Supraglacial weathering crust dynamics inferred from cryoconite hole hydrology

Water levels in cryoconite holes were monitored at high resolution over a 3‐week period on Austre Brøggerbreen (Svalbard). These data were combined with melt and energy balance modelling, providing insights into the evolution of the glacier's near‐surface hydrology and confirming that the hydrology of the near‐surface, porous ice known as the ‘weathering crust’ is dynamic and analogous to a shallow‐perched aquifer. A positive correlation between radiative forcing of melt and drainage efficiency was found within the weathering crust. This likely resulted from diurnal contraction and dilation of interstitial pore spaces driven by variations in radiative and turbulent fluxes in the surface energy balance, occasionally causing ‘sudden drainage events’. A linear decrease in water levels in cryoconite holes was also observed and attributed to cumulative increases in near‐surface ice porosity over the measurement period. The transport of particulate matter and microbes between cryoconite holes through the porous weathering crust is shown to be dependent upon weathering crust hydraulics and particle size. Cryoconite holes therefore yield an indication of the hydrological dynamics of the weathering crust and provide long‐term storage loci for cryoconite at the glacier surface. This study highlights the importance of the weathering crust as a crucial component of the hydrology, ecology and biogeochemistry of the glacier ecosystem and glacierized regions and demonstrates the utility of cryoconite holes as natural piezometers on glacier surfaces. Copyright © 2015 John Wiley & Sons, Ltd.     

Chlorinated Solvent Source‐Zone Remediation via ZVI‐Clay Soil Mixing: 1‐Year Results

ZVI‐Clay is an emerging remediation approach that combines zero‐valent iron (ZVI)‐mediated degradation and in situ stabilization of chlorinated solvents. Through use of in situ soil mixing to deliver reagents, reagent‐contaminant contact issues associated with natural subsurface heterogeneity are overcome. This article describes implementation, treatment performance, and reaction kinetics during the first year after application of the ZVI‐Clay remediation approach at Marine Corps Base Camp Lejeune, North Carolina. Primary contaminants included trichloroethylene, 1,1,2,2‐tetrachloroethane, and related natural degradation products. For the field application, 22,900 m³ of soils were treated to an average depth of 7.6 m with 2% ZVI and 3% sodium bentonite (dry weight basis). Performance monitoring included analysis of soil and water samples. After 1 year, total concentrations of chlorinated volatile organic compounds (CVOCs) in soil samples were decreased by site‐wide average and median values of 97% and >99%, respectively. Total CVOC concentrations in groundwater were reduced by average and median values of 81% and >99%, respectively. In several of the soil and groundwater monitoring locations, reductions in total CVOC concentrations of greater than 99.9% were apparent. Further reduction in concentrations of chlorinated solvents is expected with time. Pre‐ and post‐mixing average hydraulic conductivity values were 1.7 × 10^?5 and 5.2 × 10^?8 m/s, respectively, indicating a reduction of about 2.5 orders of magnitude. By achieving simultaneous contaminant mass depletion and hydraulic conductivity reduction, contaminant flux reductions of several orders of magnitude are predicted.     

Seismic Velocity and Q Structure of the Middle Eastern Crust and Upper Mantle from Surface-wave Dispersion and Attenuation

—Observed velocities and attenuation of fundamental-mode Rayleigh waves in the period range 7–82 sec were inverted for shear-wave velocity and shear-wave Q structure in the Middle East using a two-station method. Additional information on Q structure variation within each region was obtained by studying amplitude spectra of fundamental-mode and higher-mode Rayleigh waves. We obtained models for the Turkish and Iranian Plateaus (Region 1), areas surrounding and including the Black and Caspian Seas (Region 2), and the Arabian Peninsula (Region 3). The effect of continent-ocean boundaries and mixed paths in Region 2 may lead to unrealistic features in the models obtained there. At lower crustal and upper-mantle depths, shear velocities are similar in all three regions. Shear velocities vary significantly in the uppermost 10 km of the crust, being 3.21, 2.85, and 3.39 km/s for Regions 1, 2, and 3, respectively. Q models obtained from an inversion of interstation attenuation data show that crustal shear-wave Q is highest in Region 3 and lowest in Region 1. Q’s for the upper 10 km of the crust are 63, 71, and 201 for Regions 1, 2, and 3, respectively. Crustal Q’s at 30 km depth for the three regions are about 51, 71, and 134. The lower crustal Q values contrast sharply with results from stable continental regions where shear-wave Q may reach one thousand or more. These low values may indicate that fluids reside in faults, cracks, and permeable rock at lower crustal, as well as upper crustal depths due to convergence and intense deformation at all depths in the Middle Eastern crust.     

Lg Coda Q and its Relation to the Structure and Evolution of Continents: A Global Perspective

—Tomographic maps of Lg coda Q (Q ^c _Lg) variation are now available for nearly the entire African, Eurasian, South American, and Australian continents, as well as for the United States. Q ^c _Lg at 1 Hz (Q ₀) varies from less than 200 to more than 1000 and Q ^c _Lg frequency dependence (<eta>) varies between 0.0 and nearly 1.0. Q ₀ appears to increase in proportion to the length of time that has elapsed since the most recent major episode of tectonic or orogenic activity in any region. A plot of Q ₀ versus time since that activity indicates that a single Q ₀-time relation approximates most mean Q ₀ values. Those that deviate most from the trend lay in Australia, the Arabian Peninsula, and the East African rift. The increase in Q ₀ with time may be due to a continual increase in crustal shear wave Q (Q ) caused by the loss of crustal fluids and reduction of crustal permeability following tectonic or orogenic activity. Extrapolated values of Q ^c _Lg at 5 Hz (using Q ₀ and <eta> values measured at 1 Hz and assuming that <eta> is constant in all regions between 1 and 5 Hz) show a similar percentage-wise increase with times that has elapsed since the most recent activity. Other factors that can reduce Q ₀ in continental regions include thick accumulations of sediment (especially sandstone and shale of Mesozoic age and younger), severe velocity gradients at the crust-mantle transition and, possibly, lateral variations in the depth, thickness, and severity of those gradients. Severe and large increases of Q in the mid-crust of some regions can cause relatively large values of <eta>, even if the frequency dependence of Q is small.     

Wetlands and low-gradient topography are associated with longer hydrologic transit times in Precambrian Shield headwater catchments

The estimation of hydrologic transit times in a catchment provides insights into the integrated effects of water storage, mixing dynamics, and runoff generation processes. There has been limited effort to estimate transit times in southern boreal Precambrian Shield landscapes, which are characteristically heterogeneous with surface cover including till, thin soils, bedrock outcrops, and depressional wetland features that play contrasting hydrologic roles. This study presents approximately 3.5 years of precipitation and streamflow water isotope data and estimates mean transit times (MTTs) and the young water fraction (p_y) across six small catchments in the Muskoka-Haliburton region of south-central Ontario. The main objectives were to define a typical range of MTTs for headwater catchments in this region and to identify landscape variables that best explain differences in MTTs/p_y using airborne light detection and ranging and digital terrain analysis. Of the transit time distributions, the two parallel linear reservoir and gamma distributions best describe the hydrology of these catchments, particularly because of their ability to capture more extreme changes related to events such as snowmelt. The estimated MTTs, regardless of the modelling approach or distribution used, are positively associated with the percent wetland area and negatively with mean slope in the catchments. In this landscape, low-gradient features such as wetlands increase catchment scale water storage when antecedent conditions are dryer and decrease transit times when there is a moisture surplus, which plausibly explains the increases in MTTs and mean annual runoff from catchments with significant coverage of these landscape features.