The geochemistry of mercury in sedimentary rocks and soils in Pennsylvania

The mercury contents of 11 sandstone, 11 shale and 6 limestone samples from Pennsylvania average 7, 23 and 9 ppb Hg, respectively, which is lower than the values for sedimentary rocks reported in the literature. The differences may arise because many of the reported high values are from regions characterized by more mineralization and volcanism than is present in central Pennsylvania. The lowest values found for shale and sandstone in Pennsylvania (0.4 and 0.5 ppb Hg, respectively) are lower by an order of magnitude than the lowest previously reported values. The mercury content of sedimentary rocks varies markedly due to the effects of volcanism, organic material and sulfur in reducing environments, iron and manganese oxides in oxidizing environments, diagenesis, hydrothermal processes, and the thermal history of the rock.Soils in Pennsylvania have much greater amounts of mercury than their parent rocks even after taking into account possible residual concentration, suggesting that mercury is added to the soils from an outside source. Rain is the major source of mercury absorbed by the soil. A portion of the absorbed mercury returns to the atmosphere, establishing a rain-soil-atmosphere mercury cycle. The general enrichment of mercury in soils and sediments compared to rocks is supported by the observation that the mercury content of rain is greater than freshwater. The much higher values of mercury in unconsolidated sediments compared to sedimentary rocks suggest that mercury is lost during diagenesis.Man's contribution of mercury to the surface environment is nearly equal to the natural contribution. Industrial loss contributes more than 65 per cent of man's total, and the contribution of fossil fuel consumption is small, although it may be locally important. The implications of mercury loss and absorption by soils may be an important factor in concentrating mercury in crops and other living matter, especially near industrialized areas.     

Pattern and mechanism of volcanic activity at the Santiaguito Volcanic Dome,Guatemala

Santiaguito volcano has shown a continuous slow extrusion of dacite lava since 1922. In the 50 years of activity there have been four periods of abnormally high extrusion rates, interspersed by periods of little magma production. The type of activity shown by the volcano has been varied and crudely cyclic. Dome extrusion periods are accompanied by pyroclastic activity and followed by lava flows. There are now 16 time stratigraphic units delineated on the dome. Activity since 1967 has been especially closely observed. Dome extrusion at the west end of the complex has been accompanied by pyroclastic cruptions and plug dome extrusion at the east end. The eurrent extrusion rate has remained essentially constant since 1967 at about 5×10⁶ m³/yr, far below Santiaguito’s 1922–71 average of 14×10⁶ m³/yr. The active vent at the east end of the volcano (Caliente vent) has been the principal vent of the volcano since the creation of the explosion crater in 1902. After its initial period of dome extrusion (1922–25), the Caliente vent has chiefly produced pyroclastic eruptions as well as at least 95% of the dome’s lumarolic activity, while lateral vents have continued to give rise to lavas. Lava flows at Santiaguito have effective viscosity values of about 10⁶ poises, while dome lavas are significantly more viscous. The differences in viscosity are in part related to volatile content of the lava when it reaches the surface. During dome extrusion, lavas lose their volatiles through pyroclastic activity before they reach the surface. Lava flows at Santiaguito occur when lava reaches the surface with higher volatile content. Obstruction of either the central (pyroclastic) vent or the lateral (dome extrusion) vent or both vents has an important influence on succeeding activity. In June 1972, at the time of this writing, the outbreak of new lava flows at both the Caliente and lateral El Brujo vents has just occurred, resulting from obstruction of pyroclastic activity by a large plug dome at the Caliente vent.     

The paleolimnological analysis of sediments from high mountain lake Nižné Terianske pleso in the High Tatras (Slovakia)

Sedimentological climate proxies and a 200-year long climate record, reconstructed using a data-set of European-wide meteorological data, have been compared at the high mountain lake Niné Terianske pleso in the High Tatras, Slovakia. Diatoms, chrysophyte stomatocysts, chironomids, plant pigments and spheroidal carbonaceous particles (SCPs) were analysed as well as sediment lithostratigraphic parameters. Using a radiometric approach the sediment core was dated and a depth of 4.6 cm was found to correspond to 1852 AD. The sediment accumulation rate (0.0034 g·cm^–2·yr^–1) was one of the lowest identified in the European mountain lake project, MOLAR. Despite this slow accumulation rate a remarkably coherent lithological and stratigraphic record has been recovered. The sediments of this remote mountain site, largely free from the effects of direct human impact, have been found to display a wealth of variability over the last 200 years.The record of spheroidal carbonaceous particles, indicators of anthropogenic pollution deposition, begins around 4.5–5.0 cm in depth (1833–1857). Temporal patterns are typical of European lake sites with the concentration peaking in the late 1970's. The SCP/²¹⁰Pb inventory ratio for the site is also in good agreement with the European latitudinal pattern. A strong influence of sample age on the chrysophyte assemblage composition in the upper-most 4–6 cm indicates that the main changes in the cysts have been related to long term environmental changes, probably pH. Analysis of chironomid remains revealed a stable profundal community. Chironomids as a whole showed no correlations to temperature fluctuations in the last 200 years. Relatively abundant remains of Diamesa sp. head capsules and other taxa closely associated with stream conditions in the older layers contrast with the absence of Diamesa sp. in the recent sediments. This change is considered to be evidence for the existence of a stronger, more stable inlet supplied from permanent granular snow fields in the lake basin. The most important changes in diatom assemblages were observed at 3cm. Many species of the genus Achnanthes spp. together with Navicula schmassmannii and Orthoseira roeseana made up the greatest part of the diatom community above 3 cm, being absent or rare lower in the record. A positive correlation between diatoms and mean summer temperature was found.     

Lake Jezero v Ledvici (NW Solvenia) – changes in sediment records over the last two centuries

Lake Jezero v Ledvici (NW Slovenia) is a 14 m deep mountain lake at an elevation of 1860 m, situated on limestone bedrock. It is an oligotrophic, alkaline and hard-water lake with a transparency of about 14 m and has suffered several times over recent centuries from strong earthquakes. In 1996 five sediment cores, between 35 and 45 cm long, were collected from the deepest part of the lake and analysed to reconstruct environmental changes over the last few centuries. The data indicate changes induced by pollution and climate change during the last two centuries similar to those in other European mountain and remote lakes. However, at this site earthquakes have also affected the lake and partly obscure the interpretation of the sediment record. From 1780 to 1890, sediment records show low abundance of diatoms and relatively high abundance of Cladocera. After 1890, the number of diatoms started to increase coinciding with a strong earthquake. From the beginning of the 20th century, concentrations of spheroidal carbonaceous particles (SCP), diatom valves and head capsules of chironomids gradually increased whilst in Cladocera the main difference observed was a change in the proportion of benthic taxa. After 1960, in parallel with a rise in air temperature, a further increase in accumulation rate of diatoms started, but there was a decrease in Cladocera.     

A chlorine-36 study of regional groundwater flow and vertical transport in southern Nevada

Chlorine-36 data for groundwater from the Death Valley regional flow system is interpreted in the context of existing conceptual models for regional groundwater flow in southern Nevada. Chlorine-36 end member compositions are defined for both recharge and chemically evolved groundwater components. The geochemical evolution of ³⁶Cl is strongly controlled by water-rock interaction with Paleozoic carbonate rocks that comprise the regional aquifer system, resulting in chemically evolved groundwater that is characteristically low in ³⁶Cl/Cl and high in Cl. Groundwater from alluvial and volcanic aquifers that overlie the regional carbonate aquifer are generally characterized by high ³⁶Cl/Cl and low Cl signatures, and are chemically distinct from water in the regional carbonate aquifer. This difference provides a means of examining vertical transport and groundwater mixing processes. In combination with other geochemical and hydrogeologic data, the end members defined here provide constraints on aquifer residence times and mixing ratios.     

Abandoned Underground Storage Tank Location Using Fluxgate Magnetic Surveying: A Case Study

In 1993, during the removal of a diesel and a gasoline underground storage tank at the municipal garage of the Village of Kohler, Sheboygan County, Wisconsin, soil testing revealed environmental contamination at the site. A site investigation revealed the possibility of a second on-site source of petroleum contamination. Limited historical data and the present usage of structures within the suspected source area precluded the use of most invasive sampling methods and most geophysical techniques. A fluxgate magnetometer survey, followed by confirmatory excavation, was conducted at the site. The fluxgate magnetometer survey identified nine possible magnetic anomalies within the 18 × 25 m area. The subsequent excavation near the anomalies revealed the presence of five paired and two individual 2000 L underground storage tanks. The fluxgate magnetometer survey, although affected by the proximity of buildings, was able to detect the buried tanks within 3 m of the brick structures, using a 1.5 × 1.5 m sampling array.     

Landscape and labyrinths

In the endeavour to reveal the politics behind landscape production, cultural geographers often neglect the most fundamental question of landscape, namely the question of how: how does the landscape work as both a visual and material space? How does it ‘stick' in the mind and in the world? By relying on concepts such as ideology, hegemony and naturalized discourse, cultural geographers have parried the question by assuming a structural connection between the landscape's appearance in the world and people's everyday consciousness. The goal of this paper is to provide an alternative account of the landscape's existence. I argue that the landscape comes to appear in the world as it is put to task. This means that the landscape's existence is not founded on its capacity to inscribe or normalize consciousness through its appearance in the world but on the landscape's capacity to be called forth through practice. The argument is elaborated through the work of George Bataille whose concept of the labyrinth provides the theoretical groundwork for an alternative understanding of what the landscape is as well as how it can be studied.     

Soil erosion due to rainfall impact with no inflow: a numerical solution with spatial and temporal effects of sediment settling velocity characteristics

Dynamic changes take place in the nature of sediment eroded from bare soil at low slopes by rainfall impact when there is no inflow of water at the top of the eroding slope. This relates initially to fine soil sediment not settling back onto the soil after the rainfall impact. Coupled partial differential equations describing such dynamic changes have been solved numerically for a bed of soil, bounded at its upper end, and subject to a constant rainfall rate. This solution allows prediction of the change with time and downslope distance in the concentration and settling velocity (or size) characteristics of eroding sediment, allowing critical evaluation of the assumption of space-independent sediment characteristics made in prior approximate analytical solutions of the equations involved. Following the determination of as yet unpredictable soil-related parameters in the equations, the solution was tested by comparison with experimented data on two soils of contrasting structural stability, namely a vertosol [The Australian Soil Classification (1996)] and a aridisol. Investigations included the determination of a minimum number of sediment size classes required to adequately describe the settling velocity characteristics, based on the shape of the underlying basic settling velocity characteristic, which is used to predict the dynamics of sediment deposition. The effect on the solution of observed structural breakdown in soil aggregation due to rainfall impact was investigated, leading to more accurate predictions of the settling velocity characteristics of eroded sediment. Other sources of discrepancy between theory and observation remain to be determined.