Zircon and whole-rock Nd-Pb isotopic provenance of Middle and Upper Ordovician siliciclastic rocks, Argentine Precordillera

Graptolite‐bearing Middle and Upper Ordovician siliciclastic facies of the Argentine Precordillera fold‐thrust belt record the disintegration of a long‐lived Cambro‐Mid Ordovician carbonate platform into a series of tectonically partitioned basins. A combination of stratigraphic, petrographic, U‐Pb detrital zircon, and Nd‐Pb whole‐rock isotopic data provide evidence for a variety of clastic sediment sources. Four Upper Ordovician quartzo‐lithic sandstones collected in the eastern and central Precordillera yield complex U‐Pb zircon age spectra dominated by 1·05–1·10 Ga zircons, secondary populations of 1·22, 1·30, and 1·46 Ga, rare 2·2 and 1·8 Ga zircons, and a minor population (<2%) of concordant zircons in the 600–700 Ma range. Archaean‐age grains comprise <1% of all zircons analysed from these rocks. In contrast, a feldspathic arenite from the Middle Ordovician Estancia San Isidro Formation of the central Precordillera has two well‐defined peaks at 1·41 and 1·43 Ga, with no grains in the 600–1200 Ma range and none older than 1·70 Ga. The zircon age spectrum in this unit is similar to that of a Middle Cambrian quartz arenite from the La Laja Formation, suggesting that local basement rocks were a regional source of ca 1·4 Ga detrital zircons in the Precordillera Terrane from the Cambrian onwards. The lack of grains younger than 600 Ma in Upper Ordovician units reinforces petrographic data indicating that Ordovician volcanic arc sources did not supply significant material directly to these sedimentary basins. Nd isotopic data (n = 32) for Middle and Upper Ordovician graptolitic shales from six localities define a poorly mixed signal [ɛ_Nd(450 Ma) = −9·6 to −4·5] that becomes more regionally homogenized in Upper Ordovician rocks (−6·2 ± 1·0; T_DM = 1·51 ± 0·15 Ga; n = 17), a trend reinforced by the U‐Pb detrital zircon data. It is concluded that proximal, recycled orogenic sources dominated the siliciclastic sediment supply for these basins, consistent with rapid unroofing of the Precordillera Terrane platform succession and basement starting in Mid Ordovician time. Common Pb data for Middle and Upper Ordovician shales from the western and eastern Precordillera (n = 15) provide evidence for a minor (<30%) component that was likely derived from a high‐μ (U/Pb) terrane.     

Coronal disturbances

Time lapse movies acquired with the Sacramento Peak Observatory 6-in filter coronagraph very infrequently show dramatic transient events. Many of these events (at 1.04 < r/r < 1.20) are correlated with H activity at the limb, especially with large surges and eruptive prominences. Metric or centrimetric radio bursts are found associated with certain types of 5303 coronal events. The heights to which such disturbances will propagate can often be estimated from the green line movie data. We report the results of a study of all the examples of such transients observed during the last 16 years.     

Risk Management for Petroleum Reservoir Production: A Simulation-Based Study of Prediction

We consider numerical solutions of the Darcy and Buckley–Leverett equations for flow in porous media. These solutions depend on a realization of a random field that describes the reservoir permeability. The main content of this paper is to formulate and analyze a probability model for the numerical coarse grid solution error. We explore the extent to which the coarse grid oil production rate is sufficient to predict future oil production rates. We find that very early oil production data is sufficient to reduce the prediction error in oil production by about 30%, relative to the prior probability prediction.     

A model of impulsive loop flares revisited

A critical examination of the components of the recent impulsive loop flare model of Takakura is made. It is found that his analysis of the stability of the electron distribution resulting from anomalous heat conduction is in error and electron plasma waves would not be excited. Rather, in the regions where the electron/proton temperature ratioT _e/T _i 10, electrostatic ion-cyclotron waves would be excited and in the regions whereT _e 10, ion-acoustic waves would be excited. Ratios ofT _e/T _i 10 occur only in the late time development behind the conduction fronts. Since the anomalous resistivity due to electrostatic ion-cyclotron waves is fortuitously about 70% of the one used by Takakura, the general development will follow closely the one calculated by him. Because the anomalous resistivity due to ion-acoustic waves is about 95 times the one used by Takakura, the development in the parts of the loop whereT _e/T _i 10 for late times would be altered considerably.Also Guest Worker at NOAA Space Environment Laboratory, Boulder, Colorado, U.S.A.     

Artificial light at night: implications for early life stages development in four temperate freshwater fish species

Flora and fauna have both evolved under a natural cycle of light and dark. But especially in urban areas, the night is now increasingly disturbed by artificial light. Many traits and behaviours in fish are triggered by a circadian clock, for example hatching and swim bladder inflation, which predominantly take place at dusk or night. As lighting becomes brighter and extends farther into rural areas, the distinction between day and night becomes increasingly blurred. Therefore, the loss of diurnal trigger by artificial light at night was hypothesized having deleterious effects on these traits and impact fish reproduction. To assess these effects, eggs of four native freshwater fishes, Eurasian perch Perca fluviatilis, roach Rutilus rutilus, bleak Alburnus alburnus and chub Leuciscus cephalus, were incubated under two different light conditions: a photoperiod of 14 h light:10 h darkness (LD) and continuous illumination (LL). The time to hatch and swim bladder inflation was recorded. The species showed inconsistent reactions to the light treatments. In roach and bleak, the time to 50% hatch was longer in LL, whereas continuous lighting had an accelerating effect in chub. Incubation in LL elongated the hatching period in perch and roach and, in perch, the onset of darkness seemed to trigger hatching. The swim bladder inflation was significantly promoted by continuous light in chub and bleak but was not affected in roach. In conclusion, nocturnal artificial illumination could have an effect on hatching and initial swim bladder filling by masking the day–night-change and thereby diminish the trigger effect. However, the reactions were species specific and the increase in variation indicated a lack of diurnal triggering, whilst a general deleterious effect of artificial light at night has not been identified on early life stages.     

The role of prior model calibration on predictions with ensemble Kalman filter

This paper, based on a real world case study (Limmat aquifer, Switzerland), compares inverse groundwater flow models calibrated with specified numbers of monitoring head locations. These models are updated in real time with the ensemble Kalman filter (EnKF) and the prediction improvement is assessed in relation to the amount of monitoring locations used for calibration and updating. The prediction errors of the models calibrated in transient state are smaller if the amount of monitoring locations used for the calibration is larger. For highly dynamic groundwater flow systems a transient calibration is recommended as a model calibrated in steady state can lead to worse results than a noncalibrated model with a well-chosen uniform conductivity. The model predictions can be improved further with the assimilation of new measurement data from on-line sensors with the EnKF. Within all the studied models the reduction of 1-day hydraulic head prediction error (in terms of mean absolute error [MAE]) with EnKF lies between 31% (assimilation of head data from 5 locations) and 72% (assimilation of head data from 85 locations). The largest prediction improvements are expected for models that were calibrated with only a limited amount of historical information. It is worthwhile to update the model even with few monitoring locations as it seems that the error reduction with EnKF decreases exponentially with the amount of monitoring locations used. These results prove the feasibility of data assimilation with EnKF also for a real world case and show that improved predictions of groundwater levels can be obtained.     

Bildung bromhaltiger Desinfektionsnebenprodukte nach Chlorung von Bodenseewasser in Abhängigkeit von Aufbereitungsschritten und der Bromidkonzentration

Formation of Brominated Disinfection By-products after Chlorination of Water from Lake Constance Depending on Treatment Steps and Bromide Concentration The formation of halogenated disinfection by-products (DNP) (trihalomethanes (THM), haloacetic acids (HES), haloacetonitriles (HAN), haloketones (HKE) and chloropicrin (TCNM)) was studied after chlorination (0.5 mg/L) of raw water and drinking water from Lake Constance. The objectives of this study were to investigate the effect of bromide ion on the distribution of DNP-species resulting from chlorination and to draw up a bromide mass-balance. The treatment of water from Lake Constance with ozone decreased the formation of DNP about 35% and of total organic halogens (AOX) about 45%. This decline in DNP-formation is mainly due to the formation of chloroform, dichloro- and trichloroacetic acid. Though there is only a small amount of bromide (6.2 μg/L) in water from Lake Constance, about 32% of THM, 16% of HES, and 30% of HAN contained bromine after chlorination of treated water. The addition of bromide ion (up to 1 mg/L) shifted the DNP-composition to more brominated species. The distribution of the DNP-species depends on the initial molar bromide-to-chlorine ratio. A mathematic model showed the same pattern of DNP-species depending on the initial molar bromide-to-chlorine ratio that was observed experimentally in microstrained raw water and drinking water from Lake Constance. After chlorination of microstrained raw water, 27% of the bromide were incorporated in known DNP, 34% in unknown substances, and about 39% of bromide were not converted to organic bromine. After chlorination of treated water, only 16% of the bromide were incorporated in unknown substances, whereas 34% were found in known DNP. About 50% were found as bromide again. After addition of bromide (up to 25 μg/L) to ozonated and treated water from Lake Constance, between 60 and 72% of the bromide that had reacted after chlorination were found in analyzed low-molecular DNP.     

SporadicE ionization associated with meteor events

Two meteor events which were sighted in the Gujarat skies of India, were accompained by the visibility of sporadicE ionization on the ionograms recorded at Ahmedabad (Geog. Lat. 23·2°N, long. 72·30°E). The first event was the Dhajala fireball which flashed into the geoatmosphere along an E-N to W-S trail at about 20·40 h IST on 28 January 1976; the closest distance of the ground projection of meteor trail from Ahmedabad was 50km. The other event was a possible meteor group sighted over Ahmedabad on 28 May 1978, at about 21·10 h IST. This work describes the nature of the sporadicE ionization observed on Ahmedabad ionograms during the two events. Features of theEs echo during the Dhajala event which indicate that it could be of meteoric origin are discussed. Meteor theory is used to relate the observed ionization with the physical dimensions of the Dhajala meteorite as obtained by other workers.