Trace Element Partitioning and Accessory Phase Saturation during H2O-Saturated Melting of Basalt with Implications for Subduction Zone Chemical Fluxes

Experimental phase equilibrium and trace element partitioningdata are reported for H₂O-saturated mid-ocean ridge basalt at2·5 GPa, 750–900°C and oxygen fugacities atthe nickel–nickel oxide buffer. Garnet, omphacite andrutile are present at all temperatures. Amphibole and epidotedisappear as residual phases above 800°C; allanite appearsabove 750°C. The Na–Al-rich silicate glass presentin all run products is likely to have quenched from a supercriticalliquid. Trace element analyses of glasses demonstrate the importantcontrol exerted by residual minerals on liquid chemistry. Inaddition to garnet, which controls heavy rare earth elements(HREE) and Sc, and rutile, which controls Ti, Nb and Ta, allanitebuffers the light REE (LREE; La–Sm) contents of liquidsto relatively low levels and preferentially holds back Th relativeto U. In agreement with previous experimental and metamorphicstudies we propose that residual allanite plays a key role inselectively retaining trace elements in the slab during subduction.Experimental data and analyses of allanite-bearing volcanicrocks are used to derive a model for allanite solubility inliquids as a function of pressure, temperature, anhydrous liquidcomposition and LREE content. The large temperature dependenceof allanite solubility is very similar to that previously determinedfor monazite. Our model, fitted to 48 datapoints, retrievesLREE solubility (in ppm) to within a factor of 1· 40over a pressure range of 0–4 GPa, temperature range of700–1200°C and for liquids with anhydrous SiO₂ contentsof 50–84 wt %. This uncertainty in LREE content is equivalentto a temperature uncertainty of only ± 27°C at 1000K, indicating the potential of allanite as a geothermometer.Silicic liquids from either basaltic or sedimentary protolithswill be saturated in allanite except for Ca-poor protolithsor at very high temperatures. For conventional subduction geothermsthe low solubility of LREE (+ Th) in liquids raises questionsabout the mechanism of LREE + Th transport from slab to wedge.It is suggested either that, locally, temperatures experiencedby the slab are high enough to eliminate allanite in the residueor that substantial volumes of H₂O-rich fluids must pass throughthe mantle wedge prior to melting. The solubility of accessoryphases in fluids derived from subducted rocks can provide importantconstraints on subduction zone thermal structure. KEY WORDS: subduction; experimental petrology; allanite; solubility; supercritical liquid; eclogite     

在庆祝山东省地质科学实验研究院建院50周年大会上的讲话

今天,我们在这里隆重集会,庆祝省地科院建院50周年.首先,我代表山东省国土资源厅,向全院广大干部职工和离退休老同志,表示崇高的敬意!向长期以来关心支持我省地质工作的各级领导和社会各界人士,表示衷心的感谢!     

A comparison of methods to assess long-term changes in Sonoran Desert vegetation

Knowledge about the condition of vegetation cover and composition is critical for assessing the structure and function of ecosystems. To effectively quantify the impacts of a rapidly changing environment, methods to track long-term trends of vegetation must be precise, repeatable, and time- and cost-efficient. Measuring vegetation cover and composition in arid and semiarid regions is especially challenging because vegetation is typically sparse, discontinuous, and individual plants are widely spaced. To meet the goal of long-term vegetation monitoring in the Sonoran Desert and other arid and semiarid regions, we determined how estimates of plant species, total vegetation, and soil cover obtained using a widely-implemented monitoring protocol compared to a more time- and resource-intensive plant census. We also assessed how well this protocol tracked changes in cover through 82 years compared to the plant census. Results from the monitoring protocol were comparable to those from the plant census, despite low and variable plant species cover. Importantly, this monitoring protocol could be used as a rapid, “off-the shelf” tool for assessing land degradation (or desertification) in arid and semiarid ecosystems.     

Signature of differential rotation in solar disk‐integrated chromospheric line emission

UARS SOLSTICE data have been subjected to Fourier and wavelet analyses in order to search for the signature of the solar rotation law in the disk‐integrated irradiance of UV lines. Lyman‐α, Mg II, and Ca II data show a different behaviour. In the SOLSTICE data there are significant temporal variations of the rotation rate of the UV tracers over 5—6 years. Often several distinct rotation periods appear almost simultaneously. Beside the basic period around 27 days there are signals at 32—35 days corresponding to the rotation rate at very high latitudes. For more than 5 years during another period of the solar cycle the rotational behaviour is quite different; there is an indication of differential rotation of active regions in these Ca II ground‐based data. The data contain a wealth of information about the solar differential rotation, but it proves difficult to disentangle the effects of the different emitting sources.     

The radiation balance at Copenhagen

Summary At the Climate and Water Balance Station of the Danish Hydrotechnical Laboratory near Copenhagen incoming radiation has been recorded continuously since 1954 by means of Moll thermopiles in Kipp & Zonen solarimeters and further, since 1955, reflected radiation, too. Since 1956 also net radiation and net long-wave radiation has been recorded by means of thermopiles in heat flow transducers from Beckman & Whitley used as radiometers.Mean daily values are given for incoming radiation as well as monthly mean values for reflected radiation, net long-wave radiation and net radiation. Recorded and calculated values of net long-wave radiation are given and discussed.

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Zusammenfassung An der Klima- und Wasserhaushaltsstation des Dänischen Hydrotechnischen Laboratoriums bei Kopenhagen wurde seit 1954 dauernd die Einstrahlung mittels Moll-Thermosäulen in Kipp & Zonen-Solarimetern registriert und außerdem seit 1955 die Albedo. Seit 1956 wurden auch die Strahlungsbilanz und die effektive Ausstrahlung mittels Thermosäulen in Beckman & Whitley-Wärmestrommessern, die als Strahlungsmesser verwendet wurden, registriert.In einigen Tabellen werden tägliche Mittelwerte der Einstrahlung mitgeteilt wie auch Monatsmittelwerte der Reflexstrahlung, der effektiven Ausstrahlung und der Strahlungsbilanz. Ferner werden beobachtete und berechnete Werte der langwelligen Strahlungsbilanz angeführt und diskutiert.

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Résumé On a effectué des enregistrements du rayonnement incident depuis 1954 et de l'albédo depuis 1955 à la Station d'économie climatologique et hydrologique du laboratoire danois d'hydrotechnique près de Copenhague. Le bilan radiatif fut également mesuré depuis 1956 ainsi que le rayonnement émis effectif.Les auteurs donnent ici des tableaux de valeurs journalières moyennes du rayonnement incident, des moyennes mensuelles de l'albédo, du rayonnement effectif et du bilan radiatif. Enfin des valeurs enregistrés et calculés du rayonnement effectif, sont présentés et discutés.

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With 5 Figures     

用土的分形结构确定土的水份特征曲线

运用筛析法和比重计法，分析了宁夏膨胀土的颗粒分布，发现粒径介于0．002～0．1mm的粒度分布是分形的，分维介于2．46～2．67；运用上孔隙分布的分维确定水份特征曲线，得到了很好的结果。此外，还探讨了粒度分形分布的机制。     

Investigation of ammonia removal from polluted waters by Clinoptilolite zeolite

Ammonia nitrogen compounds in the wastewaters and effluents have harmful effects on water resources. Ion exchange with zeolites is a separation process for ammonia removal from effluents. The objective of this research was to study the efficiency of an ammonia removal and the factor affecting to this process. The Clinoptilolite was obtained from Semnan mines at the north part of Iran. The samples were grounded and sieved based on the U.S. standard mesh number 20, 30, 40 and conditioned by ammonia sulfate and sodium chloride solutions. The characteristics of samples for ammonia removal and the selectivity sequence for adsorbing interfering cations were then determined. Results shown that the average ion exchange capacity of zeolite in batch and continuous systems were 6.65–16 and 16.31–19.5 mg NH₄ ⁺ /g zeolite weight, respectively. In study on the zeolite for selective cations showed the ranking of K⁺, NH₄ ⁺, Na⁺, Ca²⁺ and Mg²⁺ respectively. Results indicated that high level of regeneration (95–98%) might be achieved with NaCl solution. Based on the results, Clinoptilolite may be effective applied in wastewater treatment, both from technical and economical aspects.     

The abundance and radial distribution of satellite galaxies

Using detailed mock galaxy redshift surveys (MGRSs) we investigate the abundance and radial distribution of satellite galaxies. The mock surveys are constructed using large numerical simulations and the conditional luminosity function (CLF), and are compared against data from the Two Degree Field Galaxy Redshift Survey (2dFGRS). We use Monte Carlo Markov chains to explore the full posterior distribution of the CLF parameter space, and show that the average relation between light and mass is tightly constrained and in excellent agreement with our previous models and with that of Vale & Ostriker. The radial number density distribution of satellite galaxies in the 2dFGRS reveals a pronounced absence of satellites at small projected separations from their host galaxies. This is (at least partly) owing to the overlap and merging of galaxy images in the 2dFGRS parent catalogue. Owing to the resulting close-pair incompleteness we are unfortunately unable to put meaningful constraints on the radial distribution of satellite galaxies; the data are consistent with a radial number density distribution that follows that of the dark matter particles, but we cannot rule out alternatives with a constant number density core. Marginalizing over the full CLF parameter space, we show that in a ΛCDM concordance cosmology the observed abundances of host and satellite galaxies in the 2dFGRS indicate a power spectrum normalization of  σ₈≃ 0.7  . The same cosmology but with  σ₈= 0.9  is unable to match simultaneously the abundances of host and satellite galaxies. This confirms our previous conclusions based on the pairwise peculiar velocity dispersions and the group multiplicity function.     

合肥盆地钻井地层的同位素测年与地层划分

合肥盆地内部中、新界地层大面积被第四系覆盖，其地层的时代与划分主要依赖已有的6口深井地层资料。由于缺乏可靠的化石记录，这6口深井地层时代与划分一直存在着很大的分歧，制约了对该盆地的油气勘探与远景评价。本文利用这6口深井泥岩类岩屑中自生伊利石，在其结晶度分析基础上，进行了K-Ar同位素测年，成功地获得了不同深度上的地层形成时代。据此地层年龄，文中对这6口深井所钻遇的地层进行了重新的划分。     

Proterozoic–Paleozoic development of the basement of the Central Andes (18–26°S) — a mobile belt of the South American craton

The Late Precambrian–Early Paleozoic metamorphic basement forms a volumetrically important part of the Andean crust. We investigated its evolution in order to subdivide the area between 18 and 26°S into crustal domains by means of petrological and age data (Sm–Nd isochrons, K–Ar). The metamorphic crystallization ages and t_DM ages are not consistent with growth of the Pacific margin north of the Argentine Precordillera by accretion of exotic terranes, but favor a model of a mobile belt of the Pampean Cycle. Peak metamorphic conditions in all scattered outcrop areas between 18 and 26°S are similar and reached the upper amphibolite facies conditions indicated by mineral paragensis and the occurrence of migmatite. Sm–Nd mineral isochrons yielded 525±10, 505±6 and 509±1 Ma for the Chilean Coast Range, the Chilean Precordillera and the Argentine Puna, and 442±9 and 412±18 Ma for the Sierras Pampeanas. Conventional K–Ar cooling age data of amphibole and mica cluster around 400 Ma, but are frequently reset by Late Paleozoic and Jurassic magmatism. Final exhumation of the Early Paleozoic orogen is confirmed by Devonian erosional unconformities. Sm–Nd depleted mantle model ages of felsic rocks from the metamorphic basement range from 1.4 to 2.2 Ga, in northern Chile the average is 1.65±0.16 Ga (1σ; n=12), average t_DM of both gneiss and metabasite in NW Argentina is 1.76±0.4 Ga (1σ; n=22), and the isotopic composition excludes major addition of juvenile mantle derived material during the Early Paleozoic metamorphic and magmatic cycle. These new data indicate a largely similar development of the metamorphic basement south of the Arequipa Massif at 18°S and north of the Argentine Precordillera at 28°S. Variations of metamorphic grade and of ages of peak metamorphism are of local importance. The protolith was derived from Early to Middle Proterozoic cratonic areas, similar to the Proterozoic rocks from the Arequipa Massif, which had undergone Grenvillian metamorphism at ca. 1.0 Ga.