Surface and deep water response to rapid climate changes at the Western Iberian Margin

Rapid climate changes at the onset of the last deglaciation and during Heinrich Event H4 were studied in detail at IMAGES cores MD95-2039 and MD95-2040 from the Western Iberian margin. A major reorganisation of surface water hydrography, benthic foraminiferal community structure, and deepwater isotopic composition commenced already 540 years before the Last Isotopic Maximum (LIM) at 17.43 cal. ka and within 670 years affected all environments. Changes were initiated by meltwater spill in the Nordic Seas and northern North Atlantic that commenced 100 years before concomitant changes were felt off western Iberia. Benthic foraminiferal associations record the drawdown of deepwater oxygenation during meltwater and subsequent Heinrich Events H1 and H4 with a bloom of dysoxic species. At a water depth of 3380 m, benthic oxygen isotopes depict the influence of brines from sea ice formation during ice-rafting pulses and meltwater spill. The brines conceivably were a source of ventilation and provided oxygen to the deeper water masses. Some if not most of the lower deep water came from the South Atlantic. Benthic foraminiferal assemblages display a multi-centennial, approximately 300-year periodicity of oxygen supply at 2470-m water depth. This pattern suggests a probable influence of atmospheric oscillations on the thermohaline convection with frequencies similar to Holocene climate variations. For Heinrich Events H1 and H4, response times of surface water properties off western Iberia to meltwater injection to the Nordic Seas were extremely short, in the range of a few decades only. The ensuing reduction of deepwater ventilation commenced within 500–600 years after the first onset of meltwater spill. These fast temporal responses lend credence to numerical simulations that indicate ocean–climate responses on similar and even faster time scales.     

Assessment of the management of organizations supplying ecosystem services from tropical forests

Global environmental change leads to degradation of tropical forests in many countries. In response to this pressure, programs for payments for ecosystem services (PES) are developing and organizations are emerging which manage forests in order to supply ecosystem services, rather than only harvest timber. Typically such services are carbon sequestration, biodiversity conservation, pollination, and watershed protection. Public or private actors interested to invest in or donate money for the provisioning of such services are faced with the problem of choosing the appropriate organization supplying ecosystem services. The goal of this paper was to develop an assessment framework based on the balanced scorecard concept including drivers, impact, performance and context variables. Results of a survey of international market actors were used to determine assessment criteria and their weights. Putting the focus of this paper on drivers and impacts, we assessed Latin American organizations that “sell” ecosystem services from tropical forests in terms of their general management, marketing, forest management, client and stakeholder satisfaction, and forest ecosystem status. We found that supplying organizations vary widely with respect to their achievements in these areas. However, the variance of assessment results is influenced even more by the variance in weights the international market actors allocate to the assessment criteria. The insights of this study can contribute to the continuous improvement of management processes in supplying organizations and can support investors and donors in their decision-making with respect to organization supplying ecosystem services.     

Defining organominerals: Comment on ‘Defining biominerals and organominerals: Direct and indirect indicators of life’ by Perry et al. (2007, Sedimentary Geology, 201, 157–179)

The paper by Perry et al. (2007, Defining biominerals and organominerals: Direct and indirect indicators of life, Sedimentary Geology, 201, 157–179) proposes to introduce “the new term ‘organomineral’” to describe mineral products whose formation is induced by by-products of biological activity, dead and decaying organisms, or nonbiological organic compounds, to be distinguished from the biomineral components of living organisms. The substantive ‘organomineral’, however, is not new: it was first introduced in 1993, with basically the same definition and distinction from biominerals, at the 7th International Symposium on Biomineralization (Défarge and Trichet, 1995, From biominerals to ‘organominerals’: The example of the modern lacustrine calcareous stromatolites from Polynesian atolls, Bulletin de l'Institut Océanographique de Monaco, n° spéc. 14, vol. 2, pp. 265–271). Thereafter, more than twenty-five papers by various authors have been devoted to organominerals and organomineral formation (‘organomineralization’) processes. Only two of these papers are cited by Perry et al., and without any reference to the definitions, or even the terms ‘organomineral’ or ‘organomineralization’, which they included. Moreover, Perry et al. tend to enlarge the original concept of organomineral to encompass all minerals containing organic matter, whether these organic compounds are active or passive in the mineralization, which introduces ambiguities detrimental to a fine understanding of present and past geobiological processes. Finally, Perry et al. propose to consider organominerals as indirect biosignatures that could be used in the search for evidence of life in the geological record and extraterrestrial bodies. This latter proposition also is problematical, in that organominerals may be formed in association with prebiotic or abiotic organic matter.     

‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.     

The impact of shale gas on the costs of climate policy

The use of shale gas is commonly considered as a low-cost option for meeting ambitious climate policy targets. This article explores global and country-specific effects of increasing global shale gas exploitation on the energy markets, on greenhouse gas emissions, and on mitigation costs. The global techno-economic partial equilibrium model POLES (Prospective Outlook on Long-term Energy Systems) is employed to compare policies which limit global warming to 2°C and baseline scenarios when the availability of shale gas is either high or low. According to the simulation results, a high availability of shale gas has rather small effects on the costs of meeting climate targets in the medium and long term. In the long term, a higher availability of shale gas increases baseline emissions of greenhouse gases for most countries and for the world, and leads to higher compliance costs for most, but not all, countries. Allowing for global trading of emission certificates does not alter these general results. In sum, these findings cast doubt on shale gas’s potential as a low-cost option for meeting ambitious global climate targets.

POLICY RELEVANCE

Many countries with a large shale gas resource base consider the expansion of local shale gas extraction as an option to reduce their GHG emissions. The findings in this article imply that a higher availability of shale gas in these countries might actually increase emissions and mitigation costs for these countries and also for the world. An increase in shale gas extraction may spur a switch from coal to gas electricity generation, thus lowering emissions. At the global level and for many countries, though, this effect is more than offset by a crowding out of renewable and nuclear energy carriers, and by lower energy prices, leading to higher emissions and higher mitigation costs in turn. These findings would warrant a re-evaluation of the climate strategy in most countries relying on the exploitation of shale gas to meet their climate targets.     

Mixing and chemical interdiffusion of trachytic and latitic magma in a subvolcanic complex of the Tertiary Westerwald (Germany)

A special kind of magma mixing is extraordinarily well exposed in the Bittersberg subvolcanic complex in the Tertiary volcanic field of the German Westerwald: A trachytic melt has been penetrated by a latitic dyke which has been dispersed within the host magma as small spherical enclaves (globules). Whole rock analyses of the globules show a change in composition that cannot be explained by a simple mechanical mixing between the endmembers. The most evolved globules have a phonolitic composition. Microprobe measurements in the microlithic matrix of the host rock and the guest indicate a diffusive motion of the alkalis from the host into the globules. On the other hand, an opposite trend can be observed for Ca, Mg, Fe and Ti, which are impoverished in the globules. The trace elements and the middle rare earth elements (MREE) has also been involved in the diffusive exchange. The REE-pattern of the most evolved (phonolitic) globules shows a characteristic trough in the area of the MREE which is almost identical to the REE-pattern of many phonolites. The phonolites and the alkali-rich trachytes of the Westerwald show similar globular textures as the Bittersberg volcanics. Therefore, generation of these rocks involving diffusive element exchange during mixing processes in a magma reservoir situated on a deeper crustal level may be possible.     

Location and probability of shoal margin collapses in a sandy estuary

Channel bank failure, and collapses of shoal margins and beaches due to flow slides, have been recorded in Dutch estuaries for the past 200 years but have hardly been recognized elsewhere. Current predictions lack forecasting capabilities, because they were validated and calibrated for historic data of cross‐sections in specific systems, allowing local hindcast rather than location and probability forecasting. The objectives of this study were to investigate where on shoal margins collapses typically occur and what shoal margin collapse geometries and volumes are, such that we can predict their occurrence. We identified shoal margin collapses, generally completely submerged, from bathymetry data by analyzing digital elevation models of difference of the Western Scheldt for the period 1959–2015. We used the bathymetry data to determine the conditions for occurrence, specifically to obtain slope height and angle, and applied these variables in a shoal margin collapse predictor. We found 299 collapses along 300 km of shoal margin boundaries over 56 years, meaning that more than five collapses occur on average per year. The average shoal margin collapse body is well approximated by a 1/3 ellipsoid shape, covers on average an area of 34 000 m² and has an average volume of 100 000 m³. Shoal margin collapses occur mainly at locations where shoals take up a proportionally larger area than average in the cross‐section of the entire estuary, and occur most frequently where lateral shoal margin displacement is low. A receiver operating characteristic curve shows that the forecasting method predicts the shoal margin collapse location well. We conclude that the locations of the shoal margin collapses are well predicted by the variation in conditions of the relative slope height and angle within the Western Scheldt, and likely locations are at laterally relatively stable shoal margins. This provides hypotheses aiding the recognition of these features in sandy estuaries worldwide. Copyright © 2018 John Wiley & Sons, Ltd.