Fine structures of mutually normalized rare-earth patterns of chondrites

REE abundances in ten chondrites (nine falls and one find) were determined very accurately by mass-spectrometric stable isotope dilution techniques. All of the chondrites have different relative and absolute REE patterns. Except for Eu and, rarely, for Ce, the REE abundances in chondrites are smoothly fractionated from sample to sample. Notwithstanding differences in the abundances of common REE, four of five L6 chondrites have very similar absolute Eu abundances; their mutually-normalized REE patterns are not curved, but are composed of two rectilinear segments.The Leedey-normalized REE pattern for St. Séverin (LL6) is composed of two concave curves. Yonozu's (H4,5) pattern shows negligibly concave curvature on both sides of Eu. Kesen's (H4) pattern is unusual in its overall pattern but also in irregularities for particular elements. The irregularity may be connected with the unusually high vapor pressure of metallic Yb. The REE pattern for the Allende bulk sample shows a discontinuity, presumably reflecting its considerable heterogeneity of composition and structure. It is evident that any pattern of ordinary chondrites cannot be produced from the Allende bulk pattern. A comparison is also made with the results on the chondrite composites previously investigated.     

Effect of the formation of EDTA complexes on the diffusion of metal ions in water

The diffusion coefficients of aquo metal ions (M^z+) and their EDTA complexes (M-EDTA^(z−4)+) were compared to understand the effect of EDTA complexation on the diffusion of metal ions by the diffusion cell method for Co²⁺, Ga³⁺, Rb⁺, Sr²⁺, Ag⁺, Cd²⁺, Cs⁺, Th⁴⁺, , and trivalent lanthanides. Most studies about ionic diffusion in water have dealt with free ion (hydrated ion). In many cases, however, polyvalent ions are dissolved as complexed species in natural waters. Hence, we need to study the diffusion behavior of complexes in order to understand the diffusion phenomenon in natural aquifer and to measure speciation by diffusive gradient in thin films (DGT), which requires the diffusion coefficients of the species examined. For many ions, the diffusion coefficients of M-EDTA^(z−4)+ are smaller than those of hydrated ions, but the diffusion coefficients of M-EDTA^(z−4)+ are larger than those of hydrated ions for ions with high ionic potentials (Ga³⁺ and Th⁴⁺). As a result, the diffusion coefficients of EDTA complexes are similar among various metal ions. In other words, the diffusion of each ion loses its characteristics by the complexation with EDTA. Although the difference is subtle, it was also found that the diffusion coefficients of EDTA complexes increase as the ionic potential increases, which can be explained by the size of the EDTA complex of each metal ion.     

Swell-dominant surface waves observed by a moored buoy with a GPS wave sensor in Otsuchi Bay,a ria in Sanriku,Japan

Real-time monitoring of wind and surface waves in Otsuchi Bay, Iwate, Tohoku, Japan, commenced in October 2012, using a mooring buoy with an ultrasonic anemometer and a single-mode GPS wave sensor. Wind and wave data are distributed hourly in real time via the Internet along with a chart of their time series. We analyzed data monitored in the first 3 months in order to assess the variability and occurrence of wind and waves and to elucidate the main reasons for wave variation in Otsuchi Bay. The monitoring data revealed that surface waves in the bay were predominantly affected by swells propagated from the northeastern offshore region and that the wave height was significantly correlated with the component of wind velocity toward Otsuchi Bay in the northeastern offshore region that faces the bay mouth. The offshore wind field was expected to provide information useful for predicting coastal waves in a ria bay in Sanriku such as Otsuchi Bay. However, it should be emphasized that the horizontal distribution of the offshore wind field which has a significant effect on the surface waves in a ria bay depends heavily on the topographic shape of the bay.     

New record of <Emphasis Type="Italic">Lobophora rosacea</Emphasis> (Dictyotales; Phaeophyceae) from the South China Sea

Lobophora rosacea C.W. Vieira, Payri et De Clerck is reported from the South China Sea for the first time. Our specimens are very similar to L. rosacea recently described from New Caledonia, not only in morphology but also in rbcL and cox3 gene sequences. The fan-shaped thallus grows erectly, attaching to the substrate by a basal holdfast. The thallus is composed of a single layer of large medullary cells and three to four layers of cortical cells on both sides of the medulla. Mature sporophytes are detected, with sporangium sori scattered on both surfaces of the thallus.     

Conceptual model of the evolution of groundwater quality at the wet zone in Sri Lanka

 The evolution of groundwater quality at a wet zone in Sri Lanka was made clear using field investigation, chemical and isotopic analyses methods. In the wet zone, the concentrations of major ions and electrical conductivity (EC) in the groundwater are low with small seasonal change. Except for sodium, silica and chloride, the EC and other major ion concentrations increase along the groundwater flow direction. The contributions of bicarbonate and calcium ions to the increase in EC are the largest among the major ions. The groundwater quality shows calcium-bicarbonate type, the initial stage of the Chebotarev series. There is a seasonal change in isotopic composition. The isotopically lighter groundwater was found at the valley bottom in the rainy season. Under the very heavy precipitation conditions, the slope of the regression line between δD and δ¹⁸O and deuterium excess for groundwater are close to 8 and 10, respectively. In other cases, the slopes of the regression lines and deuterium excess are, less than 8 and 10, respectively. Received: 5 August 1998 · Accepted: 19 October 1998     

RXTE observation of NGC 6240: a search for the obscured active nucleus

We present new data taken at 850 μm with SCUBA at the James Clerk Maxwell Telescope for a sample of 19 luminous infrared galaxies. Fourteen galaxies were detected. We have used these data, together with fluxes at 25, 60 and 100 μm from IRAS , to model the dust emission. We find that the emission from most galaxies can be described by an optically thin, single temperature dust model with an exponent of the dust extinction coefficient ( k _λ ∝ λ ^{− β} ) of β ≃1.4–2. A lower β ≃1 is required to model the dust emission from two of the galaxies, Arp 220 and NGC 4418. We discuss various possibilities for this difference and conclude that the most likely is a high dust opacity. In addition, we compare the molecular gas mass derived from the dust emission, M _850 μm, with the molecular gas mass derived from the CO emission, M _CO, and find that M _CO is on average a factor 2–3 higher than M _850 μm.     

Geochemical constraints on the depositional environment of the 1.84 Ga Embury Lake Formation,Flin Flon Belt,Canada

The Flin Flon Belt of Canada contains Paleoproterozoic volcanic–sedimentary sequences that are related to the Trans‐Hudson Orogeny. The sequences include island arc volcanic and volcaniclastic rocks (Amisk Group) that are unconformably overlain by subaerial sedimentary rocks (Missi Group), and younger deep facies sediments. In the Flin Flon area, several north–south trending faults divide the sequences into blocks and obscure the depositional environment of the deep facies sediments. Locally, within the Flin Flon area, the Embury Lake Formation is in fault contact with island arc volcanic–sedimentary sequences of the Amisk and Missi Groups. To identify the depositional environment of the Embury Lake Formation, we used lithologic and geochemical approaches. Here, we report carbon isotopic values in organic matter (δ¹³C_org) and sulfur isotopes (δ³⁴S), as well as total organic carbon and total sulfur measurements for the black shale in the formation. Samples were taken from a drill core that contains alternating bands of sandstone and black shale. Pyrite in the black shale is divided into four textural types: euhedral, vein‐type, elliptical, and microcrystalline. Microcrystalline pyrite is typically generated by microbially mediated sulfate reduction. An extremely low S/C ratio (avg. = 0.04) is consistent with lacustrine deposition. The ranges of δ¹³C_org (?36 ‰ to ?27 ‰) and δ³⁴S (+3.0 ‰ to +7.7 ‰) values can be explained by bacterial photosynthesis that involved Calvin cycle and acetyl CoA pathways, and sulfate reduction in a low‐sulfate environment. Considering the depositional age reported in a previous study of < 1.84 Ga, the Embury Lake Formation was likely emplaced in a lacustrine setting during the Trans‐Hudson Orogeny.     

Devonian shallow marine ostracods from central Japan

Thirteen ostracod species including two new species, Clavofabellina fukujiensis n. sp. and Bythocypris wangi n. sp., are reported from the Middle Shale Member of the Fukuji Formation, Devonian of central Japan. The ostracods demonstrate species‐links with South China, indicating that the Hida‐Gaien Terrane of central Japan shared biogeographical affinities with the shallow marine faunas of the South China paleocontinent during the Early Devonian.     

Contribution of different functional groups to the diet of major predatory fishes at a seagrass meadow in northeastern Japan

We examined the variation in habitat use and diet of three dominant fish species (Myoxocephalus brandti, Pholidapus dybowskii, and Pholis crassispina) in a seagrass meadow in the Akkeshi-ko estuary in northeastern Japan, where broad and dense Zostera marina beds exist, using a semi-quantitative census of the fishes and analyses of their stomach contents. Differences among the three fish species in the temporal variation in abundance of each age class (mainly 1- and 2-year age classes) indicated that the temporal pattern of utilization of the seagrass meadow were different among them. In the semi-quantitative dietary analysis, two prey categories, i.e., taxonomic group (order and suborder) and functional group, were used to explain the variation in prey composition with size-dependent changes. The six prey functional groups were classified based on the ecological traits of the prey, i.e., trophic level, size, and life type (habitat and behavior). Ontogenetic shifts in prey of the three fish species could be fully explained by a combination of the two prey categories, and not by the use of only one category (taxonomic or functional group). The pattern of ontogenetic shifts in prey differed among the fish species and size (age) classes. These results indicate that segregation of habitat (seagrass meadow) and prey group (taxonomic and functional group) is performed among the three species, which may contribute to their coexistence in this estuary.