular automata environment that embodies neighborhood-based transition algorithms and spatial feedback approaches in a stochastic multi-step simulation framework. Biophysical variables and legal restrictions drove this simulation model, and statistical validation tests were then conducted for the generated past simulations (from 2000 to 2005), by means of multiple resolution fitting methods. Based on optimal calibration of past simulations, future scenarios were conceived, so as to figure out trends and spatial patterns of forest conversion in the study area for the year 2015. In all simulated scenarios, pasturelands remained nearly stable throughout the analyzed period, while a large expansion in croplands took place. The most optimistic scenario indicates that more than 50% of the natural forest will be replaced by either cropland or pastureland by 2015. This modeling experiment revealed the suitability of the adopted model to simulate processes of forest conversion. It also indicates its possible further applicability in generating simulations of deforestation for areas with expanding rural activities in the Amazon and in tropical forests worldwide.     

Observations of the 1.4mm brightness distribution of the sun

Observations of the 1.4 mm center to limb solar brightness distribution show that there is little, if any, limb brightening at this wavelength. Knowledge of the antenna radiation pattern is vital in interpreting the radio measurements.This work was supported by the U.S. Air Force under Contract No. F04701-70-C-0069.     

Tectonic accretion of a subducted intraoceanic remnant arc in Cretaceous Hokkaido, Japan, and implications for evolution of the Pacific northwest

Abstract   An accretionary complex, which contains fragments of a remnant island arc, was newly recognized in the Cretaceous accretionary terranes in Hokkaido, Japan. It consists of volcanics, volcanic conglomerate, intermediate to ultramafic intrusive rocks with island-arc affinity including boninitic rocks, accompanied by chert and deformed terrigenous turbidites. Compared with the results of modern oceanic surveys, the preserved sequence from island-arc volcanics to chert, via reworked volcanics, is indicative of intraoceanic remnant arc, because the sequence suggests an inactive arc isolated within a pelagic environment before its accretion. The age of a subducting oceanic crust can be discontinuous before and after a remnant-arc subduction, resulting in abrupt changes in accretion style and metamorphism, as seen in Cretaceous Hokkaido. Subduction of such an intraoceanic remnant arc suggests that the subducted oceanic plate in the Cretaceous was not an extensive oceanic plate like the Izanagi and/or Kula Plates as previously believed by many authors, but a marginal basin plate having an arc–back-arc system like the present-day Philippine Sea Plate.     

A comparison of 3.3-mm bursts and Hα emission during flares

Radio bursts observed at a wavelength of 3.3 mm are always associated with flares. The enhancement in the millimeter emission is strongly correlated with some optical event that is associated with the flare. Emissions in the bursts observed thus far, with the possible exception of those associated with proton flares, have not been large increases over quiescent readings and can be explained by a thermal mechanism.This work was supported by the U.S. Air Force under Contract No. F04695-67-C-0158.     

Correction to: Multilevel Graph Partitioning for Three-Dimensional Discrete Fracture Network Flow Simulations

Mathematical Geosciences - The publication of this article unfortunately contained a mistake. The assignment to the affiliations of author Satish Karra was not correct     

Estimation of HⅡ Bubble Size Distribution from 21cm Power Spectrum with Artificial Neural Networks

The bubble size distribution of ionized hydrogen regions probes information about the morphology of HⅡ bubbles during reionization.Conventionally,the HⅡ bubble ...     

Early Carboniferous HP metamorphism in the Hida Gaien Belt,Japan: Implications for the Palaeozoic tectonic history of proto‐Japan

We report two new eclogite localities (at Kanayamadani and Shinadani) in the high‐P (HP) metamorphic rocks of the Omi area in the western most region of Niigata Prefecture, Japan, which form part of the Hida Gaien Belt, and determine metamorphic conditions and pressure–temperature (P–T) paths. The metamorphic evolution of the eclogites is characterized by a tight hairpin‐shaped P–T path from prograde epidote–blueschist facies to peak eclogite facies and then retrograde blueschist facies. The prograde metamorphic stage is characterized by various amphibole (winchite, barroisite, glaucophane) inclusions in garnet, whereas the peak eclogite facies assemblage is characterized by omphacite, garnet, phengite and rutile. Peak P–T conditions of the eclogites were estimated to be ~600°C and up to 2.0 GPa by conventional cation‐exchange thermobarometry, Ti‐in‐zircon thermometry and quartz inclusion Raman barometry respectively. However, the Raman spectra of carbonaceous material thermometry of metapelites associated with the eclogites gave lower peak temperatures, possibly due to metamorphism at different conditions before being brought together during exhumation. The blueschist facies overprint following the peak of metamorphism is recognized by the abundance of glaucophane in the matrix. Zircon grains in blueschist facies metasedimentary samples from two localities adjacent to the eclogites have distinct oscillatory‐zoned cores and overgrowth rims. Laser ablation inductively coupled plasma mass spectrometry U–Pb ages of the detrital cores yield a wide range between 3,200 and 400 Ma, with a peak at 600–400 Ma. In the early Palaeozoic, proto‐Japan was located along the continental margin of the South China craton, providing the source of the older population of detrital zircon grains (3,200–600 Ma) deposited in the trench‐fill sediments. In addition, subduction‐related magmatism c. 500–400 Ma is recorded in the crust below proto‐Japan, which might have been the source for the younger detrital zircon grains. The peak metamorphic age was constrained by SHRIMP dating of the overgrowth rims, yielding Tournaisian ages of 347 ± 4 Ma, suggesting subduction in the early Carboniferous. Our results provide clear constraints on the initiation of subduction, accretion and the development of an arc‐trench system along the active continental margin of the South China craton and help to unravel the Palaeozoic tectonic history of proto‐Japan.     

Seismic performance of chevron-configured special concentrically braced frames with yielding beams

Current seismic design requirements for special concentrically braced frames (SCBFs) in chevron configurations require that the beams supporting the braces be designed to resist the demands resulting from the simultaneous yielding of the tension brace and degraded, post-buckling strength of the compression brace. Recent research, including large-scale experiments and detailed finite-element analyses, has demonstrated that limited beam yielding is not detrimental to chevron braced frame behavior and actually increases the story drift at which the braces fracture. These findings have resulted in new expressions for computing beam demands in chevron SCBFs that reduce the demand in the tension brace to be equal to the expected compressive capacity at buckling of the compression brace. In turn, the resultant force on the beam is reduced as is the required size of the beam. Further study was undertaken to investigate the seismic performance of buildings with SCBFs, including chevron SCBFs with and without yielding beams and X-braced frames. Prototype three- and nine-story braced frames were designed using all three framing systems, that is, chevron, chevron with yielding beams, and X SCBFs, resulting in six building frames. The nonlinear dynamic response was studied for ground motions simulating two different seismic hazard levels. The results were used to characterize the seismic performance in terms of the probability of salient damage states including brace fracture, beam vertical deformation, and collapse. The results demonstrate that the seismic performance of chevron SCBFs with limited beam yielding performs as well as or better than the conventionally designed chevron and X SCBFs.     

The basement geology of Japan from A to Z

The Precambrian and lower Paleozoic units of the Japanese basement such as the Hida Oki and South Kitakami terranes have geological affinities with the eastern Asia continent and particularly strong correlation with units of the South China block. There are also indications from units such as the Hitachi metamorphics of the Abukuma terrane and blocks in the Maizuru terrane that some material may have been derived from the North China block. In addition to magmatism, the Japanese region has seen substantial growth due to tectonic accretion. The accreted units dominantly consist of mudstone and sandstone derived from the continental margin with lesser amounts of basaltic rocks associated with siliceous deep ocean sediments and local limestone. Two main phases of accretionary activity and related metamorphism are recorded in the Jurassic Mino–Tanba–Ashio, Chichibu, and North Kitakami terranes and in the Cretaceous to Neogene Shimanto and Sanbagawa terranes. Other accreted material includes ophiolitic sequences, e.g. the Yakuno ophiolite of the Maizuru terrane, the Oeyama ophiolite of the Sangun terrane, and the Hayachine–Miyamori ophiolite of the South Kitakami terrane, and limestone‐capped ocean plateaus such as the Akiyoshi terrane. The ophiolitic units are likely derived from arc and back‐arc basin settings. There has been no continental collision in Japan, meaning the oceanic subduction record is more complete than in convergent orogens seen in intracontinental settings making this a good place to study the geological record of accretion. Hokkaido lacks most of the Paleozoic history recognized in Honshu, Shikoku, Kyushu, and the Ryukyu Islands to the south and its geology reflects the Cenozoic development of two convergent domains with volcanic arcs, their approach, and eventual collision. The Hidaka terrane reveals a cross section through a volcanic arc and the main accretionary complex of the convergent system is represented by the Sorachi–Yezo terrane.