Simulation analysis of ground liquefaction induced by earthquake

A dynamic effective stress analysis with the finite element method has long been recommended to predict the liquefaction phenomena of sandy soil by authors and Zienkiewicz et al. as well as the similar approaches by the others. Our approach of the analysis is summarized in the first.

Until recently, however, these approaches has not commonly been used as the means of design, although its capability of prediction is appreciated by geotechnicians. This method has been neglected because of the lack of verification studies of soil models of sand and mathematical formulation for boundary problems of liquefaction phenomena. Therefore the verification of the numerical method to evaluate liquefaction potential are urgent requirement of the recent engineering practice. To respond this requirement, extensive numerical studies on the liquefation simulations are performed by DIANA program for shaking table tests which have been conducted by the authors. The test models are soil-structure type models with combination of homogenous ground and partially improved ground by compaction.

The good performance of our approach is proved by the results of numerical simulation showing good agreement with experimental data in terms of response acceleration, excess pore pressure, and deformation profile. It is also demonstrated that the numerical results can provide substantial information to understand the mechanisms of soil ground behavior which is not easily obtained by experiments.

The procedure to identify soil constants for the reflecting surface model is also reported in details.     

Evaluating Global Warming Potentials with historical temperature

Global Warming Potentials (GWPs) are evaluated with historical temperature by applying them to convert historical CH₄ and N₂O emissions to equivalent CO₂ emissions. Our GWP analysis is based on an inverse estimation using the Aggregated Carbon Cycle, Atmospheric Chemistry, and Climate Model (ACC2). We find that, for both CH₄ and N₂O, indices higher than the Kyoto GWPs (100-year time horizon) would reproduce better the historical temperature. The CH₄ GWP provides a best fit to the historical temperature when it is calculated with a time horizon of 44 years. However, the N₂O GWP does not approximate well the historical temperature with any time horizon. We introduce a new exchange metric, TEMperature Proxy index (TEMP), that is defined so that it provides a best fit to the temperature projection of a given period. By comparing GWPs and TEMPs, we find that the inability of the N₂O GWP to reproduce the historical temperature is caused by the GWP calculation methodology in IPCC using simplifying assumptions for the background system dynamics and uncertain parameter estimations. Furthermore, our TEMP calculations demonstrate that indices have to be progressively updated upon the acquisition of new measurements and/or the advancement of our understanding of Earth system processes.     

Diffuse bifurcations engraving diverse shear bands in granular materials

Shear bands with characteristic spatial patterns observed in an experiment for a cubic or parallelepiped specimen of dry dense sand were simulated by numerical bifurcation analysis using the Cam‐clay plasticity model. By incorporating the subloading surface concept into the plasticity model, the model became capable of reproducing hardening/softening and contractive/dilative behavior observed in the experiment. The model was reformulated to be compatible with the multiplicative hyperelasto‐plasticity for finite strains. This enhanced constitutive model was implemented into a finite‐element code reinforced by a stress updating algorithm based on the return‐mapping scheme, and by an efficient numerical procedure to compute critical eigenvectors of elastoplastic tangent stiffness matrix at bifurcation points. The emergence of diamond‐ and column‐like diffuse bifurcation modes breaking uniformity of the materials, followed by the evolution of shear bands through strain localization, was observed in the analysis. In the bifurcation analysis of plane strain compression test, unexpected bifurcation modes, which broke out‐of‐plane uniformity and led to 3‐dimensional diamond‐like patterns, were detected. Diffuse bifurcations, which were difficult to observe by experiments, have thus been found as a catalyst creating diverse shear band patterns.     

Spirits of Yokokurayama: shrine of the Japanese trilobites

‘We are such stuff as dreams are made on, and our little life is rounded with a sleep’. So sleep the trilobites of Yokokurayama, a sacred mountain hidden within the beautiful landscape of Japan’s Shikoku’s island. And though Prospero may have been speaking to his daughter and her fiancé (in William Shakespeare’s The Tempest), he might well have been contemplating the magnificent trilobite fossils of Yokokurayama. Japan may be better known for its sweeping volcanic landscapes, majestic castles, Shinto shrines and bullet trains, but it is also home to important collections of Silurian and Devonian trilobites.     

Seasonal variation in the Ra/Ra ratio of coastal water within the Sea of Japan: Implications for the origin and circulation patterns of the Tsushima Coastal Branch Current

In the current study, low-background γ-spectrometry was employed to determine the ²²⁸Ra/²²⁶Ra activity ratio and ¹³⁷Cs activity of 84 coastal water samples collected at six sites along the main island of Japan (Honshu Island) within the Sea of Japan, including the Tsushima Strait, and two other representative sites on Honshu Island (a Pacific shore and the Tsugaru Strait) at 1-month intervals in 2006.The ²²⁸Ra/²²⁶Ra ratio of coastal waters in the Sea of Japan exhibited similar patterns of seasonal variation, with minimum values during early summer (²²⁸Ra/²²⁶Ra = 0.6–0.8), maximum values during autumn (²²⁸Ra/²²⁶Ra = 1.5–3), and a time lag in their temporal changes ( 2.5 months and over  1300 km distance). However, the 2 other sites represented no clear periodic variation.In contrast to the positive correlation between ¹³⁷Cs activity (0.6–1.7 mBq/L) and salinity (15–35), the ²²⁸Ra/²²⁶Ra ratio of coastal water samples from the Sea of Japan was not observed to correlate with salinity, and the increase in the ²²⁸Ra/²²⁶Ra ratio was not as marked (0.5–1; May–June 2004 and 2005) during the migration along Honshu Island. The input of land-derived water and/or the diffusion of radium from coastal sediments is unlikely to have affected the wide seasonal variation in the ²²⁸Ra/²²⁶Ra ratio observed in these water samples.The seasonal variation in the ²²⁸Ra/²²⁶Ra ratio recorded for the coastal waters of the Sea of Japan is considered to be mainly controlled by the remarkable changes in the mixing ratio of the ²²⁸Ra-poor Kuroshio and the ²²⁸Ra-rich continental shelf waters within the East China Sea (ECS). After passing through the Tsushima Strait, this water mass moves northeast along the coastline of the Sea of Japan as the Tsushima Coastal Branch Current (TCBC).     

Does black carbon abatement hamper CO 2 abatement?

Concerns have been raised that near-term black carbon abatement strategies for global warming mitigation would interfere with the longer-term CO₂ abatement efforts. In response, we put forward a “combined target and metric approach”, a theoretical framework, in which the time horizon of the metric is linked to the specific target of the climate policy. In this approach, a shorter time horizon for the metric is justified only when the overall climate policy is tightened; the lower the target level of the climate policy, the earlier the year of the target. Employing a consistent time perspective for the metric and target means that enhanced near-term reduction of short-lived climate forcers does not reduce the importance of the CO₂ abatement, since the overall climate target is stricter.     

The structure and behavior of the arctic cyclone in summer analyzed by the JRA-25/JCDAS data

In this study, three-dimensional structures and the life-time behavior of arctic cyclones are investigated as case studies, using reanalysis data of JRA-25 and JCDAS. In recent years, arctic region has undergone drastic warming in conjunction with the reduced sea ice concentration in summer. The rapid reduction of the sea ice concentration is explained, to some extent, by a pressure dipole of the arctic cyclone and Beaufort high over the Arctic Ocean. This paper presents some case studies for the structure of the arctic cyclone.It is found by the analysis of this study that the arctic cyclone indicates many differences in structure and behavior compared with the mid-latitude cyclone. The arctic cyclones move rather randomly in direction over the Arctic Ocean. The arctic cyclone has a barotropic structure in the vertical from the surface to the stratosphere. The arctic cyclone detected at the sea level pressure is connected with the polar vortex at the 500 hPa level and above. Importantly, the arctic cyclone has a cold core in the troposphere and a warm core around the 200 hPa level. The mechanism of the formation is discussed based on the analyzed structure of the arctic cyclones.     

Phytoplankton assemblage in the Plio-Pleistocene record of Lake Baikal as indicated by sedimentary steryl chlorin esters

Past changes in phytoplankton assemblages in Lake Baikal over the last 4.5 Ma, both in population and composition, are inferred from the downcore profiles of the relatively stable chlorophyll derivatives steryl esters of pyropheophorbides a and b (steryl chlorine esters; SCEs) in the 0–200 m section of the BDP-98 drill core, supplemented by the data on biogenic silica (BSi) and total organic carbon (TOC) contents. SCEs-a and -b dominate among sedimentary chlorophyll derivatives in the BDP-98 sediments except for the upper few meters, indicating their high stability during diagenetic alteration of sediments. The depth (age) profiles of SCEs-a are consistent with BSi and TOC profiles and are interpreted as reflecting primary productivity of the lake in the past. Baikal proxies reveal close correlation with marine oxygen isotope records (MIS stratigraphy). These observations confirm that climate change in the northern hemisphere has been a primary factor controlling the total phytoplankton productivity in Lake Baikal during the last several million years.Among SCEs-a, C₃₀ (dinostanol)-SCE-a, a marker of dinoflagellates was identified by GC–MS analysis. SCE-b, a marker of green algae, was identified by its UV–vis spectrum. The ratio of C₃₀-SCE-a to total SCEs-a (TSCEs-a) was higher during 4.5–4.2 and 1.7–1.3 Ma, suggesting that dinoflagellates proliferated preferentially in those periods. The early Pleistocene maximum of this ratio corresponds to the broad minimum of diatom abundance previously suggested to have recorded a prolonged regional cooling. An abrupt increase in the SCE-b/TSCEs-a ratio was observed at 2.5–2.6 Ma, indicating that green algae containing chlorophyll b have proliferated in Lake Baikal during this period. This interval has also been suggested to contain evidence for a significant regional cooling based on minima of diatom abundance and BSi in sediments. The depth profile of C₂₇Δ⁵ (cholesterol)-SCE-a relative to TSCEs-a showed a trend similar to that of BSi, suggesting that C₂₇Δ⁵-SCE-a/TSCEs-a ratio is a potential marker of diatoms in Lake Baikal.Certain mismatches between the Lake Baikal profiles of biological indicators and the marine oxygen isotope records, as well as the slight temporal offsets between different Lake Baikal biological marker signals suggest that the regional component of climatic and/or lacustrine environmental changes also have played a role in determining the composition of the Lake Baikal Plio-Pleistocene phytoplankton assemblage.     

Long-range transport of particulate polycyclic aromatic hydrocarbons at Cape Hedo remote island site in the East China Sea between 2005 and 2008

Particle-associated polycyclic aromatic hydrocarbons (PAHs) in outflow from East Asia were observed at Cape Hedo, Okinawa, Japan between 2005 and 2008. The filter samples of the total suspended particles were analyzed by means of gas chromatography-mass spectrometry. The total concentration of fourteen 3–7-ring PAHs was 0.01–24 ng m^?3 (average 1.6 ng m^?3). The average PAH concentration increased in the winter-spring season and decreased in the summer-fall season. The average benzo(a)pyrene to benzo(e)pyrene ratio was 0.49 in the winter-spring season and was lower than the literature values for East Asian cities in the same season. This result shows that aging of organic aerosol particles proceeds during long-range transport from East Asia. In the Asian Pacific region, these pollutants are transported from East Asia in the winter-spring season, whereas clean air mass is transported from the Pacific Ocean in the summer-fall season.     

EXAFS study on the cause of enrichment of heavy REEs on bacterial cell surfaces

Rare earth element (REE) pattern is a unique geochemical tracer and has been measured for various natural materials. Among these, the REE distribution pattern between bacteria and water exhibits anomalous enrichment in the heavy REE (HREE) part, which can act as a signature of bacteria-related materials in natural samples. In this study, the REE binding site on the cell surface of a Gram-positive bacterium (Bacillus subtilis) responsible for HREE enrichment has been identified using extended X-ray absorption fine structure (EXAFS) coupled with a study of the variation in REE distribution patterns. The EXAFS data showed that the HREEs form complexes with multiple phosphate site (including phosphoester site) with a larger coordination number (CN) at lower REE-bacteria ratios ([REE]/[bac]), while light and middle REEs form complexes to the phosphate site with a lower CN. The fraction coordinated to carboxylate increased for all REEs with increasing [REE]/[bac] ratio. On the other hand, the enrichment of HREE in the REE distribution patterns of the bacteria was less marked with increasing [REE]/[bac] ratio. This result is consistent with the EXAFS data, because the REE pattern of surface complex with multiple phosphate in a reference material exhibits a monotonous increase for heavier REE, while phosphate surface complex with a low CN and a carboxylate site reach a maximum around Sm and Eu. Based on these results, it is clear that the REE are primarily bound to the phosphate site and subsequently to the carboxylate site on the bacterial cell surface.Regarding the pH dependence in the range (3 < pH < 7), both the EXAFS and REE pattern data indicate that the fraction of REE-carboxylate increased as the pH increases. The results above obtained for B. subtilis were also valid for Escherichia coli, a Gram-negative bacterium, showing that similar phosphate and carboxylate sites are also available in the cell walls of E. coli, or other Gram negative bacteria. In all our results, the variation in REE patterns correlated with the binding site indicated by EXAFS, showing that the REE pattern itself reflects the binding site of the REE at the bacterial surface for various parameters (pH and [REE]/[bac] ratio). Thus, the REE patterns can be used to estimate the binding sites for lower [REE]/[bac] ratios where spectroscopic techniques cannot be applied.The average bond length between the REE and oxygen was compared for various REE sorbed on bacteria, showing that the bond length for HREE (Er to Lu) was much shorter than those extrapolated from the trend between La and Dy, because of the selective binding of the HREE as the multiple phosphate surface complexes. Our results are consistent with the selective enrichment of the HREE at the bacterial cell surfaces, considering that chemical species with a shorter bond length are more stable. Thus, it is clear that the HREE enrichment at the bacterial cell surfaces is caused by the formation of the multiple phosphate surface complexes. Based on these results, it is suggested that materials having such phosphate sites such as bacteria and bacteria-related materials can induce anomalous HREE enrichment in natural systems.