巯基棉分离富集-荧光分光光度法测定地下水中的痕量硒

在盐酸介质中,利用巯基棉分离富集地下水中痕量硒,然后在HC l-HNO3混合酸溶液及沸水浴加热条件下解脱富集的硒。通过测定2,3-二氨基萘与Se(Ⅳ)反应生成4,5-苯并苤硒脑的荧光强度,进而实现地下水中痕量硒的测定。实验表明,荧光光度法测定硒的线性范围为0~1.0μg,最低检测浓度为0.03μg/L,应用此法测定0.1μg/L硒的地下水,相对标准偏差小于7%,回收率达91%~105%,可满足地下水中硒的测定要求。     

胶东金矿集中区构造体系多层次控矿规律研究

提出中新生代东亚大陆与西太平洋带活动带相互关联的构造剪切带即是NNE向新华夏系巨型构造带。胶东金矿集中区产生于洋-陆过渡关联的该NNE向构造剪切带。对胶东构造体系进行了进一步研究,指出胶东中生代主要发育新华夏体系和华夏式构造系,而纬向构造体系,即EW向构造不发育。在此基础上,对胶东金矿集中区构造控制矿带、矿床、矿脉、地球化学分布和物理化学条件等不同层次特征加以分析,提出了胶东金矿成矿期构造具有多层次控矿特点,新华夏系NEE向泰山式构造控制胶东区域金矿带的展布;新华夏系NNE向区域剪切带控制金矿田产生部位;构造带断裂性质控制金矿矿床类别;构造断裂带的产状控制矿床矿体的倾伏侧伏规律;剪切构造两盘的运移特点和断裂组合形式控制矿脉的分布规律;构造变形岩相带控制构造地球化学特征;构造控制水岩系统成矿物理化学条件等认识。成矿构造研究、测量和资料分析证实,成矿阶段构造应力场最大主应力和最小主应力轴面是近于水平的,而中间主应力接近于垂直;区域成矿期应力场呈水平反钟向扭动剪切状,具有新华夏系应力场特征。从中生代应力场分析发现,除了区域反钟向挤压剪切构造特征外,主要成矿阶段构造环境还表现出应力松弛和拉张的特点,有普遍的断裂上盘下滑的构造成矿的特征。     

Initial Rifting Age of the Nearly N–S Rifts in Southern Tibetan Plateau: New Evidence from the Age limit of the Early Sediments

<正>Objective The nearly parallel N–S-trending rifts in southern Tibet represent the E–W extension of the Tibet Plateau.Most data which constrained the age of the extensional deformation come from isotopic dating of the dikes probably related to the activity of the nearly N–S faulting and micas from hydrothermal activity and the lowtemperature thermochronology of plateau uplift.Previous     

A Climatological Perspective on Extratropical Synoptic-Scale Transient Eddy Activity Response to Western Pacific Tropical Cyclones

An observational study focusing on the contribution of tropical cyclones(TCs)that form over the western North Pacific(WNP)to the synoptic-scale transient eddy activity(STEA)over the North Pacific during the boreal autumn and early winter in the period 1979–2019 is presented in this paper.Statistical results show that WNP TCs entering the midlatitudinal North Pacific provide significant positive effects on the pentad mean strength of STEA,which is primarily concentrated over the Kuroshio/Oyashio Extensions(KOE)and regions from east of Japan to 160°W in the lower and midto-upper troposphere,respectively.TC intensity is highly indicative of the subsequent STEA with a correlation coefficient of 0.37/0.33/0.45 at 300 hPa/500 hPa/850 hPa exceeding the 99%confidence level for the period 1979–2019.The strength of STEA in the upper troposphere associated with TCs presents a more significant linear growth with TC intensity than that at the mid-to-lower levels after the cyclones enter the KOE region,suggesting that the impact of TCs on STEA gradually increases with height.Further analyses reveal that the contribution of TCs accounts for 4%–6%of the total STEA change over the KOE region during the late autumn and early winter.In addition,the influence of TCs on STEA experienced an interdecadal decrease from the early 2000 s through the early 2010 s.     

江淮梅雨与梅雨期西北太平洋热带气旋的关系

基于梅雨综合指数,本文对1955—2010年江淮梅雨与梅雨期西北太平洋TC的变化关系及成因进行统计分析研究。结果表明:梅雨强弱与梅雨期TC频数存在显著的负相关,达到-0.41。同时,挑选出强梅雨年和弱梅雨年,发现强、弱梅雨异常年的TC特征差异显著,表现在:强梅雨年TC生成较少,以西、西北行为主,主要影响我国南部地区;弱梅雨年TC生成偏多,以转向路径为主,影响我国东南沿海众多省份。此外,两者通过大气环流场相互影响,梅雨期季风槽的位置与强度影响TC生成频数与源地,TC的活动又反作用于梅雨期的环流形式与水汽输送。     

沙坡头地区新月形沙丘粒度特征

由腾格里沙漠东南缘沙坡头附近新月形沙丘表面沉积物的系统采集分析结果,发现从北部沙漠主体向黄河南岸,沙丘沙平均粒径变细但分选变差。同时,粒径及分选性在沙丘断面出现两种变化模式,其一是沙漠主体新月形沙丘由两侧坡部向丘顶区域粒径变细分选变好;其二为黄河两岸阶地和湖盆滩地的新月形沙丘丘顶沙粒粗于其它部位但分选仍然最好。根据粒度参数间的相互关系和其它环境条件的分析,对沙丘沙粒度变化的原因及偏度等也作了初步探讨。     

The 30–60-day oscillation in the East Asian summer monsoon and its time-dependent association with the ENSO

Based on 30–60-day oscillation in the East Asian summer monsoon (EASM), the relationship between its northward propagation and ENSO (El Niño and Southern Oscillation) was investigated. To explicitly describe the 30–60-day monsoonal evolution, an empirical orthogonal function (EOF) analysis was carried out on the temporal-latitude section of the longitudinal average for 115°E–120°E. The principal 30–60-day EASM mode captures a northward propagation of well-organized intraseasonal oscillation (NISO). Using the associated time series of the first mode, we found a significant lagged correlation between interannual variability of the NISO and ENSO. Its lagged correlations with NINO indices have a quasi-biennial (QB) characteristic through the preceding summer and the concurrent summer. Their relationship was found by the regression analysis relating the low-level circulation to the ocean temperature. The western North Pacific anticyclone and the anticyclone-induced easterly vertical wind shear anomalies induce the dynamical linkage between the NISO and QB-type ENSO. It is shown that the NISO is more closely tied with QB-type ENSO in its phase than in its amplitude, and may be connected to the anomalous easterly wind and the eastward evolution of an oceanic Kelvin wave, which is associated with abrupt ENSO transition. The predictability on ENSO and NISO is examined through the canonical correlation analysis.     

ROLE OF EQUATORIAL PACIFIC OCEAN SUBSURFACE OCEANIC TEMPERATURE MODE IN ENSO CYCLE

Based on the simple ocean data assimilation (SODA) reanalysis dataset from the University of Maryland and the method of Empirical Orthogonal Functions (EOF), the characteristics of interannual and interdecadal variabilities of the equatorial Pacific subsurface oceanic temperature anomaly (SOTA) are captured. The first and second modes of the equatorial Pacific SOTA in the interannual and interdecadal variations are found respectively and the effect of the second mode on the ENSO cycle is discussed. Results show that the first mode of SOTA’s interannual and interdecadal variabilities exhibit a dipole pattern, indicating that the warm and cold temperature anomalies appear simultaneously in the equatorial subsurface Pacific. The second mode shows coherent large-scale temperature anomalies in the equatorial subsurface Pacific, which is a dominant mode in the evolution of ENSO cycle. The temporal series of the second mode has a significant lead correlation with the Ni?o-3.4 index, which can make a precursory prediction signal for ENSO. The function of this prediction factor in SOTA is verified by composite and case analyses.     

藏南及邻区典型晚新生代盆地磁性地层研究现状与时代对比分析

在系统梳理扎达盆地、尼泊尔Thakkhola半地堑盆地、吉隆—沃马盆地、乌郁盆地磁性地层研究成果的基础上, 对古地磁年代所代表的地质事件进行了对比和分析, 认为藏南及邻区各近南北向裂谷盆地自形成以来均发育2次明显的沉积变动事件, 第一次为距今10.6~8.1 Ma期间各盆地分别开始接受沉积, 第二次为距今3.5~2.0 Ma各湖盆的连续消亡; 总结高原的气候变化可以发现, 高原在距今约8 Ma及3 Ma左右也有明显的2次气候变化, 即沉积事件与气候变化事件在时间上具有近同时性。扎达盆地、吉隆—沃马盆地、达涕盆地三趾马化石的时代都处于距今7.0~6.5 Ma之间, 也具有近同时性。结合高原的整体演化, 认为其可能在距今10.6~8.1 Ma、3.5~2.0 Ma发生了2期比较强烈的隆升运动。同时, 分析指出了青藏高原南部及邻区晚新生代盆地磁性地层研究过程中存在的问题及解决方法, 并对今后青藏高原南部及邻区地区晚新生代磁性地层研究提出了建议。      

基于数字化水位的张渤带地区构造应力场时序特征分析

选取张渤带地区2008年以来连续稳定、固体潮形态明显的昌平台井、顺义板桥井、宝坻井、辛庄井、玉田冀03井、大灰厂井等6口井数字化水位及相应的气压资料。利用气压系数和M2波潮汐因子等滑动拟合,得到不排水状态下,各井含水层的孔隙度、固体骨架的体积压缩系数和水的体积压缩系数。接着在水平层状含水层(一维)模式下,利用部分含水层介质参数(孔隙度、水和固体骨架的体积压缩系数)、井水位变化量与含水层垂直向应力变化量的关系式,定量分析了张渤带地区构造应力场的动态变化过程。结果表明,张渤带近几年以持续的应力增强活动为主,今后需加强多学科、多手段的密切跟踪。