Chemical and mineralogical compositions of two grains recovered from asteroid Itokawa

Two silicate grains (RB‐QD04‐0049 and RA‐QD02‐0064, whose estimated masses are 0.050 μg and 0.048 μg, respectively) recovered from the asteroid Itokawa by the Hayabusa spacecraft were studied for their mineralogical characteristics by synchrotron X‐ray diffraction and synchrotron X‐ray microtomography and further analyzed for their bulk chemical compositions by instrumental neutron activation analysis (INAA). According to X‐ray tomography, RB‐QD004‐0049 is composed of olivine, high‐Ca pyroxene, plagioclase, Ca‐phosphate, and troilite, whereas RA‐QD002‐0064 entirely consists of olivine. INAA data are consistent with these mineral compositions except for rare earth elements (REEs). Although the grain RB‐QD004‐0049 contains measurable REEs, which seems to be consistent with the presence of Ca‐phosphate, their abundances are anomalously high. Very low abundance of Co implies less than 0.1 mass% of metals in these two grains by calculation, which is in contrast to the result for the previously analyzed grain RA‐QD02‐0049 (Ebihara et al., 2011). FeO/Sc ratios of the grains fall within the range of those for ordinary chondrite olivines, implying that these grains are extraterrestrial in origin. FeO/MnO ratios also confirm this conclusion and further suggest that the Hayabusa grains analyzed in this study are similar to material found in LL chondrites rather than CK chondrites although olivines from LL and CK chondrites have similar Fa# (molar% of Fe relative to [Fe+Mg] in olivine) (~30) to those of the Hayabusa grains including the two grains analyzed in this study.     

Global warming trend without the contributions from decadal variability of the Arctic Oscillation

Climate change associated with recent global warming is most prominent in the Arctic and subarctic. The Arctic Oscillation (AO) is a dominant atmospheric phenomenon in the Northern Hemisphere. Decadal variability of surface air temperature (SAT) associated with the AO index shows high correlation with recent global warming trend. In this study, the SAT variability in the Northern Hemisphere is separated in contributions from decadal variability by the AO and remaining components.The results indicate that the decadal variability of the AO index shows high correlation with the SAT variation until 1990. The AO index and SAT variabilities show a negative trend during 1949–1969, while the trend is positive during 1969–1989. In addition, the spatial distribution pattern of the SAT linear trend during each period shows the same pattern as AO. However, while the AO index indicates a negative trend, the SAT trend is continuously positive also after 1990. This warming pattern appearing after 1990 is caused by the Arctic amplification.Although the AO has a large amplitude on local scale, the AO is almost dynamically orthogonal to the hemispheric warming component. However, the AO can be related to the decadal variability of the Arctic and subarctic temperature change through the feedbacks by climate sub-systems.     

Capability of the penetrator seismometer system for lunar seismic event observation

We developed a seismometer system for a hard landing “penetrator” probe in the course of the former Japanese LUNAR-A project to deploy new seismic stations on the Moon. The penetrator seismometer system (PSS) consists of two short-period sensor components, a two-axis gimbal mechanism for orientation, and measurement electronics. To carry out seismic observations on the Moon using the penetrator, the seismometer system has to function properly in a lunar environment after a hard landing (impact acceleration of about 8000 G), and requires a signal-to-noise ratio to detect lunar seismic events. We evaluated whether the PSS could satisfactorily observe seismic events on the Moon by investigating the frequency response, noise level, and response to ground motion of our instrument in a simulated lunar environment after a simulated impact test. Our results indicate that the newly developed seismometer system can function properly after impact and is sensitive enough to detect seismic events on the Moon. Using this PSS, new seismic data from the Moon can be obtained during future lunar missions.     

Pingos on Earth and Mars

Pingos are massive ice-cored mounds that develop through pressurized groundwater flow mechanisms. Pingos and their collapsed forms are found in periglacial and paleoperiglacial terrains on Earth, and have been hypothesized for a wide variety of locations on Mars. This literature review of pingos on Earth and Mars first summarizes the morphology of terrestrial pingos and their geologic contexts. That information is then used to asses hypothesized pingos on Mars. Pingo-like forms (PLFs) in Utopia Planitia are the most viable candidates for pingos or collapsed pingos. Other PLFs hypothesized in the literature to be pingos may be better explained with other mechanisms than those associated with terrestrial-style pingos.     

(Na,Ca)(Ti3+,Mg)Si2O6-clinopyroxenes at high pressure: influence of cation substitution on elastic behavior and phase transition

A compressional study of (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxenes was carried out at high pressures between 10⁻⁴ and 10.2 GPa using in situ single-crystal X-ray diffraction, Raman spectroscopy and optical absorption spectroscopy. Compressional discontinuities accompanied by structural changes, in particular, the appearance of two distinct Ti³⁺–Ti³⁺ distances within the octahedral chains at 4.37 GPa, provide evidence for the occurrence of a phase transition in NaTi³⁺Si₂O₆. Equation-of-state parameters are K ₀ = 115.9(7) GPa with K′ = −0.9(3) and K ₀ = 102.7(8) GPa with K′ = 4.08(5) for the low- and high-pressure range, respectively. The transition involves a C2/c–P [`1] \overline{1} symmetry change, which can be confirmed by the occurrence of new modes in Raman spectra. Since no significant discontinuity in the evolution of the unit-cell volume with pressure has been observed, the transition appears to be second-order in character. The influence of the coupled substitution Na⁺Ti³⁺↔Ca²⁺Mg²⁺ on the static compression behavior and the structural stability has been investigated using a sample of the intermediate composition (Na_0.54Ca_0.46)(Mg_0.46Ti_0.54)Si₂O₆. No evidence for a deviation from continuous compression behavior has been found, neither in lattice parameter nor in structural data and the fit of a third-order Birch–Murnaghan equation-of-state to the pressure–volume data yields a bulk modulus of K ₀ = 109.1(5) GPa and K′ = 5.02(13). Raman and polarized absorption spectra have been compared to NaTiSi₂O₆ and reveal major similarities. The main driving force for the phase transition in NaTi³⁺Si₂O₆ is the localization of the Ti³⁺ d-electron and the accompanying distortion, which is suppressed in the (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxene.     

Determination of the oxidation state of radiogenic Pb in natural zircon using X-ray absorption near-edge structure

We examined the L_III-edge Pb X-ray absorption near-edge structure (XANES) of three natural zircon samples with different amounts of radiation doses (1.9 × 10¹⁵ to 6.8 × 10¹⁵ α-decay events/mg). The results suggest that the oxidation state of radiogenic Pb in the zircon sample with the highest radiation dose is divalent. The XANES spectra of the two other samples with lower radiation doses suggest that radiogenic Pb(II) is present, and further that some Pb may be tetravalent. This is the first work on the determination of the oxidation state of radiogenic Pb in natural zircon using XANES.     

Fragmentation model dependence of collision cascades

Mass depletion of bodies through successive collisional disruptions (i.e., collision cascade) is one of the most important processes in the studies of the asteroids belt, the Edgeworth-Kuiper belt, debris disks, and planetary formation. The collisional disruption is divided into two types, i.e., catastrophic disruption and cratering. Although some studies of the collision cascades neglected the effect of cratering, it is unclear which type of disruption makes a dominant contribution to the collision cascades. In the present study, we construct a simple outcome model describing both catastrophic disruption and cratering, which has some parameters characterizing the total ejecta mass, the mass of the largest fragment, and the power-law exponent of the size distribution of fragments. Using this simple outcome model with parameters, we examine the model dependence of the mass depletion time in collision cascades for neglect of coalescence of colliding bodies due to high collisional velocities. We find the cratering collisions are much more effective in collision cascades than collisions with catastrophic disruption in a wide region of the model parameters. It is also found that the mass depletion time in collision cascades is mainly governed by the total ejecta mass and almost insensitive to the mass of the largest fragment and the power-law exponent of fragments for a realistic parameter region. The total ejecta mass is usually determined by the ratio of the impact energy divided by the target mass (i.e. Q-value) to its threshold value for catastrophic disruption, as well as in our simple model. We derive a mass depletion time in collision cascades, which is determined by of the high-mass end of collision cascades. The mass depletion time derived with our model would be applicable to debris disks and planetary formation.     

A heating process of Kuchi-erabu-jima volcano,Japan, as inferred from geomagnetic field variations and electrical structure

Since August 2000, we have recorded the total intensity of the geomagnetic field at the summit area of Kuchi-erabu-jima volcano, where phreatic eruptions have repeatedly occurred. A time series analysis has shown that the variations in the geomagnetic field since 2001 have a strong relationship to an increase in volcanic activity. These variations indicate thermal demagnetization of the subsurface around the presently active crater. The demagnetization source for the early variations, until summer 2002, was estimated at about 200 m below sea level. For the variations since 2003, the source was modeled on the basis of the expansion of a uniformly magnetized ellipsoid. The modeling result showed that the source is located at 300 m above sea level beneath the crater. We carried out an audio-frequency magnetotelluric survey with the aim of obtaining a relation between the demagnetization source and the shallow structure of the volcano. A two-dimensional inversion applied to the data detected two good conductors, a shallow thin one which is restricted to a region around the summit area, while the other extends over the edifice at depths between 200 and 800 m. These conductors are regarded as clay-rich layers with low permeability, which were assumed to be generated through hydrothermal alteration. The demagnetization source for the early variations was possibly located at the lower part of the deep conductor and the source after 2003 lies between the two conductors, where groundwater is considered to be abundant. Based on these results, as well as on seismological, geodetic, and geochemical information, we propose a heating process of the Kuchi-erabu-jima volcano. In the initial stage, high-temperature volcanic gases supplied from the deep-seated magma remained temporarily at the level around the lower part of the less permeable deep conductor since the ascent path had not yet been established. Then, when the pathway developed as a result of repeated earthquakes, it became possible for a massive flux of volcanic gases to ascend through the conductor. The high temperature gases reached the aquifer located above the conductor and the heat was efficiently transported to the surrounding rocks through the groundwater. As a consequence, an abrupt increase of the gas flux and diffusion of the heat through the aquifer occurred and the high-temperature zone expanded. Since the high-temperature zone is located beneath another conductor, which acts as caprock, we assume that the energy of the phreatic explosion is accumulated there.     

Generation of greenhouse effect gases from different landfill types

Recently much attention is focussed on the problems of global warming due to greenhouse effect gases, notably carbon dioxide and methane. Because these gases cause important problems to the global environment, their generation from landfill sites containing solid wastes has drawn attention and their environmental impact is causing concern.

Generally, the gases associated with a greenhouse effect include carbon dioxide, methane and nitrous oxide. However, there are no general basic data available concerning gases generated from biodegradation of solid wastes in landfill sites. Specifically, no assessment has been made concerning greenhouse effect gases from different landfill types.

This paper proposes a quantitative model for estimating the gasification rate by different landfill types. The model is based on measurement data for a long-term material balance for an aerobic landfill and an anaerobic landfill, obtained with two types of large-scale lysimeters.

This paper will also give an estimate for the amount of greenhouse effect gases by for different types of landfill and propose countermeasures for their reduction.