Center-to-limb analysis of the solar oxygen lines

Several lines of neutral oxygen observed at various positions on the solar disk were used to study the influence of (1) the temperature distribution, (2) the velocity field, and (3) the damping on the line profiles and the abundance of oxygen in the photosphere. Theoretical profiles were calculated on the basis of four different model atmospheres in LTE. It was found that the model proposed by Holweger (1967) best reproduced the center-to-limb observations of the lines studied. The weighted mean of the oxygen abundance turned out to be log _O = 8.83 on the basis of log _H = 12.00.     

A new scenario framework for Climate Change Research: scenario matrix architecture

This paper describes the scenario matrix architecture that underlies a framework for developing new scenarios for climate change research. The matrix architecture facilitates addressing key questions related to current climate research and policy-making: identifying the effectiveness of different adaptation and mitigation strategies (in terms of their costs, risks and other consequences) and the possible trade-offs and synergies. The two main axes of the matrix are: 1) the level of radiative forcing of the climate system (as characterised by the representative concentration pathways) and 2) a set of alternative plausible trajectories of future global development (described as shared socio-economic pathways). The matrix can be used to guide scenario development at different scales. It can also be used as a heuristic tool for classifying new and existing scenarios for assessment. Key elements of the architecture, in particular the shared socio-economic pathways and shared policy assumptions (devices for incorporating explicit mitigation and adaptation policies), are elaborated in other papers in this special issue.     

CBDR&RC in a regime applicable to all

The principle of common, but differentiated, responsibilities and respective capabilities (CBDR&RC) is fundamental to the UNFCCC. Some options for a nuanced model of differentiation that addresses both responsibility and capability in a changing world are explored, such as new categories of countries, and some of the political issues that such a model might face are considered. The strengths and limitations of options for graduation based on ‘objective’ criteria such that countries could move between categories or ‘graduate’ – an option provided by the UNFCCC – are discussed. Countries could also choose to join another club (e.g. the G20), self-elect into categories or differentiate among themselves implicitly by accepting different commitments and actions. CBDR&RC will form part of the overall legally binding agreement, and must apply symmetry in some respects and differentiation in others to the commitments and actions contained therein. Some possible characteristics of CBDR&RC of relevance in a regime ‘applicable to all’ are outlined. These include promoting climate action and using mechanisms available in the UNFCCC to instil dynamism. Differentiation on mitigation must consider the distinctions between absolute and relative reductions, as well as commitments to outcomes and implementation. CBDR&RC should be applied to mitigation, adaptation, and the means of implementation.

Policy relevance

In Durban, Parties agreed to negotiate a regime ‘applicable to all’, which sent a political signal that there should be greater symmetry between nations. The world has changed since the UNFCCC was negotiated in 1992. It is now less helpful to think only in terms of two groups of countries (e.g. Annex I and non-Annex I), and evident that there are significant differences between member states. This requires a more nuanced interpretation of the principles of equity and CBDR&RC, which is an integral part of the UNFCCC. The options for the different approaches outlined in this article might help in the construction of a more nuanced model. All must do more, while some must do more still than others. To achieve this, some defining characteristics of CBDR&RC in a regime applicable to all are suggested.     

Schmidt hammer exposure‐age dating (SHD) of late Quaternary fluvial terraces in New Zealand

Schmidt hammer (SH) R‐values are reported for surface clasts from numerically dated Holocene and Pleistocene fluvial terraces in the South Island of New Zealand. The R‐values are combined with previously obtained weathering rind, radiocarbon, terrestrial cosmogenic nuclide and luminescence terrace ages to derive SH R‐value chronofunctions for greywacke clasts from four distinct locations. Our results show that different weathering rates affect the form of the SH R‐value versus Age curve, however a fundamental dependency between the two remains constant over timescales ranging from 10² to 10⁵ years. Power law scaling constants suggest changes in clast weathering rates are primarily affected by climatic (precipitation and temperature) and sedimentologic variables (source terrane petrology). Age uncertainties of ~22% of the surface age suggest that Schmidt hammer exposure‐age dating (SHD) is a reliable calibrated‐age dating technique for fluvial terraces. Copyright © 2013 John Wiley & Sons, Ltd.     

Comparison of electronic and mechanical Schmidt hammers in the context of exposure‐age dating: are Q‐ and R‐values interconvertible?

Application of Schmidt‐hammer exposure‐age dating (SHD) to landforms has substantially increased in recent years. The original mechanical Schmidt hammer records R‐(rebound) values. Although the newly introduced electronic Schmidt hammer (SilverSchmidt) facilitates greatly improved data processing, it measures surface hardness differently, recording Q‐(velocity) values that are not a priori interconvertible with R‐values. This study is the first to compare the performance of both instruments in the context of field‐based exposure‐age dating with a particular focus on the interconvertibility of R‐values and Q‐values. The study was conducted on glacially polished pyroxene‐granulite gneiss, Jotunheimen, southern Norway. Results indicate that mean Q‐values are consistently 8–10 units higher than mean R‐values over the range of values normally encountered in the application of SHD to glacial and periglacial landforms. A convenient conversion factor of ±10 units may, therefore, be appropriate for all but the softest rock types close to the technical resolution of the instruments. The electronic Schmidt hammer should therefore be regarded as a useful complement and potential replacement for the mechanical Schmidt hammer. Conversion of published R‐values data to Q‐values requires, however, careful control and documentation of instrument calibration. Copyright © 2014 John Wiley & Sons, Ltd.     

A conceptual framework for multi-regional climate change assessments for international market systems with long-term investments

A conceptual framework for climate change assessments of international market systems that involve long-term investments is proposed. The framework is a hybrid of dynamic and static modeling. Dynamic modeling is used for those system components for which temporally continuous modeling is possible, while fixed time slices are used for other system components where it can be assumed that underlying assumptions are held constant within the time slices but allowed to vary between slices. An important component of the framework is the assessment of the “metauncertainty” arising from the structural uncertainties of a linked sequence of climate, production, trade and decision-making models. The impetus for proposing the framework is the paucity of industry-wide assessments for market systems with multiple production regions and long-term capital investments that are vulnerable to climate variations and change, especially climate extremes. The proposed framework is pragmatic, eschewing the ideal for the tractable. Even so, numerous implementation challenges are expected, which are illustrated using an example industry. The conceptual framework is offered as a starting point for further discussions of strategies and approaches for climate change impact, vulnerability and adaptation assessments for international market systems.     

Condensation particle counting below 2 nm seed particle diameter and the transition from heterogeneous to homogeneous nucleation

Particle detection by condensation particle counters (CPCs) is ultimately limited by the onset of homogeneous nucleation. At vapour supersaturations around the homogeneous nucleation limit the diameter of critical clusters is typically about 2 nm. It is widely assumed that only particles larger than critical clusters can be activated by vapour condensation and the general detection limit of CPCs is therefore currently accepted to be around 2 nm particle diameter. Using an expansion type CPC with n-propanol as working fluid we investigated the transition from heterogeneous to homogeneous nucleation, clearly showing that particles are activated much before the onset of homogeneous nucleation, even at particle diameters as small as 1.4 nm. For particle diameters below 2 nm we have usually found condensation particle counting to be influenced by the simultaneous presence of ions as generated in a bipolar diffusion charger. In this paper we illustrate how the presence of ions influences particle number concentration measurement and how ions can be removed in order to obtain accurate seed particle number concentrations for particle diameters down to 1 nm.     

First attempt to combine terrestrial cosmogenic nuclide (10Be) and Schmidt hammer relative-age dating: Strauchon Glacier, Southern Alps, New Zealand

This study provides the first attempt to combine terrestrial (in situ) cosmogenic nuclide (¹⁰Be) surface exposure dating with Schmidt hammer relative-age dating for the age estimation of Holocene moraines at Strauchon Glacier, Southern Alps, New Zealand. Numerous Schmidt hammer tests enable a multi-ridged lateral moraine system to be related to three late-Holocene ‘Little Ice Age’-type events. On the basis of cosmogenic ¹⁰Be ages, those events are dated to c. 2400, 1700, and 1100 years ago. Linear age-calibration curves are constructed in order to relate Schmidt hammer R-values to cosmogenic ¹⁰Be ages. The high explanation yielded reveals the causal link between both data sets. The potential of combining both methods in a ‘’multiproxy approach’ is discussed alongside possible future improvements. Terrestrial cosmogenic nuclide dating delivers absolute ages needed as fixed points for Schmidt hammer age-calibration curves. The Schmidt hammer technique can be used to crosscheck the boulder surfaces chosen for surface exposure dating by terrestrial cosmogenic nuclides. It should, therefore, reduce the number of samples necessary and costs.