Dynamic stream network intermittence explains emergent dissolved organic carbon chemostasis in headwaters

Dissolved organic carbon (DOC) concentrations vary among headwaters, with variation typically decreasing with watershed area. We hypothesized that streamflow intermittence could be an important source of variation in DOC concentrations across a small watershed, through (a) temporal legacies of drying on organic matter accumulation and biotic communities and (b) spatial patterns of connectivity with DOC sources. To test these hypotheses, we conducted three synoptic water chemistry sampling campaigns across a 25.5‐km² watershed in south‐eastern Idaho during early spring, late summer, and late fall. Using changepoint analysis, we found that DOC variability collapsed at a consistent location (watershed areas ~1.3 to ~1.8 km²) across seasons, which coincided with the watershed area where variability in streamflow intermittence collapsed (~1.5 km²). To test hypothesized mechanisms through which intermittence may affect DOC, we developed temporal, spatial, and spatio‐temporal metrics of streamflow intermittence and related these to DOC concentrations. Streamflow intermittence was a strong predictor of DOC across seasons, but different metrics predicted DOC depending on season. Seasonal changes in the effects of intermittence on DOC reflected seasonal changes from instream to flowpath controls. A metric that captured spatial connectivity to sources significantly predicted DOC during high flows, when DOC is typically controlled by transport. In contrast, a reach‐scale temporal metric of intermittence predicted DOC during the late growing season, when DOC is typically controlled by instream processes and when legacy effects of drying (e.g., diminished biological communities) would likely affect DOC. The effects of intermittence on DOC extend beyond temporal legacies at a point. Our results suggest that legacy effects of intermittence do not propagate downstream in this system. Instead, snapshots of spatial patterns of intermittence upstream of a reach are critical for understanding spatial patterns of DOC through connectivity to DOC sources, and these processes drive patterns of DOC even in perennial reaches.     

Mapping of prospectivity and estimation of number of undiscovered prospects for lode gold,southwestern Ashanti Belt,Ghana

In the southwestern part of the Ashanti Belt, the results of fractal and Fry analyses of the spatial pattern of 51 known mines/prospects of (mostly lode) gold deposits and the results of analysis of their spatial associations with faults and fault intersections suggest different predominant structural controls on lode gold mineralisation at local and district scales. Intersections of NNE- and NW-trending faults were likely predominantly involved in local-scale structural controls on lode gold mineralisation, whilst NNE-trending faults were likely predominantly involved in district-scale structural controls on lode gold mineralisation. The results of the spatial analyses facilitate the conceptualisation and selection of spatial evidence layers for lode gold prospectivity mapping in the study area. The applications of the derived map of lode gold prospectivity and a map of radial density of spatially coherent lode gold mines/prospects results in a one-level prediction of 37 undiscovered lode gold prospects. The applications of quantified radial density fractal dimensions of the spatial pattern of spatially coherent lode gold mines/prospects result in an estimate of 40 undiscovered lode gold prospects. The study concludes finally that analysis of the spatial pattern of discovered mineral deposits is the key to a strong link between mineral prospectivity mapping and assessment of undiscovered mineral deposits.     

Influence of groundwater and topography on stream drying in semi-arid headwater streams

Non-perennial streams comprise over half of the global stream network and impact downstream water quality. Although aridity is a primary driver of stream drying globally, surface flow permanence varies spatially and temporally within many headwater streams, suggesting that these complex drying patterns may be driven by topographic and subsurface factors. Indeed, these factors affect shallow groundwater flows in perennial systems, but there has been only limited characterisation of shallow groundwater residence times and groundwater contributions to intermittent streams. Here, we asked how groundwater residence times, shallow groundwater contributions to streamflow, and topography interact to control stream drying in headwater streams. We evaluated this overarching question in eight semi-arid headwater catchments based on surface flow observations during the low-flow period, coupled with tracer-based groundwater residence times. For one headwater catchment, we analysed stream drying during the seasonal flow recession and rewetting period using a sensor network that was interspersed between groundwater monitoring locations, and linked drying patterns to groundwater inputs and topography. We found a poor relationship between groundwater residence times and flowing network extent (R² < 0.24). Although groundwater residence times indicated that old groundwater was present in all headwater streams, surface drying also occurred in each of them, suggesting old, deep flowpaths are insufficient to sustain surface flows. Indeed, the timing of stream drying at any given point typically coincided with a decrease in the contribution from near-surface sources and an increased relative contribution of groundwater to streamflow at that location, whereas the spatial pattern of drying within the stream network typically correlated with locations where groundwater inputs were most seasonally variable. Topographic metrics only explained ~30% of the variability in seasonal flow permanence, and surprisingly, we found no correlation with seasonal drying and down-valley subsurface storage area. Because we found complex spatial patterns, future studies should pair dense spatial observations of subsurface properties, such as hydraulic conductivity and transmissivity, to observations of seasonal flow permanence.     

Geologically Constrained Fuzzy Mapping of Gold Mineralization Potential,Baguio District,Philippines

An application of the theory of fuzzy sets to the mapping of gold mineralization potential in the Baguio gold mining district of the Philippines is described. Proximity to geological features is translated into fuzzy membership functions based upon qualitative and quantitative knowledge of spatial associations between known gold occurrences and geological features in the area. Fuzzy sets of favorable distances to geological features and favorable lithologic formations are combined using fuzzy logic as the inference engine. The data capture, map operations, and spatial data analyses are carried out using a geographic information system. The fuzzy predictive maps delineate at least 68% of the known gold occurrences that are used to generate the model. The fuzzy predictive maps delineate at least 76% of the unknown gold occurrences that are not used to generate the model. The results are highly comparable with the results of previous stream-sediment geochemical survey in the area. The results demonstrate the usefulness of a geologically constrained fuzzy set approach to map mineral potential and to redirect surficial exploration work in the search for yet undiscovered gold mineralization in the mining district. The method described is applicable to other mining districts elsewhere.     

Development of ecosystem indicators for the Suwannee River estuary: Oyster reef habitat quality along a salinity gradient

The Suwannee River watershed is one of the least developed in the eastern United States, but with increasing urbanization it is facing potential long-term alterations in freshwater flow to its estuary in the Gulf of Mexico. The purpose of this study was to develop biological indicators of oyster reef state along a natural salinity gradient in the Suwannee River estuary in order to allow the rapid assessment of the effect of changing freshwater input to this system. Percent cover and density of three size classes of living oysters, as well as the abundance of several predominant reef-associated invertebrates, were measured along a broad salinity gradient in the estuary and were correlated with salinity estimates from a long-term database for the preceding 12–24 mo. All eastern oyster,Crassostrea virginica, parameters (percent cover and density of three size classes) were significantly and negatively related to salinity. Data from samples collected near the lower intertidal were more closely dependent upon salinity than were samples from the higher intertidal at the same sites. Salinity differences were most closely reflected in differences in total oyster cover. This relationship corresponded with a general decline in oyster habitat with increasing distance from the mouth of the Suwannee River. Species richness was significantly and positively correlated with allC. virginica parameters (percent cover and density of three size classes), but the relationship explained only about half the variability. Density data of the hooked mussel,Ischadium recurvum, and a mud crab,Eurypanopeus depressus, were positively and strongly correlated withC. virginica parameters, likely reflecting the abundance of habitat provided byC. virginica shells. All of the biological indicators measured responded similarly along the salinity gradient, indicating they provide reliable indices of the effect of changing salinities in the Suwannee River estuary over the previous 1 or 2 yr. Some areas of positive relief defined as reefs 30 years ago are no longer oyster habitat, suggesting an ongoing decline, but nearshoreC. virginica were abundant. *** DIRECT SUPPORT *** A02BY003 00002     

A Klovan-type box corer for use with SCUBA

A stainless steel, Klovan-type box corer for use by SCUBA divers in shallow water has been developed. Details for construction of the 0.45 × 0.30 × 0.20-m wedge-shaped corer are provided together with operational details. Excellent undisturbed samples have been collected from gravelly sands, sands, and muds at water depths ranging from 15 m to intertidal. The wet sand cores typically are treated in the field using an epoxy to obtain high-relief sediment peels.     

Soil air carbon dioxide and oxygen measurements as a guide to concealed mineralization in semi-arid and arid regions

The differences between the CO₂ and O₂ concentrations in soil air and atmospheric air have been measured where sulfide mineralization occurs beneath transported exotic overburden in semi-arid and arid areas of the USA, South West Africa (Namibia) and Saudi Arabia. These mineralizations are reflected near surface by anomalous levels of CO₂ and O₂ in soil air, whereas in most cases heavy-metal anomalies are absent. The normal background variability of CO₂ and O₂ in soil air falls with increasing aridity, and anomaly definition improves with increasing aridity. Thus soil air CO₂ and O₂ data are potentially useful in exploring for concealed mineralization, especially in regions with an arid climate or conspicuous dry season.     

Oxidation of titanomagnetites in mafic and felsic intrusive rocks

We report opaque mineralogical observations and magnetic properties of primary titanomagnetites in Tertiary submarine gabbros from DSDP, Legs 30 and 37 and in a late Archean, continental granitic pluton, the Shelley Lake granite. The titanomagnetites and silicates in all the submarine gabbros have been deuterically oxidized. There is no indication of subsequent low-temperature oxidation, although serpentization of olivines is pervasive in the deeper Leg 37 units. The Leg 30 samples, from a single thick sill, contain abundant coarse (≈100 μm) titanomagnetites with fully developed ilmenite exsolution lamellae. Curie temperatures are 515–550°C; there are no low Curie temperatures that would indicate surviving unoxidized titanomagnetite. The unserpentinized Leg 37 gabbros contain scarce opaques with pure magnetite Curie points that are barely resolvable microscopically; most occur as inclusions in pyroxene. In the Shelley Lake granite, on the other hand, many samples exhibit bimodal blocking-temperature spectra, with blocking temperature peaks at 250–300°C and 550–575°C. The low-blocking-temperature phase is unidentified. No pyrrhotite was seen in thin section. Optically homogeneous grains coexist with fully exsolved neighbours, but the electron microprobe indicates no titanium. The lamellae appear to be haematite, not ilmenite, and the primary composition of the opaques is pure magnetite. The oxidation state of the opaques is very inhomogeneous, even on a fine scale.     

Dispersion patterns of carbonyl sulphide above mineral deposits

Thermodynamic calculations and experiments in vitro have pointed to the potential value of carbonyl sulphide (COS) as a gaseous pathfinder for sulphide mineral deposits concealed beneath overburden. Convenient sampling and analytical techniques have, therefore, been developed for the determination of COS in overburden materials. In temperate regions, samples of soil are taken below the normal rooting depth of vegetation; in arid and semi-arid regions the surface microlayer is collected. The analytical procedure involves the selective thermal desorption of COS from the < 150 μm fraction of overburden materials and quantitative determination by a rapid gas chromatographic method.Field studies of surficial dispersion patterns of COS have been carried out in the vicinity of replacement-type Cu (-Zn) and porphyry Cu deposits in the southwestern U.S.A., meta-sedimentary Cu-Zn mineralization in Saudi Arabia, volcano-sedimentary polymetallic sulphides in South Africa and stratabound Pb-Zn mineralization in Ireland, and are described here. These deposits are covered by different types and various thicknesses of overburden material. Anomalous concentrations of COS occur in the overburden above all of these deposits. The anomalies tend to be of modest but satisfactory contrast and are in some instances discontinuous or patchy.Results indicate that COS may be used as a guide to concealed mineral deposits in a variety of geologic and physiographic settings. Significant anomalies can be recognized even where mineralization lies beneath more than 90 m of transported overburden.     

Monitoring Temporal Changes in Multivariate Classifications

Multivariate classifications have been used extensively to make inductive generalizations about place or objects under study. If classifications are dynamic, changing as the variables that define them change, then these generalizations and the policies and strategies based on these generalizations may not hold over time. This paper presents a replicable method for monitoring temporal changes in a classification at the structural and group levels. The method is then illustrated in an empirical example using longitudinal data that relate to the economies of a selected set of geographic areas.