Oolithische Strukturen in Pyriten des Ventersdorp-Contact-Reefs,Südafrika

Zusammenfassung Oolithische Strukturen in Pyriten des Ventersdorp-Contact-Reefs im Witwatersrand Gebiet, die bisher als radial pyrites beschrieben wurden, zeigen eine starke Ähnlichkeit zu Eisenoolithen der Pretoria Serie des Transvaal Systems. Letztere wurden bereits als primäre Strukturen gedeutet, an deren Bildung Algen wahrscheinlich wesentlich beteiligt waren. Die Verfasser sind der Ansicht, daß sowohl der authigene Kohlenstoff im Ventersdorp- und Witwatersrand System als auch die oolithischen Strukturen in Pyriten des Ventersdorp-Contact-Reefs wahrscheinlich Überbleibsel von primitiven Organismen darstellen, die vor rund 2750×10⁶ Jahren im Sedimentationsbecken des Witwatersrand Systems existierten.

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Oölitic textures present in pyrites of the Ventersdorp Contact Reef at Venterspost Gold Mine, South Africa, which have previously been described as radial pyrites strongly resemble iron oöliths of the Pretoria Series of the Transvaal System. The latter have been considered to be primary textures; a causative connection was believed to have existed between primitive organic life and the formation of these oöliths and related textures. It is suggested that both the authigenic carbonaceous material present in the Ventersdorp- and Witwatersrand Systems and the oölitic textures shown by the pyrite in the Ventersdorp Contact Reef probably represent relicts of an early form of life which existed in the sedimentary basin of the Witwatersrand System some 2,750 × 10⁶ years ago.

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Résumé Les textures oolitiques dans les pyrites du Ventersdorp-Contact-Reef dans la région du Witwatersrand, étant dénommées jusqu'ici «radial pyrites», nous montre une affinité très forte avec oolites ferriques de la série Prétoria du système Transvaal. On a déjà interprété les derniers comme textures primaires; probablement alginite. Suivant l'opinion des auteurs, non seulement le carbone authigène dans le système Ventersdorp et Witwatersrand mais encore les textures oolitiques dans les pyrites du Ventersdorp-Contact-Reef sont probablement des restes des organismes primitifs, ayant existés dans le bassin sédimentaire du système Witwatersrand il y a 2750×10⁶ années.

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Geology,petrography, and petrology of Pinzon Island,galapagos archipelago

Three stratigraphic units based on geologic relationships and paleomagnetic observations may be distinguished on Pinzon Island. The oldest unit is a broad shield which forms the main body of the island and was erupted during a period of reversed magnetic polarity from an area now occupied by a caldera. Subsequent activity was centered about 1.5 km to the north-northwest from vents later engulfed by the collapse of a younger caldera. The lower portion of this sequence was erupted during a period of transitional pole positions and is overlain by flows of normal polarity. Pinzon has the most diverse suite of differentiated tholeiitic rocks found in the Galapagos Archipelago. Products of eruptive cycles are preserved as sequences of tuffs and flows that have decreasing degrees of differentiation and increasing phenocryst abundance upsection. The sequences may be a consequence of tapping successively deeper levels of compositionally zoned magma chambers. Such a model is consistent with computer calculations utilizing major and trace element data for Pinzon rocks, which suggest that lavas of the island may be related by shallow-level crystal fractionation of observed phenocryst minerals.     

Über die Bildungsbereiche mediterraner Jurasedimente am Beispiel der Betischen Kordillere (Südost-Spanien)

Zusammenfassung In der Betischen Kordillere sind die Lagerungsbeziehungen der Faziestypen des mediterranen Juras sehr gut erschlossen. Aus Geländebeobachtungen und sedimentologischen Untersuchungen ergab sich die Hypothese, daß das Entstehen derartiger Faziestypen in erster Linie von den morphologischen Verhältnissen am Meeresboden abhängt; die Wassertiefe wirkt sich nur mittelbar aus. Veränderungen der submarinen Land schaft und damit auch Fazieswechsel wurden hauptsächlich durch bruchtektonische Vorgänge hervorgerufen. Eine verhältnismäßig klare paläogeographische Gliederung erhält man im Bereich der pelagischen Schwellen, deren Ablagerungen normalerweise sehr starke diagenetische Veränderungen erfahren haben. Hierbei fällt den roten Knollenkalken (Ammonitico rosso-Fazies) eine Schlüsselrolle zu.

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Due to large scale exposures in the Betic Cordilleras, it is possible there to study the interrelations of mediterranean Jurassic facies types. Field work and sedimentological investigations resulted in the hypothesis, that the origin of a facies type depends in the first place on submarine morphological settings; water depth bears only secondary influence. Changes in submarine morphology were controled by faulting. A detailed paleography can be obtained on the seamont areas, where sediments were normally affected by important diagenetic alterations. A key role, in this connection, must be attributed to red nodular limestones.

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Résumé Dans les Cordillères Bétiques, les relations entre les différents types de facies du Jurassique méditerranéen sont bien exposées. Des investigations sédimentologiques, complétées d'observations de terrain, conduisent à cette hypothèse que ces types de facies dépendent en premier lieu des relations morphologiques au sein du fond marin; la profondeur de l'eau n'a qu'une influence indirecte. Pendant le Jurassique, les changements morphologiques du fond marin, et avec eux les modifications de faciès ont été induits par une tectonique de failles radiales. Généralement, les sédiments des seuils pélagiques sont affectés par des altérations diagénétiques bien marquées, il est donc possible d'en déduire une paléogéographie bien détaillée. Dans ce contexte, on doit attribuer un rôle-clef aux calcaires noduleux rouges (faciès »Ammonitico rosso«).

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Gefügeregelung und elastische Anisotropie eines Marmors

Petrofabric analyses by means of the X-ray diffraotometer and ultrasonic measurements were made on a sample of marble from the Austrian Alps. The marble represents a B-tectonite with concentration of calcite crystallographic a axes subparallel to B-lineation and a girdle of c axes. The elastic longitutinal wave propagation is controlled to a large extent by the marble fabric. Parallel to the a axes maximum the longitudinal wave velovity propagation is high (v _p=6,82 km/sec). For propagation normal to the a axes maximum (parallel to c axes concentration) wave velocities are low (v _p min=6,17 km/sec). The results are qualitatively consistent with single crystal data (v _p‖ a=7,25 km/sec; v _p ‖ c=5,62 km/sec).     

Struktur und Polymorphie des Eukryptits (Tief-LiAlSiO4). (Betrachtungen zur Polymorphie II.)

Ohne ZusammenfassungHerrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet.     

Stabilitätsbeziehungen zwischen Chlorit,Cordierit und Almandin bei der Metamorphose

The stability relations between cordierite and almandite in rocks, having a composition of CaO poor argillaceous rocks, were experimentally investigated. The starting material consisted of a mixture of chlorite, muscovite, and quartz. Systems with widely varying Fe²⁺/Fe²⁺+Mg ratios were investigated by using two different chlorites, thuringite or ripidolite, in the starting mixture. Cordierite is formed according to the following reaction: $${\text{Chlorite + muscovite + quartz}} \rightleftharpoons {\text{cordierite + biotite + Al}}_{\text{2}} {\text{SiO}}_{\text{5}} + {\text{H}}_{\text{2}} {\text{O}}$$ . At low pressures this reaction characterizes the facies boundary between the albite-epidotehornfels facies and the hornblende-hornfels facies, at medium pressures the beginning of the cordierite-amphibolite facies. Experiments were carried out reversibly and gave the following equilibrium data: 505±10°C at 500 bars H₂O pressure, 513±10°C at 1000 bars H₂O pressure, 527±10°C at 2000 bars H₂O pressure, and 557±10°C at 4000 bars H₂O pressure. These equilibrium data are valid for the Fe-rich starting material, using thuringite as the chlorite, as well as for the Mg-rich starting mixture with ripidolite. At 6000 bars the equilibrium temperature for the Mg-rich mixture is 587±10°C. In the Fe-rich mixture almandite was formed instead of cordierite at 6000 bars. The following reaction was observed: $${\text{Thuringite + muscovite + quartz}} \rightleftharpoons {\text{almandite + biotite + Al}}_{\text{2}} {\text{SiO}}_{\text{5}} {\text{ + H}}_{\text{2}} {\text{O}}$$ . Experiments with the Fe-rich mixture, containing Fe²⁺/Fe²⁺+Mg in the ratio 8∶10, yielded three stability fields in a P,T-diagram (Fig.1):

1. Above 600°C/5.25 kb and 700°C/6.5 kb almandite+biotite+Al₂SiO₅ coexist stably, cordierite being unstable.
2. The field, in which almandite, biotite and Al₂SiO₅ are stable together with cordierite, is restricted by two curves, passing through the following points:
   1. 625°C/5.5 kb and 700°C/6.5 kb,
   2. 625°C/5.5 kb and 700°C/4.0 kb.
3. At conditions below curves 1 and 2b, cordierite, biotite, and Al₂SiO₅ are formed, but no garnet.

An appreciable MnO-content in the system lowers the pressures needed for the formation of almandite garnet, but the quantitative influence of the spessartite-component on the formation of almandite could not yet be determined. the Mg-rich system with Fe²⁺/Fe²⁺+Mg=0.4 garnet did not form at pressures up to 7 kb in the temperature range investigated. Experiments at unspecified higher pressures (in a simple squeezer-type apparatus) yielded the reaction: $${\text{Ripidolite + muscovite + quartz}} \rightleftharpoons {\text{almandite + biotite + Al}}_{\text{2}} {\text{SiO}}_{\text{5}} {\text{ + H}}_{\text{2}} {\text{O}}$$ . Further experiments are needed to determine the equilibrium data. The occurence of garnet in metamorphic rocks is discussed in the light of the experimental results.     

Anthophyllit und Hornblende in einigen metamorphen Reaktionen

Reactions which occur at the lower boundary of the hornblende-hornfels facies and in the so-called pyroxene-hornfels facies were experimentally investigated for an ultrabasic rock at 500, 1000 and 2000 bars H₂O pressure.The starting material used was a mixture of natural chlorite, talc, tremolite and quartz such that its composition, except for surplus quartz, corresponded to that of an ultrabasic rock. The atomic ratio Fe²⁺+Fe²⁺/Mg+Fe³⁺+Fe³⁺ in the system was 0.16.The lower boundary of the hornblende-hornfels facies was defined by the formation of the orthorhombic amphibole anthophyllite and hornblende according to the following idealized reaction: chlorite+talc+tremolite+quartz hornblende+anthophyllite+H₂O In effect, this reaction consists of the two bivariant reactions: chlorite+tremolite+quartz hornblende+anthophyllite+H₂O talc+chlorite anthophyllite+quartz+H₂OThe equilibrium temperatures obtained for the two reactions in the given system are practically the same and are as follows: 535±10°C at 500 bars H₂O pressure 550±20°C at 1000 bars H₂O pressure 560±10°C at 2000 bars H₂O pressure 580±10°C at 4000 bars H₂O pressureAt 2000 bars and higher temperatures within the hornblende-hornfels facies, anorthite is formed in addition to hornblende and anthophyllite, probably according to the following reaction: hornblende₁+quartz hornblende₂+anthophyllite+anorthite+H₂O; because of the formation of anorthite it is to be expected that the hornblende in this case is poorer in aluminium than the hornblende at 500 and 1000 bars. Winkler (1967) suggests renaming the pyroxene-hornfels facies as K-feldspar-cordierite-hornfels facies which, in turn, is subdivided into a lower-temperature orthoamphibole subfacies without orthopyroxene and a higher-temperature orthopyroxene subfacies without orthoamphibole. The orthopyroxene subfacies itself may in its lower temperature part still carry hornblende which finally disappears in the higher temperature part.The appearance of orthopyroxene characterizes the transition from the orthoamphibole to the orthopyroxene subfacies of the K-feldspar-cordierite hornfels facies. The following reaction takes place at pressures lower than 2000 bars: hornblende₁+anthophyllite hornblende₂+enstatite+anorthite+H₂OSince at 2000 bars an Al-poor hornblende already exists in the hornblende-hornfels facies, it is very likely that here only anthophyllite breaks down to give enstatite+quartz+H₂O.The equilibrium temperatures for these reactions which give rise to enstatite are: 650±10°C at 250 bars H₂O pressure 690±10°C at 500 bars H₂O pressure 715±10°C at 1000 bars H₂O pressure 770±10°C at 2000 bars H₂O pressureOnly after an increase in temperature to about 710°C at 500 bars and about 770°C at 1000 bars does hornblende in the system investigated here break down completely according to the reaction: hornblende = enstatite+anorthite+diopside+H₂OExcept at very small H₂O-pressures (see Fig. 3), there exists, therefore, a region within the orthopyroxene subfacies where hornblende, enstatite and anorthite coexist. As a result we have, as mentioned above, a lower-temperature and a higher-temperature part of the orthopyroxene subfacies, and it is only in the latter part that the parageneses correspond to the pyroxene-hornfels facies as stated by Eskola (1939).Summing up, the starting material consisting of chlorite, talc, tremolite plus quartz remains unchanged in the albite-epidote-hornfels facies; this gives rise in the hornblende-hornfels facies to the paragenesis hornblende+anthophyllite, or — at higher pressures — to hornblende+anthophyllite+anorthite. For the particular composition of the starting material, however, no reactions take place at the transition of the hornblende-hornfels facies to the orthoamphibole subfacies of the K-feldspar-cordierite-hornfels facies as this transition is typified by the breakdown of muscovite in the presence of quartz. However, at the end of the orthoamphibole subfacies the breakdown of anthophyllite, by which orthopyroxene is formed, heralds the onset of the orthopyroxene subfacies. In this subfacies — at greater than about 300 bars — hornblende is still present and coexists with enstatite and anorthite, but with rising temperature hornblende breaks down to give way to the paragenesis enstatite+anorthite+diopside. The experimentally determined parageneses confirm known petrographic occurrences.

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Für die Förderung dieser Arbeit danken wir der Deutschen Forschungsgemeinschaft vielmals. Der Dank von Choudhuri gilt dem Akademischen Auslandsamt der Universität Göttingen für ein Stipendium, das ihm den Abschluß seiner Studien an der Universität Göttingen ermöglichte.     

Shock-induced mechanical deformations in biotites from crystalline rocks of the ries crater (Southern Germany)

Mechanical deformation features in shocked biotites from crystalline rocks of the Ries crater are: kink bands, planar elements, and plastic lattice deformations as determined by X-ray investigations.Kink bands can be observed in micas of various pressure histories (stages 0, I, II and less frequently stage III of shock metamorphism). Kink bands in shocked micas are less symmetrical than kinks of static origin. Asymmetry increases with increasing dynamic pressures. Moreover, kink band width is sensitive against changing peak pressures. Distribution of kinked and undistorted micas within a rock permits to fix the shock front direction. Shock-induced kinks in micas are produced by various gliding processes in the cleavage plane (001).Planar elements seldom occur in biotites of shock stages II and III and have never been described in endogenic rocks. Up to now orientations of planar elements parallel to (111), (1¯11), (112) and (11¯2) have been determined. Planar elements are interpreted as planes of plastic lattice gliding. {[110]} is supposed to be the main gliding direction. In the same pressure region other plastic lattice deformations have been determined. They are orientated parallel to (001), (100) and (¯132) or (201) which results from single crystal X-ray investigations and may represent planes of plastic lattice gliding. The dependency of formation of gliding planes and gliding directions on increasing dynamic pressures will be discussed.